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We present a method to explore the free energy landscapes of chemical reactions with post-transition-state bifurcations using an enhanced sampling method based on well-tempered metadynamics. Obviating the need for computationally expensive…

化学物理 · 物理学 2023-04-18 Juno Nam , YounJoon Jung

We consider the statistical mechanics of a full set of two-dimensional protein-like heteropolymers, whose thermodynamics is characterized by the coil-to-globular ($T_\theta$) and the folding ($T_f$) transition temperatures. For our model,…

chem-ph · 物理学 2009-10-28 Carlos J. Camacho , D. Thirumalai

We consider the relationship between the temperature at which averaged energy landscape properties change sharply ($T_{o}$), and the breakdown of mean-field treatments of the dynamics of supercooled liquids. First, we show that the solution…

软凝聚态物质 · 物理学 2009-11-10 Yisroel Brumer , David R. Reichman

Nested sampling is a Bayesian sampling technique developed to explore probability distributions lo- calised in an exponentially small area of the parameter space. The algorithm provides both posterior samples and an estimate of the evidence…

生物大分子 · 定量生物学 2015-03-17 Nikolas S. Burkoff , Csilla Varnai , Stephen A. Wells , David L. Wild

An all-atom model of proteins is used to show that the same sequence of amino acids can have many alternative structures, that are very distant from, and that can be as stable as, the corresponding native structure. Such alternative…

生物物理 · 物理学 2008-02-11 Leonor Cruzeiro

I review single-molecule experiments (SME) in biological physics. Recent technological developments have provided the tools to design and build scientific instruments of high enough sensitivity and precision to manipulate and visualize…

软凝聚态物质 · 物理学 2016-08-31 F. Ritort

Temperature Accelerated Sliced Sampling (TASS) is an efficient method to compute high dimensional free energy landscapes. The original TASS method employs the Weighted Histogram Analysis Method (WHAM) which is an iterative post-processing…

计算物理 · 物理学 2021-10-18 Asit Pal , Subhendu Pal , Shivani Verma , Motoyuki Shiga , Nisanth N. Nair

Within the frame of an effective, coarse-grained hydrophobic-polar protein model, we employ multicanonical Monte Carlo simulations to investigate free-energy landscapes and folding channels of exemplified heteropolymer sequences, which are…

软凝聚态物质 · 物理学 2009-11-13 Stefan Schnabel , Michael Bachmann , Wolfhard Janke

A growing number of proteins have been shown to adopt knotted folds. Yet the biological roles and biophysical properties of these knots remain poorly understood. We have used protein engineering and atomic force microscopy to explore…

生物物理 · 物理学 2009-11-13 T. Bornschloegl , D. M. Anstrom , E. Mey , J. Dzubiella , M. Rief , K. T. Forest

We compute the single particle spectral function of a Bose liquid on a lattice, at integer filling, close to the superfluid-Mott transition. We use a `static path approximation' that retains all the classical thermal fluctuations in the…

强关联电子 · 物理学 2017-12-13 Abhishek Joshi , Pinaki Majumdar

We present a unified framework for folding kinetics of proteins and RNA. The basis for this framework relies on the notion of topological frustration, which gives rise to several competing basins of attraction (CBA) in addition to the…

软凝聚态物质 · 物理学 2009-09-25 D. Thirumalai , D. K. Klimov , S. A. Woodson

Configuration transitions of individual molecules and atoms on surfaces are traditionally described with energy barriers and attempt rates using an Arrhenius law. This approach yields consistent energy barrier values, but also attempt rates…

介观与纳米尺度物理 · 物理学 2017-03-03 Jeffrey C. Gehrig , Marcos Penedo , Manfred Parschau , Johannes Schwenk , Miguel A. Marioni , Eric W. Hudson , Hans J. Hug

Exact and approximate expressions for thermodynamic characteristics of heated matter, which consists of particles with finite mass-widths, are constructed. They are expressed in terms of Fermi/Bose distributions and spectral functions,…

核理论 · 物理学 2008-11-26 D. N. Voskresensky

Many aspects of the study of protein folding and dynamics have been affected by the recent advances in machine learning. Methods for the prediction of protein structures from their sequences are now heavily based on machine learning tools.…

生物物理 · 物理学 2019-11-25 Frank Noé , Gianni De Fabritiis , Cecilia Clementi

Nucleosomes form the basic unit of compaction within eukaryotic genomes and their locations represent an important, yet poorly understood, mechanism of genetic regulation. Quantifying the strength of interactions within the nucleosome is a…

生物物理 · 物理学 2016-08-25 Joshua Lequieu , Andres Cordoba , David C. Schwartz , Juan J. de Pablo

In molecular charge transport, transition voltage spectroscopy (TVS) holds the promise that molecular energy levels can be explored at bias voltages lower than required for resonant tunneling. We investigate the theoretical basis of this…

介观与纳米尺度物理 · 物理学 2011-09-09 Fatemeh Mirjani , Joseph M. Thijssen , Sense Jan van der Molen

The thermodynamic properties for three different types of off-lattice four-strand beta-sheet protein models interacting via a hybrid Go-type potential have been investigated. Discontinuous molecular dynamic simulations have been performed…

生物物理 · 物理学 2009-11-07 Hyunbum Jang , Carol K. Hall , Yaoqi Zhou

We illustrate in terms familiar to modern day science students that: (i) an uncertainty slope mechanism underlies the usefulness of temperature via its reciprocal, which is incidentally around 42 [nats/eV] at the freezing point of water;…

物理教育 · 物理学 2008-02-03 P. Fraundorf

We use mesoscopic non-equilibrium thermodynamics theory to describe RNA unfolding under tension. The theory introduces reaction coordinates, characterizing a continuum of states for each bond in the molecule. The unfolding considered is so…

统计力学 · 物理学 2007-09-18 J. M. Rubi , D. Bedeaux , S. Kjelstrup

Optical microscopy provides rich spatio-temporal information characterizing in vivo molecular motion. However, effective forces and other parameters used to summarize molecular motion change over time in live cells due to latent state…

定量方法 · 定量生物学 2015-11-06 Christopher P. Calderon , Kerry S. Bloom