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We report phonon renormalisation in bilayer graphene as a function of doping. The Raman G peak stiffens and sharpens for both electron and hole doping, as a result of the non-adiabatic Kohn anomaly at the $\Gamma$ point. The bilayer has two…

介观与纳米尺度物理 · 物理学 2015-05-13 A. Das , B. Chakraborty , S. Piscanec , S. Pisana , A. K. Sood , A. C. Ferrari

Raman spectroscopy is a fast, non-destructive means to characterize graphene samples. In particular, the Raman spectra show a significant dependence on doping. While the change in position and width of the G peak can be explained by the…

材料科学 · 物理学 2015-05-13 D. M. Basko , S. Piscanec , A. C. Ferrari

We have investigated the effects of ozone treatment on graphene by Raman scattering. Sequential ozone short-exposure cycles resulted in increasing the $p$ doping levels as inferred from the blue shift of the 2$D$ and $G$ peak frequencies,…

介观与纳米尺度物理 · 物理学 2015-05-19 F. Alzina , H. Tao , J. Moser , Y. Garcia , A. Bachtold , C. M. Sotomayor-Torres

We present a new way to tune the electron-phonon coupling (EPC) in graphene by changing the deformation potential with electron/hole doping. We show the EPC for highest optical branch at the high symmetry point K, acquires a strong…

材料科学 · 物理学 2011-05-03 Claudio Attaccalite , Ludger Wirtz , Michele Lazzeri , Francesco Mauri , Angel Rubio

Graphene is known as the strongest 2D material in nature, yet we show that moderate charge doping of either electrons or holes can further enhance its ideal strength by up to ~17%, based on first principles calculations. This unusual…

材料科学 · 物理学 2015-06-11 Chen Si , Wenhui Duan , Zheng Liu , Feng Liu

We investigate the many-body properties of graphene on top of a piezoelectric substrate, focusing on the interaction between the graphene electrons and the piezoelectric acoustic phonons. We calculate the electron and phonon self-energies…

介观与纳米尺度物理 · 物理学 2017-09-20 D. G. González , I. Zapata , J. Schiefele , F. Sols , F. Guinea

We compute, from first-principles, the frequency of the E2g, Gamma phonon (Raman G-band) of graphene, as a function of the charge doping. Calculations are done using i) the adiabatic Born-Oppenheimer approximation and ii) time-dependent…

介观与纳米尺度物理 · 物理学 2007-05-23 Michele Lazzeri , Francesco Mauri

We study the effects of metallic doping on the electronic properties of graphene using density functional theory in the local density approximation in the presence of a local charging energy (LDA+U). The electronic properties are sensitive…

材料科学 · 物理学 2009-11-13 B. Uchoa , C. -Y. Lin , A. H. Castro Neto

We report a Raman spectroscopy study of graphene field-effect transistors (GFET) with a controlled amount of defects introduced in graphene by exposure to electron-beam irradiation. Raman spectra are taken at T = 8 K over a range of back…

材料科学 · 物理学 2015-06-22 Isaac Childres , Luis A. Jauregui , Yong P. Chen

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

We use first-principles density-functional calculations to determine the frequency shift of the A$'_1$-${\bf K}$ phonon (Raman D band) in monolayer graphene, as a function of the charge doping. A detailed DFT study on the electron-phonon…

材料科学 · 物理学 2007-05-23 Srijan Kumar Saha , U. V. Waghmare , H. R. Krishnamurthy , A. K. Sood

We point out that plasmons in doped graphene simultaneously enable low-losses and significant wave localization for frequencies below that of the optical phonon branch $\hbar\omega_{Oph}\approx 0.2$ eV. Large plasmon losses occur in the…

介观与纳米尺度物理 · 物理学 2015-05-14 Marinko Jablan , Hrvoje Buljan , Marin Soljačić

We have investigated antidot lattices, which were prepared on exfoliated graphene single layers via electron-beam lithography and ion etching, by means of scanning Raman spectroscopy. The peak positions, peak widths and intensities of the…

介观与纳米尺度物理 · 物理学 2011-07-01 S. Heydrich , M. Hirmer , C. Preis , T. Korn , J. Eroms , D. Weiss , C. Schüller

We achieve fine tuning of graphene effective doping by applying ultrahigh pressures (> 10 GPa) using Atomic Force Microscopy (AFM) diamond tips. Specific areas in graphene flakes are irreversibly flattened against a SiO2 substrate. Our work…

We demonstrate electrochemical top gating of graphene by using a solid polymer electrolyte. This allows to reach much higher electron and hole doping than standard back gating. In-situ Raman measurements monitor the doping. The G peak…

Ab-initio calculations based on density functional theory (DFT) have been performed to study the optical properties of pure graphene and have been compared to that of individual boron (B), nitrogen (N) and BN co-doped graphene sheet. The…

介观与纳米尺度物理 · 物理学 2020-05-22 Pooja Rani , Girija S Dubey , V. K. Jindal

Here we use pristine graphene samples in order to analyze how the Raman peaks intensity, measured at 2.4 eV and 1.96 eV excitation energy, changes with the amount of doping. The use of pristine graphene allows investigating the intensity…

介观与纳米尺度物理 · 物理学 2015-05-14 C. Casiraghi

We observe a giant increase of the infrared intensity and a softening of the in-plane antisymmetric phonon mode Eu (~0.2 eV) in bilayer graphene as a function of the gate-induced doping. The phonon peak has a pronounced Fano-like asymmetry.…

Ab-initio calculations have been performed to study the geometry and electronic structure of boron (B) and nitrogen (N) doped graphene sheet. The effect of doping has been investigated by varying the concentrations of dopants from 2 % (one…

介观与纳米尺度物理 · 物理学 2012-09-25 Pooja Rani , V. K. Jindal

An experimental study of Raman scattering in N-layer graphene as a function of the top layer doping is reported. At high doping level, achieved by a CHF_3 plasma treatment, we observe a splitting of the $G$ band in the spectra of bilayer…

介观与纳米尺度物理 · 物理学 2010-03-23 M. Bruna , S. Borini
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