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Standard results for the fluctuations of thermodynamic quantities are derived under the assumption of sampling identical systems that are in different, not fully equilibrated states. These results apply to fluctuations with time in a…

介观与纳米尺度物理 · 物理学 2015-05-13 R. A. Serota

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

统计力学 · 物理学 2009-11-13 Alex V. Popov , Rigoberto Hernandez

Classical thermodynamics treats temperature as a state variable characterizing systems in equilibrium with idealized infinite reservoirs. We argue that this framing, while computationally exact, obscures an essential physical reality: any…

量子物理 · 物理学 2026-04-14 David Vaknin

We propose a novel component to the understanding of the temperature structure of galaxy clusters which does not rely on any heating or cooling mechanism. The new ingredient is the use of non-extensive thermo-statistics which is based on…

天体物理学 · 物理学 2007-05-23 Steen H. Hansen

This study shows that the generalized Boltzmann distribution is the only distribution mathematically consistent with thermodynamics when the system is described by an ensemble of a certain mathematical form. This mathematical form is very…

统计力学 · 物理学 2022-02-10 Xiang Gao

Several results of black holes thermodynamics can be considered as firmly founded and formulated in a very general manner. From this starting point we analyse in which way these results may give us the opportunity to gain a better…

广义相对论与量子宇宙学 · 物理学 2009-11-11 J. P. Badiali

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

化学物理 · 物理学 2007-05-23 Elias P. Gyftopoulos

Local Shannon entropy lies at the heart of modern thermodynamics, with much discussion of trajectory-dependent entropy production. When taken at both boundaries of a process in phase space, it reproduces the second law of thermodynamics…

统计力学 · 物理学 2015-01-20 Lee Jinwoo , Hajime Tanaka

In this book, we study Statistical Physics under conditions of thermodynamic equilibrium, starting from the definition of statistical ensembles. The book is divided into five chapters: First, a brief introduction to statistical methods.…

统计力学 · 物理学 2024-03-12 David A. Miranda , Carlos J. Paéz

A thermodynamic model for multifragmentation which is frequently used appears to give very different values for specific heat at constant volume depending upon whether canonical or grand canonical ensemble is used. The cause for this…

核理论 · 物理学 2009-11-10 C. B. Das , S. Das Gupta , A. Z. Mekjian

The unification of relativity and thermodynamics has been a subject of considerable debate over the last 100 years. The reasons for this are twofold: (i) Thermodynamic variables are nonlocal quantities and, thus, single out a preferred…

统计力学 · 物理学 2009-12-18 Jörn Dunkel , Peter Hänggi , Stefan Hilbert

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

化学物理 · 物理学 2009-12-03 Chi-Ho Cheng

According to thermodynamics, the specific heat of Boltzmannian short-range interacting systems is a positive quantity. Less intuitive properties are instead displayed by systems characterized by long-range interactions. In that case, the…

统计力学 · 物理学 2015-05-18 F. Staniscia , A. Turchi , D. Fanelli , P. H. Chavanis , G. De Ninno

Algorithmic entropy can be seen as a special case of entropy as studied in statistical mechanics. This viewpoint allows us to apply many techniques developed for use in thermodynamics to the subject of algorithmic information theory. In…

数学物理 · 物理学 2013-02-27 John C. Baez , Mike Stay

Ensemble inequivalence occurs when a systems thermodynamic properties vary depending on the statistical ensemble used to describe it. This phenomenon is known to happen in systems with long-range interactions and has been observed in many…

统计力学 · 物理学 2026-04-09 Daniel Arrufat-Vicente , David Mukamel , Stefano Ruffo , Nicolo Defenu

All ensembles of statistical mechanics are equivalent in the sense that they give the equivalent thermodynamic functions in the thermodynamic limit. However, when investigating microscopic structures in the first-order phase transition…

统计力学 · 物理学 2019-05-13 Yasushi Yoneta , Akira Shimizu

We propose a method to calculate finite-temperature properties of a quantum many-body system for a microcanonical ensemble by introducing a pure quantum state named here an energy-filtered random-phase state, which is also a potentially…

量子物理 · 物理学 2022-10-06 Kazuhiro Seki , Seiji Yunoki

We show that entropy is globally concave with respect to energy for a rich class of mean field interactions, including regularizations of the the point-vortex model in the plane, plasmas and self-gravitating matter in 2D, as well as the…

数学物理 · 物理学 2022-11-30 Robert J. Berman

We present a statistical mechanical calculation of the thermodynamical properties of (non rotating) isolated horizons. The introduction of Planck scale allows for the definition of an universal horizon temperature (independent of the mass…

广义相对论与量子宇宙学 · 物理学 2015-05-28 Amit Ghosh , Alejandro Perez

Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…

统计力学 · 物理学 2017-09-12 Robert H. Swendsen
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