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We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

统计力学 · 物理学 2020-10-13 Jianzhong Wu

Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of…

统计力学 · 物理学 2007-05-23 Sumiyoshi Abe

Starting from microscopic mechanics, we derive thermodynamic relations for heat conducting nonequilibrium steady states. The extended Clausius relation enables one to experimentally determine nonequilibrium entropy to the second order in…

统计力学 · 物理学 2009-11-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…

统计力学 · 物理学 2013-02-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

In his ninth memoir Clausius summarizes the two principles of thermodynamics as follows: "The whole mechanical theory of heat rests on two fundamental theorems: that of equivalence of heat and work, and that of equivalence of…

统计力学 · 物理学 2023-06-08 Giovanni Jona-Lasinio

A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…

统计力学 · 物理学 2019-02-04 David M. Rogers , Susan B. Rempe

Generalizing a recent work [T. Taniguchi and E. G. D. Cohen, J. Stat. Phys. 126, 1 (2006)] that was based on the Onsager-Machlup theory, a nonlinear relaxation process is considered for a macroscopic thermodynamic quantity. It is found that…

统计力学 · 物理学 2009-11-13 Yuki Sughiyama , Sumiyoshi Abe

We present a simple derivation of the integral fluctuation theorems for excess housekeeping heat for an underdamped Langevin system, without using the concept of dual dynamics. In conformity with the earlier results, we find that the…

统计力学 · 物理学 2016-01-07 Sourabh Lahiri , A. M. Jayannavar

We extend the canonical Gibbs distribution, originally formulated for systems at equilibrium, to systems driven out of equilibrium. The stochastic dynamics of a small system are described by a probability distribution over discrete energy…

统计力学 · 物理学 2026-03-31 Jean-Luc Garden

Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…

统计力学 · 物理学 2015-06-17 Shin-ichi Sasa

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

量子物理 · 物理学 2026-03-26 Gian Paolo Beretta

We use a relationship between response and correlation function in nonequilibrium systems to establish a connection between the heat production and the deviations from the equilibrium fluctuation-dissipation theorem. This scheme extends the…

统计力学 · 物理学 2014-04-11 E. Lippiello , M. Baiesi , A. Sarracino

We develop non-equilibrium theory by using averages in time and space as a generalized way to upscale thermodynamics in non-ergodic systems. The approach offers a classical perspective on the energy dynamics in fluctuating systems. The rate…

软凝聚态物质 · 物理学 2021-09-29 James E. McClure , Steffen Berg , Ryan T. Armstrong

We present a general framework for systems which are prepared in a non-stationary non-equilibrium state in the absence of any perturbation, and which are then further driven through the application of a time-dependent perturbation. We…

统计力学 · 物理学 2012-12-06 Gatien Verley , David Lacoste

A generalization of the Onsager-Machlup theory from equilibrium to nonequilibrium steady states and its connection with recent fluctuation theorems are discussed for a dragged particle restricted by a harmonic potential in a heat reservoir.…

统计力学 · 物理学 2007-05-23 Tooru Taniguchi , E. G. D. Cohen

Recently, in their attempt to construct steady state thermodynamics (SST), Komatsu, Nakagwa, Sasa, and Tasaki found an extension of the Clausius relation to nonequilibrium steady states in classical stochastic processes. Here we derive a…

统计力学 · 物理学 2015-05-28 Keiji Saito , Hal Tasaki

We study nonequilibrium fluctuation theorems in the presence of a time-reversal symmetry-breaking field and nonconservative forces, in a stochastic as well as a deterministic set up. We consider a system and a heat bath, called the combined…

统计力学 · 物理学 2010-02-22 Punyabrata Pradhan

Starting from the most general formulation of stochastic thermodynamics---i.e. a thermodynamically consistent nonautonomous stochastic dynamics describing systems in contact with several reservoirs---, we define a procedure to identify the…

统计力学 · 物理学 2018-02-07 Riccardo Rao , Massimiliano Esposito

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

We extend Onsager's minimum dissipation principle to stationary states that are only subject to local equilibrium constraints, even when the transport coefficients depend on the thermodynamic forces. Crucial to this generalization is a…

统计力学 · 物理学 2023-07-19 Giorgio Sonnino , Jarah Evslin , Alberto Sonnino
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