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We generalize the model of transition-metal nanocluster growth in aqueous solution, proposed recently [Phys. Rev. E \textbf{87}, 022132 (2013)]. In order to model time evolution of the system, kinetic equations describing time dependence of…

化学物理 · 物理学 2013-11-27 Jakub Jȩdrak

We continue our study of the statistical properties of particles in equilibrium obeying Smoluchowski dynamics. We show that the system is governed by a kinetic equation of the memory function form and that the memory function is given by…

统计力学 · 物理学 2012-05-09 Gene F. Mazenko , David D. McCowan , Paul Spyridis

We report a number of exact solutions for temperature-dependent Smoluchowski equations. These equations quantify the ballistic agglomeration, where the evolution of densities of agglomerates of different size is entangled with the evolution…

统计力学 · 物理学 2022-11-09 Alexander Osinsky , Nikolay Brilliantov

In small systems, quantitative discrepancies between stochastic and deterministic descriptions of chemical kinetics can be significant, with their magnitude depending on the specific reaction network. Here, we study the Finke-Watzky…

化学物理 · 物理学 2025-10-07 Tomasz Bednarek , Jakub Jędrak

We introduce an extended Smoluchowski equation describing coagulation processes for which clusters of mass s grow between collisions with $ds/dt=As^\beta$. A physical example, dropwise condensation is provided, and its collision kernel K is…

统计力学 · 物理学 2009-10-30 Stephane Cueille , Clement Sire

This work outlines an exact combinatorial approach to finite coagulating systems through recursive equations and use of generating function method. In the classic approach the mean-field Smoluchowski coagulation is used. However, the…

统计力学 · 物理学 2021-04-16 Michał Łepek , Paweł Kukliński , Agata Fronczak , Piotr Fronczak

Binary coagulation is an important process in aerosol dynamics by which two particles merge to form a larger one. The distribution of particle sizes over time may be described by the so-called Smoluchowski's coagulation equation. This…

数学物理 · 物理学 2021-06-25 Marina A. Ferreira

We construct a time-dependent solution to the Smoluchowski coagulation equation with a constant flux of dust particles entering through the boundary at zero. The dust is instantaneously converted into particles and flux solutions have…

偏微分方程分析 · 数学 2024-12-11 Marina A. Ferreira , Aleksis Vuoksenmaa

A simple kinematic growth model for muscular arteries is presented which allows the incorporation of residual stresses such that a homeostatic in-vivo stress state under physiological loading is obtained. To this end, new evolution…

定量方法 · 定量生物学 2025-02-28 Klemens Uhlmann , Daniel Balzani

We analyzed the stochastic behavior of systems controlled by autocatalytic reaction A+X -> X+X, X+X -> A+X, X -> B provided that the distribution of reacting particles in the system volume is uniform, i.e. the point model of reaction…

统计力学 · 物理学 2016-08-31 L. Pal

The exact solution of the kinetic equation of the one step process of a growth (birth) in the presence of sources (runs-off) is found for arbitrary dependence of the rate of the growth on the number of the state (or size). It is shown that…

统计力学 · 物理学 2013-08-14 Ikhtier Umirzakov

Reactions in solution require "contact" between the reagents. We can predict the rate at which reagents come into "contact" (at least in dilute conditions), but if the initial collision does not lead to reaction, what happens then? The…

化学物理 · 物理学 2024-07-30 Manuel Dedola , Gaia Cassarà-Airoldi , Ludovico Cademartiri

We introduce an autocatalytic aggregation model in which the rate at which two clusters merge to form a cluster is controlled by the presence of a third "catalytic" cluster whose mass must equal to the mass of one of the reaction partners.…

统计力学 · 物理学 2025-01-14 P. L. Krapivsky , S. Redner

The steady-state nucleation rate and flux of composite nucleus at the saddle point is studied by extending the theory of binary nucleation. The Fokker-Planck equation that describes the nucleation flux is derived using the Master equation…

材料科学 · 物理学 2015-06-05 Masao Iwamatsu

Using the formalism of the classical nucleation theory, we derive a novel kinetic equation for the size and composition distribution of an ensemble of aqueous organic aerosols, evolving via nucleation and concomitant chemical aging. This…

大气与海洋物理 · 物理学 2020-07-01 Yuri S. Djikaev , Eli Ruckenstein

A modeling framework for the internal conformational dynamics and external mechanical movement of single biological macromolecules in aqueous solution at constant temperature is developed. Both the internal dynamics and external movement…

生物物理 · 物理学 2007-05-23 Hong Qian

The processes of simultaneous coagulation and Ostwald ripening of particles in the concluding stage of phase transformation are considered. We solve the integro-differential system of Smoluchowski-type kinetic and mass balance equations…

In this article we study an extension of Smoluchowski's discrete coagulation equation, where particle in- and output takes place. This model is frequently used to describe aggregation processes in combination with sedimentation of clusters.…

数学物理 · 物理学 2018-01-10 Christian Kuehn , Sebastian Throm

Self-accelerating solutions in massive gravity provide explicit, calculable examples that exhibit the general interplay between superluminality, the well-posedness of the Cauchy problem, and strong coupling. For three particular classes of…

高能物理 - 理论 · 物理学 2015-08-26 Pavel Motloch , Wayne Hu , Austin Joyce , Hayato Motohashi

We study the self-similar behavior of the exchange-driven growth model, which describes a process in which pairs of clusters, consisting of an integer number of monomers, interact through the exchange of a single monomer. The rate of…

偏微分方程分析 · 数学 2021-03-18 Constantin Eichenberg , André Schlichting
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