相关论文: The "True" Widom Line for a Square-Well System
We revisit the scaling properties of a model for non-equilibrium wetting [Phys. Rev. Lett. 79, 2710 (1997)], correcting previous estimates of the critical exponents and providing a complete scaling scheme. Moreover, we investigate a special…
Recently there have been significant theoretical advances in our understanding of liquids and dense supercritical fluids based on their ability to support high frequency transverse (shear) waves. Here, we have constructed a new computer…
Following a cell-method due to van Kampen for the calculation of a coarse-grained free energy functional for the van der Waals gas, we compute a corresponding entropy functional from microscopic principles. This entropy functional is one of…
The well-known Maxwell construction[1] (the equal-area rule, EAR) was devised for vapor liquid equilibrium (VLE) calculation with the van der Waals (vdW) equation of state (EoS)[2]. The EAR generates an intermediate volume between the…
Based on the Maxwell relationship and experimental viscosity data, the phonon theory of liquids can provide a temperature-dependent description of liquid heat capacity that is consistent with experimental data. However, since liquid heat…
Using molecular dynamics simulations, we study a liquid model which consists of particles interacting via a spherically-symmetric two-scale Jagla ramp potential with both repulsive and attractive ramps. The Jagla potential displays…
A schematic model is presented that allows one to study the behavior of interacting pseudo-Fermi matter locked in a thermostatic box. As a function of the box volume and temperature, the matter is seen to show all of the familiar…
Despite the technological importance of supercritical fluids, controversy remains about the details of their microscopic dynamics. In this work, we study four supercritical fluid systems -- water, Si, Te, and Lennard-Jones fluid --…
The Curie-Weiss Potts model is a mean field version of the well-known Potts model. In this model, the critical line $\beta = \beta_c (h)$ is explicitly known and corresponds to a first order transition when $q > 2$. In the present paper we…
This article reviews a new and general theory of nonuniform fluids that naturally incorporates molecular scale information into the classical van der Waals theory of slowly varying interfaces. The method optimally combines two standard…
A comparable study of the quantum van der Waals and Walecka models of nuclear matter is presented. Each model contains two parameters which characterize the repulsive and attractive interactions between nucleons. These parameters are fixed…
In this paper, we explore the the phase transition, critical behavior and microstructure of the FRW in the framework of a new higher order generalized uncertainty principle. Our initial step involves deriving the equation of state by…
A model for the radial distribution function $g(r)$ of a square-well fluid of variable width previously proposed [S. B. Yuste and A. Santos, J. Chem. Phys. {\bf 101}, 2355 (1994)] is revisited and simplified. The model provides an explicit…
The thermodynamic behavior of a fluid near a vapor-liquid and, hence, asymmetric critical point is discussed within a general ``complete'' scaling theory incorporating pressure mixing in the nonlinear scaling fields as well as corrections…
The phase diagram of the penetrable square-well fluid is investigated through Monte Carlo simulations of various nature. This model was proposed as the simplest possibility of combining bounded repulsions at short scale and short-range…
The slope of the coexistence line of the liquid-liquid phase transition (LLPT) can be positive, negative, or zero. All three possibilities have been found in Monte-Carlo simulations of a modified spherically symmetric two-scale Jagla model.…
A model of polar fluid is studied theoretically. The interaction potential, in addition to dipole-dipole term, possesses a dispersion contribution of the van der Waals-London form. It is found that when the dispersion force is comparable to…
The problem of a weak shock, reflected and diffracted by a wedge, is studied for the two-dimensional compressible Euler system. Some recent developments are overviewed and a perspective is presented within the context of a real gas, modeled…
Using Monte-Carlo simulation and mean field calculations, we study the liquid-vapour phase diagram of a square well binary fluid mixture as a function of a parameter $\delta$ measuring the relative strength of interactions between particles…
A large and mostly unexplored part of the phase diagram lies above the critical point. The supercritical matter was traditionally believed to be physically homogeneous with no discernible differences between liquidlike and gaslike states.…