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The electronic excitations of manganese phthalocyanine (MnPc) films were studied as a function of potassium doping using electron energy-loss spectroscopy in transmission. Our data reveal doping induced changes in the excitation spectrum,…

材料科学 · 物理学 2011-05-20 Benjamin Mahns , Friedrich Roth , Mandy Grobosch , Dietrich R. T. Zahn , Martin Knupfer

We have investigated the evolution of the temperature-dependent conductivity of electron-doped pentacene (PEN) thin films, in which the electron density is controlled by means of potassium (K) intercalation. We find that the conductivity is…

强关联电子 · 物理学 2007-05-23 M. F. Craciun , S. Rogge , A. F. Morpurgo

We performed electron energy-loss spectroscopy studies in order to get a deeper insight into the electronic properties of potassium intercalated picene, a recently discovered superconductor. A comparison of the loss function of the undoped…

超导电性 · 物理学 2011-04-05 Friedrich Roth , Benjamin Mahns , Bernd Büchner , Martin Knupfer

We investigate electronic transport through pentacene thin-films intercalated with potassium. From temperature-dependent conductivity measurements we find that potassium-intercalated pentacene shows metallic behavior in a broad range of…

强关联电子 · 物理学 2009-03-31 M. F. Craciun , G. Giovannetti , S. Rogge , G. Brocks , A. F. Morpurgo , J. van den Brink

The electronic excitation spectra of undoped, and potassium as well as calcium doped phenantrene-type hydrocarbons have been investigated using electron energy-loss spectroscopy (EELS) in transmission. In the undoped materials, the lowest…

材料科学 · 物理学 2015-02-26 Friedrich Roth , Martin Knupfer

We performed electron energy-loss spectroscopy studies in transmission in order to obtain insight into the electronic properties of potassium intercalated coronene, a recently discovered superconductor with a rather high transition…

超导电性 · 物理学 2012-01-20 Friedrich Roth , Johannes Bauer , Benjamin Mahns , Bernd Büchner , Martin Knupfer

Potassium (K) intercalated manganese phthalocyanine (MnPc) reveals vast changes of its electronic states close to the Fermi level. However, theoretical studies are controversial regarding the electronic configuration. Here, MnPc doped with…

In strongly correlated transition metal dichalcogenides, an intricate interplay of polaronic distortions, stacking arrangement, and electronic correlations determines the nature of the insulating state. Here, we study the response of the…

By the first principles calculations and X-ray diffraction simulations, we perform a systematic study of multiple superconducting phases of potassium-doped picene [Nature {\bf464} 76, 2010]. The combination of optimized lattice parameters,…

超导电性 · 物理学 2014-07-04 Xun-Wang Yan , Zhongbing Huang , Hai-Qing Lin

The electronic structure of the unoccupied and occupied states of potassium (K)-doped and undoped picene crystalline films has been investigated by using the element-selective and bulk-sensitive photon-detection methods of X-ray absorption…

材料科学 · 物理学 2012-10-16 Hiroyuki Yamane , Nobuhiro Kosugi

We report an insulator-metal-insulator transition in films of five metal phthalocyanines (MPc) doped with alkali atoms. Electrical conduction measurements demonstrate that increasing the alkali concentration results in the formation of a…

其他凝聚态物理 · 物理学 2007-05-23 M. F. Craciun , S. Rogge , M. J. L. den Boer , S. Margadonna , K. Prassides , Y. Iwasa , A. F. Morpurgo

Recent work applying multidimentional coherent electronic spectroscopy at dilute samples in the gas phase is reviewed. The development of refined phase-cycling approaches with improved sensitivity has opened-up new opportunities to probe…

原子与分子团簇 · 物理学 2019-09-12 Lukas Bruder , Ulrich Bangert , Marcel Binz , Daniel Uhl , Frank Stienkemeier

We report a set of adiabatic potential energy surfaces (PESs) for diiodomethane, including the ground electronic state and all excited states accessible via single-photon absorption near 260 nm. Although constrained to four dimensions,…

化学物理 · 物理学 2026-02-26 Yijue Ding

We present precision measurements with MHz uncertainty of the energy gap between asymptotic and well bound levels in the electronic ground state X $^1\Sigma_{\mathrm{g}}^+$ of the $^{39}$K$_2$ molecule. The molecules are prepared in a…

Synthesis methodology for flakes of p-terphenyl through sublimation under inert atmosphere of argon is presented. Flake morphology of p-terphenyl provides a favourable environment for efficient intercalation of potassium. Ratio of potassium…

超导电性 · 物理学 2018-09-26 P. Neha , V. Sahu , S. Patnaik

Chemiluminescence in 1,2-dioxetane occurs through a thermally activated decomposition reaction into two formaldehyde molecules. Both ground-state and nonadiabatic dynamics (including singlet excited states) of the decomposition reaction…

The electronic structure of the conjugated polymer, polyaniline, has been studied by resonant and nonresonant X-ray emission spectroscopy using synchrotron radiation for the excitation. The measurements were made on polyaniline and a few…

材料科学 · 物理学 2012-01-05 M. Magnuson , J. -H. Guo , S. M. Butorin , A. Agui , C. Såthe , J. Nordgren , A. P. Monkman

We present electron energy-loss spectroscopic measurements of potassium (K) intercalated tungsten diselenide (WSe2). After exposure of pristine WSe2 films to potassium, we observe a charge carrier plasmon excitation at about 0.97 eV, which…

介观与纳米尺度物理 · 物理学 2017-04-05 M. Ahmad , E. Müller , C. Habenicht , R. Schuster , M. Knupfer , B. Büchner

We have studied potassium-intercalated bulk HfS$_2$ and HfSe$_2$ by combining transmission electron energy loss spectroscopy, angle-resolved photoemission spectroscopy and density functional theory calculations. Calculations of the…

介观与纳米尺度物理 · 物理学 2020-07-01 Carsten Habenicht , Jochen Simon , Manuel Richter , Roman Schuster , Martin Knupfer , Bernd Büchner

We present optical absorption spectra of mixed films of pentacene (PEN) and perfluoropentacene (PFP) grown on SiO2. We investigated the influence of intermolecular coupling between PEN and PFP on the optical spectra by analyzing samples…

材料科学 · 物理学 2011-06-22 K. Broch , U. Heinemeyer , A. Hinderhofer , F. Anger , R. Scholz , A. Gerlach , F. Schreiber
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