相关论文: Quantum Fermi's Golden Rule
We shall revisit the conventional adiabatic or Markov approximation, which --contrary to the semiclassical case-- does not preserve the positive-definite character of the corresponding density matrix, thus leading to highly non-physical…
We present and discuss a general density-matrix description of energy-dissipation and decoherence phenomena in open quantum systems, able to overcome the intrinsic limitations of the conventional Markov approximation. In particular, the…
We propose a new quantum transition-state theory for calculating Fermi's golden-rule rates in complex multidimensional systems. This method is able to account for the nuclear quantum effects of delocalization, zero-point energy and…
Fermi's Golden Rule (FGR) applies in the limit where an initial quantum state is weakly coupled to a {\it continuum} of other final states overlapping its energy. Here we investigate what happens away from this limit, where the set of final…
We obtain new types of exponential decay laws for solutions of density-matrix master equations in the weak-coupling limit: after comparing with results already present in the literature and developing the necessary techniques, we study the…
Fermi's golden rule describes the leading-order behaviour of the reaction rate as a function of the diabatic coupling. Its asymptotic $(\hbar \rightarrow 0)$ limit is the semiclassical golden-rule instanton rate theory, which rigorously…
Quantum systems with chaotic classical counterparts cannot be treated by perturbative techniques or any kind of adiabatic approximations. This is so, in spite of the quantum suppression of classical chaos. We explicitly calculate the…
We develop from first principles Markovian master equations suited for studying the time evolution of a system evolving adiabatically while coupled weakly to a thermal bath. We derive two sets of equations in the adiabatic limit, one using…
A novel and readily understandable derivation of the Golden Rule of time dependent perturbation theory is presented. The derivation is based on adiabatic turning on of the perturbation as used, for instance, in some formal developments of…
Classical and quantum phase transitions involve observables which are non-analytic as functions of a controlled thermodynamical variable. As occurs with the self-consistent Fermi Golden Rule, one condition to obtain the discontinuous…
Non-adiabatic decay rates for a radio-frequency dressed magnetic trap are calculated using Fermi's Golden Rule: that is, we examine the probability for a single atom to make transitions out of the dressed trap and into a continuum in the…
The adiabatic particle number in mean field theory obeys a quantum Vlasov equation which is nonlocal in time. For weak, slowly varying electric fields this particle number can be identified with the single particle distribution function in…
We present an approach for carrying out non-adiabatic molecular dynamics simulations of systems in which non-adiabatic transitions arise from the coupling between the classical atomic motions and a quasi-continuum of electronic quantum…
Fermi's golden rule applies to a situation in which a single quantum state $|\psi\rangle$ is coupled to a near-continuum. This "quasi-continuum coupling" structure results in a rate equation for the population of $|\psi\rangle$. Here we…
We study, analytically and numerically, the stability of quantum motion for a classically chaotic system. We show the existence of different regimes of fidelity decay which deviate from Fermi Golden rule and Lyapunov decay.
Adiabatic evolution is an emergent design principle for time modulated metamaterials, often inspired by insights from topological quantum computing such as braiding operations. However, the pursuit of classical adiabatic metamaterials is…
We generalize the adiabatic approximation to the case of open quantum systems, in the joint limit of slow change and weak open system disturbances. We show that the approximation is ``physically reasonable'' as under wide conditions it…
Fermi's golden rule is of great importance in quantum dynamics. However, in many textbooks on quantum mechanics, its contents and limitations are obscured by the approximations and arguments in the derivation, which are inevitable because…
We study the adiabatic limit in the density matrix approach for a quantum system coupled to a weakly dissipative medium. The energy spectrum of the quantum model is supposed to be non-degenerate. In the absence of dissipation, the geometric…
The adiabatic theorem is an important concept in quantum mechanics, it tells that a quantum system subjected to gradually changing external conditions remains to the same instantaneous eigenstate of its Hamiltonian as it initially in. In…