相关论文: Ehrenfest dynamics is purity non-preserving: a nec…
A model based on the classic non-interacting Ehrenfest urn model with two-urns is generalized to $M$ urns with the introduction of interactions for particles within the same urn. As the inter-particle interaction strength is varied, phases…
Quantum and classical systems evolving under the same formal Hamiltonian $H$ may dramatically differ after the Ehrenfest timescale $t_E \sim \log(\hbar^{-1})$, even as $\hbar \to 0$. Coupling the system to a Markovian environment results in…
The Ehrenfest time scale in quantum transport separates essentially classical propagation from wave interference and here we consider its effect on the transmission and reflection through quantum dots. In particular we calculate the…
Dissipation and decoherence, and the evolution from pure to mixed states in quantum physics are handled through master equations for the density matrix. Master equations such as the Lindblad equation preserve the trace of this matrix.…
The computational challenges posed by many-particle quantum systems are often overcome by mixed quantum-classical (MQC) models in which certain degrees of freedom are treated as classical while others are retained as quantum. One of the…
We review properties of open chaotic mesoscopic systems with a finite Ehrenfest time tau_E. The Ehrenfest time separates a short-time regime of the quantum dynamics, where wave packets closely follow the deterministic classical motion, from…
Ehrenfest urns with interaction that are connected in a ring is considered as a paradigm model for non-equilibrium thermodynamics and is shown to exhibit two distinct non-equilibrium steady states (NESS) of uniform and non-uniform particle…
We derive the fundamental equations of an optimal control theory for systems containing both quantum electrons and classical ions. The system is modeled with Ehrenfest dynamics, a non-adiabatic variant of molecular dynamics. The general…
A long-standing challenge in mixed quantum-classical trajectory simulations is the treatment of entanglement between the classical and quantal degrees of freedom. We present a novel approach which describes the emergence of entangled states…
We investigate the role of a statistical complexity measure to assign equilibration in isolated quantum systems. While unitary dynamics preserve global purity, expectation values of observables often exhibit equilibration-like behavior,…
We have derived equations for nonadiabatic Ehrenfest molecular dynamics which conserve the total energy in the case of time-dependent discretization for electrons. A discretization is time-dependent in all cases where it or part of it…
Two-dimensional electronic spectroscopy (2DES) provides a detailed picture of electronically nonadiabatic dynamics that can be interpreted with the aid of simulations. Here, we develop and contrast trajectory-based nonadiabatic dynamics…
We study the quantum dynamics generated by the repeated action of a non-unitary evolution operator on a system of qubits. Breaking unitarity can lead to the purification of mixed initial states, which corresponds to the loss of sensitivity…
We investigate quantum dynamical systems defined on a finite dimensional Hilbert space and subjected to an interaction with an environment. The rate of decoherence of initially pure states, measured by the increase of their von Neumann…
We consider the interaction dynamics of a classical oscillator and a quantum two-level system for different pure-dephasing Hamiltonians of the type $\widehat{H}(q,p)=H_C(q,p)\boldsymbol{1}+H_I(q,p)\widehat\sigma_z$. This type of systems…
Quantum path interferences or resonances in multilevel dissipative quantum systems play an important and intriguing role in the transport processes of nanoscale systems. Many previous minimalistic models used to describe the quantum path…
We investigate detailed balance for a quantum system interacting with thermal radiation within mixed quantum-classical theory. For a two-level system coupled to classical radiation fields, three semiclassical methods are benchmarked: (1)…
In quantum information theory, quantum discord has been proposed as a tool to characterise the presence of "quantum correlations" between the subparts of a given system. Whether a system behaves quantum-mechanically or classically is…
Nonadiabatic transition dynamics lies at the core of many electron/hole transfer, photoactivated, and vacuum field-coupled processes. About a century after Ehrenfest proposed "Phasenraum" and the Ehrenfest theorem, we report a conceptually…
Linear and nonlinear electronic spectra provide an important tool to probe the absorption and transfer of electronic energy. Here we introduce a pure state Ehrenfest approach to obtain accurate linear and nonlinear spectra that is…