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A problem of the equivalence of statistical ensembles is critically analyzed. It is shown, that although different probability distributions of statistical physics have the same behavior in the thermodynamic limit, there are physical…

高能物理 - 理论 · 物理学 2007-11-17 Ludwik Turko

We extend the recently developed non-gaussian thermodynamic formalism \cite{tre98} of a (presumably strongly turbulent) non-Markovian medium to its most general form that allows for the formulation of a consistent thermodynamic theory. All…

空间物理 · 物理学 2009-10-31 R. A. Treumann

It is shown that the structure of thermodynamics is "form invariant", when it is derived using maximum entropy principle for various choices of entropy and even beyond equilibrium. By the form invariance of thermodynamics, it is meant that…

量子物理 · 物理学 2015-11-12 Avijit Misra , Uttam Singh , Manabendra Nath Bera , A. K. Rajagopal

The phenomenon of partial equivalence of statistical ensembles is illustrated by discussing two examples, the mean-field XY and the mean-field spherical model. The configurational parts of these systems exhibit partial equivalence of the…

统计力学 · 物理学 2007-09-25 Lapo Casetti , Michael Kastner

Molecular or condensed matter systems are often well approximated by hybrid quantum-classical models: the electrons retain their quantum character, whereas the ions are considered to be classical particles. We discuss various alternative…

化学物理 · 物理学 2021-05-07 J. L. Alonso , C. Bouthelier , A. Castro , J. Clemente-Gallardo , J. A. Jover-Galtier

A great many observables seen in intermediate energy heavy ion collisions can be explained on the basis of statistical equilibrium. Calculations based on statistical equilibrium can be implemented in microcanonical ensemble (energy and…

核理论 · 物理学 2009-11-10 C. B. Das , S. Das Gupta , W. G. Lynch , A. Z. Mekjian , M. B. Tsang

We provide a quantum statistical basis for (a)a characterisation of a complete set of thermodynamic variables and (b) the differentiability of the entropy function of these variables

数学物理 · 物理学 2019-03-27 Geoffrey L. Sewell

We present a universal thermodynamic framework for quantum systems that may be strongly coupled to thermal environments. Unlike previous approaches, our method enables a clear definition of thermostatic properties while preserving the same…

量子物理 · 物理学 2026-04-16 Ignacio González , Sagnik Chakraborty , Ángel Rivas

We consider the micro-canonical ensemble of a classical Hamiltonian dynamical system, the Hamiltonian being parameter dependent and in the possible presence of other first integrals. We describe a thermodynamic formalism in which a 1st law…

混沌动力学 · 物理学 2007-05-23 Hans Henrik Rugh

We devise a hierarchy of computational algorithms to enumerate the microstates of a system comprising N independent, distinguishable particles. An important challenge is to cope with integers that increase exponentially with system size,…

计算物理 · 物理学 2015-05-28 Trisha Salagaram , Nithaya Chetty

To understand under which conditions thermodynamics emerges from the microscopic dynamics is the ultimate goal of statistical mechanics. Despite the fact that the theory is more than 100 years old, we are still discussing its foundations…

量子物理 · 物理学 2017-03-14 Fabio Anza , Vlatko Vedral

In the present paper we continue our reconsideration about the foundations for a thermostatistical description of the called Hamiltonian nonextensive systems (see in cond-mat/0604290). After reviewing the selfsimilarity concept and the…

统计力学 · 物理学 2007-05-23 L. Velazquez , F. Guzman

In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…

量子物理 · 物理学 2007-05-23 Elias P. Gyftopoulos , Gian Paolo Beretta

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

统计力学 · 物理学 2011-06-13 P. D. Gujrati

Motivated by the fact that the (inverse) temperature might be a function of the energy levels in the Planck distribution $n_\epsilon=\frac1{\zeta^{-1}e^{\beta(\epsilon)\epsilon}-1}$ for the occupation number $n_\epsilon$ of the level…

统计力学 · 物理学 2017-01-04 Francesco Fidaleo , Stefano Viaggiu

The problem of temperature in nonextensive statistical mechanics is studied. Considering the first law of thermodynamics and a "quasi-reversible process", it is shown that the Tsallis entropy becomes the Clausius entropy if the inverse of…

统计力学 · 物理学 2009-11-11 Sumiyoshi Abe

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

数学物理 · 物理学 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

The equivalence of thermodynamic results in the canonical and the microcanonical ensembles has been questioned in some calculations for spin models with long-range interactions. We show that these claims of inequivalence are related to an…

统计力学 · 物理学 2015-01-19 Vera B. Henriques , Silvio R. Salinas

Temperature of a finite-sized system fluctuates due to the thermal fluctuations. However, a systematic mathematical framework for measuring or estimating the temperature is still underdeveloped. Here, we incorporate the estimation theory in…

统计力学 · 物理学 2026-03-17 Shaoyong Zhang , Zhaoyu Fei , Xiaoguang Wang

We present a novel Ensemble Monte Carlo Growth method to sample the equilibrium thermodynamic properties of random chains. The method is based on the multicanonical technique of computing the density of states in the energy space. Such a…

统计力学 · 物理学 2020-03-04 Graziano Vernizzi , Trung Dac Nguyen , Henri Orland , Monica Olvera de la Cruz