相关论文: Scott correction for large atoms and molecules in …
We consider a large neutral molecule with total nuclear charge $Z$ in a model with self-generated classical magnetic field and where the kinetic energy of the electrons is treated relativistically. To ensure stability, we assume that $Z…
We consider a large atom with nuclear charge $Z$ described by non-relativistic quantum mechanics with classical or quantized electromagnetic field. We prove that the absolute ground state energy, allowing for minimizing over all possible…
We provide a proof of the first correction to the leading asymptotics of the minimal energy of pseudo-relativistic molecules in the presence of magnetic fields, the so-called "relativistic Scott correction", when $\max{Z_k\alpha} \leq…
The purpose of this paper is to derive sharp asymptotics of the ground state energy for the heavy atoms and molecules in the relativistic settings, with the self-generated magnetic field, and, in particular, to derive relativistic Scott…
We consider relativistic many-particle operators which - according to Brown and Ravenhall - describe the electronic states of heavy atoms. Their ground state energy is investigated in the limit of large nuclear charge and velocity of light.…
This paper is divided into two parts. In the first one the von Weizs\"acker term is introduced to the Magnetic TF theory and the resulting MTFW functional is mathematically analyzed. In particular, it is shown that the von Weizs\"acker term…
We prove the first correction to the leading Thomas-Fermi energy for the ground state energy of atoms and molecules in a model where the kinetic energy of the electrons is treated relativistically. The leading Thomas-Fermi energy,…
We consider the semiclassical asymptotics of the sum of negative eigenvalues of the three-dimensional Pauli operator with an external potential and a self-generated magnetic field $B$. We also add the field energy $\beta \int B^2$ and we…
We describe atoms by a pseudo-relativistic model that has its origin in the work of Chandrasekhar. We prove that the leading energy correction for heavy atoms, the Scott correction, exists. It turns out to be lower than in the…
The quantum mechanical ground state of a 2D $N$-electron system in a confining potential $V(x)=Kv(x)$ ($K$ is a coupling constant) and a homogeneous magnetic field $B$ is studied in the high density limit $N\to\infty$, $K\to \infty$ with…
Let E(B,Z,N) denote the ground state energy of an atom with N electrons and nuclear charge Z in a homogeneous magnetic field B. We study the asymptotics of E(B,Z,N) as $B\to \infty$ with N and Z fixed but arbitrary. It is shown that the…
In this paper we study the large-Z behaviour of the ground state energy of atoms with electrons having relativistic kinetic energy sqrt(p^2c^2+m^2c^4)-mc^2. We prove that to leading order in Z the energy is the same as in the…
The purpose of this paper is to derive sharp asymptotics of the ground state energy for the heavy atoms and molecules in the relativistic settings, and, in particular, to derive relativistic Scott correction term and also Dirac, Schwinger…
We give the first derivation of the Scott correction in the large-$Z$ expansion of the energy of an atom in Dirac-Fock theory without projections.
We consider asymptotics of the ground state energy of heavy atoms and molecules in the self-generatedl magnetic field. Namely, we consider $$ H=((D-A)\cdot\boldsymbol{\sigma})^2-V $$ with $$V=\sum_{1\le m\le M} \frac{Z_m}{|x-y_m|}$$ and a…
We consider the grand canonical pressure for Coulombic matter with nuclear charges $\sim Z$ in a magnetic field $B$ and at nonzero temperature. We prove that its asymptotic limit as $Z\to\infty$ with $B/Z^3\to 0$ can be obtained by…
The moving neutral system of two Coulomb charges on a plane subject to a constant magnetic field $B$ perpendicular to the plane is considered. It is shown that the composite system of finite total mass is bound for any center-of-mass…
We consider a non-relativistic two-dimensional (2D) hydrogen-like atom in a weak, static, uniform magnetic field perpendicular to the atomic plane. Within the framework of the Rayleigh-Schr\"odinger perturbation theory, using the Sturmian…
We consider non-interacting particles subject to a fixed external potential $V$ and a self-generated magnetic field $B$. The total energy includes the field energy $\beta \int B^2$ and we minimize over all particle states and magnetic…
In the limit of large nuclear charge, $Z\gg 1$, or small lepton velocity, $\beta \ll 1$, Coulomb corrections to nuclear beta decay and related processes are enhanced as $Z\alpha/\beta$ and become large or even non-perturbative (with…