相关论文: Regularized Boltzmann entropy determines macroscop…
Clausius introduced, in the 1860s, a thermodynamical quantity which he named {\it entropy} $S$. This thermodynamically crucial quantity was proposed to be {\it extensive}, i.e., in contemporary terms, $S(N) \propto N$ in the thermodynamic…
Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…
Observational entropy provides a general notion of quantum entropy that appropriately interpolates between Boltzmann's and Gibbs' entropies, and has recently been argued to provide a useful measure of out-of-equilibrium thermodynamic…
The basic aspects of both Boltzmann-Gibbs (BG) and nonextensive statistical mechanics can be seen through three different stages. First, the proposal of an entropic functional ($S_{BG} =-k\sum_i p_i \ln p_i$ for the BG formalism) with the…
Non-extensive systems do not allow to go to the thermodynamic limit. Therefore we have to reformulate statistical mechanics without invoking the thermodynamical limit. I.e. we have to go back to Pre-Gibbsian times. We show that Boltzmann's…
We prove that the transport of any differentiable scalar observable in $d$-dimensional non-equilibrium systems is bounded from above by the total entropy production scaled by the amount the observation "stretches" microscopic coordinates.…
Let $\pi\colon (M,\omega)\to B$ be a non-singular Lagrangian torus fibration on a complete base $B$ with prequantum line bundle $\bigl(L,\nabla^L\bigr)\to (M,\omega)$. Compactness on $M$ is not assumed. For a positive integer $N$ and a…
To reconstruct thermodynamics based on the microscopic laws is one of the most important unfulfilled goals of statistical physics. Here, we show that the first law and the second law for adiabatic processes are derived from an assumption…
Many natural and artificial systems whose range of interaction is long enough are known to exhibit (quasi)stationary states that defy the standard, Boltzmann-Gibbs statistical mechanical prescriptions. For handling such anomalous systems…
Boltzmann's ergodic hypothesis furnishes a possible explanation for the emergence of statistical mechanics in the framework of classical physics. In quantum mechanics, the Eigenstate Thermalization Hypothesis (ETH) is instead generally…
The Boltzmann-Gibbs celebrated entropy $S_{BG}=-k\sum_ip_i \ln p_i$ is {\it concave} (with regard to all probability distributions $\{p_i\}$) and {\it stable} (under arbitrarily small deformations of any given probability distribution). It…
It has recurrently been proposed that the Boltzmann textbook definition of entropy $S(E)=k\ln \Omega (E)$ in terms of the number of microstates $\Omega (E)$ with energy $E$ should be replaced by the expression $S_G(E)=k\ln \sum_{E^\prime…
Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…
Entropy, its production, and its change in a dynamical system can be understood from either a fully stochastic dynamic description or from a deterministic dynamics exhibiting chaotic behavior. By taking the former approach based on the…
Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…
The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established…
An unified thermodynamical framework based in the use of a generalized Massieu-Planck thermodynamic potential is proposed and a new formulation of Boltzmann-Gibbs Statistical Mechanics is established. Under this philosophy a generalization…
The quantum adiabatic theorem is a fundamental result in quantum mechanics, with a multitude of applications, both theoretical and practical. Here, we investigate the dynamics of adiabatic processes for quantum many-body systems %in detail…
Carnot's four-part ideal-gas cycle includes both isothermal and adiabatic expansions and compressions. Analyzing this cycle provides the fundamental basis for statistical thermodynamics. We explore the cycle here from a pedagogical view in…
This paper shows that the energetics of Boussinesq and anelastic fluids possesses a term that can be identified as the approximation $\delta W_{ba}$ to the compressible work of expansion/contraction $\delta W =-P {\rm d}\upsilon$, where $P$…