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Recent large-scale computer simulations suggest that it may be possible to create a new class of soft solids, called `bijels', by stabilizing and arresting the bicontinuous interface in a binary liquid demixing via spinodal decomposition…

软凝聚态物质 · 物理学 2007-12-14 E. M. Herzig , K. A. White , A. B. Schofield , W. C. K. Poon , P. S. Clegg

Colloidal particles with appropriate wetting properties can become very strongly trapped at an interface between two immiscible fluids. We have harnessed this phenomenon to create a new class of soft materials with intriguing and…

软凝聚态物质 · 物理学 2009-11-13 K. A. White , A. B. Schofield , B. P. Binks , P. S. Clegg

We present examples of bicontinuous interfacially jammed emulsion gels ("bijels") with a designed gradient in the channel size along the sample. These samples are created by quenching binary fluids which have a gradient in particle…

软凝聚态物质 · 物理学 2022-03-28 David J. French , Andrew B. Schofield , Job H. J. Thijssen

Porous materials possess numerous useful functions because of their high surface area and ability to modulate the transport of heat, mass, fluids, and electromagnetic waves. Unlike highly ordered structures, disordered porous structures…

软凝聚态物质 · 物理学 2022-11-21 Tiancheng Wang , Robert A. Riggleman , Daeyeon Lee , Kathleen J. Stebe

Nanostructured materials formed via kinetically controlled self-assembly processes gather more interest nowadays. Bicontinuous emulsion gels stabilized by colloidal particles, called bijels, are attractive materials in soft-matter as they…

Bicontinuous Pickering emulsions (bijels) are a physically interesting class of soft materials with many potential applications including catalysis, microfluidics and tissue engineering. They are created by arresting the spinodal…

软凝聚态物质 · 物理学 2022-03-07 M. Reeves , J. H. J. Thijssen

We demonstrate that the formation of bicontinuous emulsions stabilized by interfacial particles (bijels) is more robust when nanoparticles rather than microparticles are used. Emulsification via spinodal demixing in the presence of nearly…

软凝聚态物质 · 物理学 2015-09-30 M. Reeves , A. T. Brown , A. B. Schofield , M. E. Cates , J. H. J. Thijssen

Using controlled spinodal decomposition, we have created a fluid-bicontinuous structure stabilized by colloidal particles. We present confocal microscopy studies of these structures and their variation with kinetic pathway. Our studies…

Carefully tuned composite materials can have properties wholly unlike their separate constituents. We review the development of one example: colloid-stabilized emulsions with bicontinuous liquid domains. These non-equilibrium structures…

软凝聚态物质 · 物理学 2008-02-25 P. S. Clegg

Particle-stabilised emulsions are a cornerstone of soft matter science due to their broad application and fundamental relevance. Computer simulations provide key insights into the formation and behaviour of these emulsions, yet current…

软凝聚态物质 · 物理学 2026-02-19 Elisabeth C. Eij , Joost de Graaf , Martin F. Haase , Jesse M. Steenhoff

We use lattice Boltzmann simulations to investigate the formation of arrested structures upon demixing of a binary solvent containing neutrally wetting colloidal particles. Previous simulations for symmetric fluid quenches pointed to the…

软凝聚态物质 · 物理学 2008-04-03 E. Kim , K. Stratford , R. Adhikari , M. E. Cates

We investigated the formation of cocontinuous structures in polymer blends. These polymeric bijels (bicontinuous interfacially jammed emulsion gels) were composed of polystyrene oligomer, polybutene and fluorescent hydrophobic silica…

软凝聚态物质 · 物理学 2015-02-03 Lian Bai , John Fruehwirth , Xiang Cheng , Christopher W. Macosko

Colloidal particles or nanoparticles, with equal affinity for two fluids, are known to adsorb irreversibly to the fluid-fluid interface. We present large-scale computer simulations of the demixing of a binary solvent containing such…

软凝聚态物质 · 物理学 2007-05-23 K. Stratford , R. Adhikari , I. Pagonabarraga , J. -C. Desplat , M. E. Cates

Particle stabilized emulsions are ubiquitous in the food and cosmetics industry, but our understanding of the influence of microscopic fluid-particle and particle-particle interactions on the macroscopic rheology is still limited. In this…

软凝聚态物质 · 物理学 2015-03-14 Fabian Jansen , Jens Harting

We present a confocal-microscopy study of demixing and remixing in binary liquids containing colloidal particles. First, particle-stabilized emulsions have been fabricated by nucleation and growth of droplets upon cooling from the…

软凝聚态物质 · 物理学 2015-03-19 Job H. J. Thijssen , Paul S. Clegg

We present a quantitative confocal-microscopy study of the transient and final microstructure of particle-stabilised emulsions formed via demixing in a binary liquid. To this end, we have developed an image-analysis method that relies on…

软凝聚态物质 · 物理学 2010-11-04 Job H J Thijssen , Paul S Clegg

Magnetic gels with embedded micro/nano-sized magnetic particles in crosslinked polymer networks can be actuated by external magnetic fields, with changes in their internal microscopic structures and macroscopic mechanical properties. We…

软凝聚态物质 · 物理学 2024-03-21 Xuefeng Wei , Gaspard Junot , Ramin Golestanian , Xin Zhou , Yanting Wang , Pietro Tierno , Fanlong Meng

Colloidal gels are widely applied in industry due to their rheological character -- no flow takes place below the yield stress. Such property enables gels to maintain uniform distribution in practical formulations; otherwise, solid…

软凝聚态物质 · 物理学 2023-05-17 Yujie Jiang , Ryohei Seto

Ferrogels, i.e., hydrogels loaded with magnetic nanoparticles, have the ability to deform in external magnetic fields. The precise shape of deformation and the alignment of the gel in the field, however, depend on the interplay of several…

软凝聚态物质 · 物理学 2017-04-24 Rudolf Weeber , Christian Holm

We explore the influence of particle softness and internal structure on both the bulk and interfacial rheological properties of colloidal suspensions. We probe bulk stresses by conventional rheology, by measuring the flow curves, shear…

软凝聚态物质 · 物理学 2015-05-20 Domenico Truzzolillo , Valentin Roger , Christelle Dupas , Serge Mora , Luca Cipelletti
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