相关论文: Bohr's 1913 molecular model revisited

The atomic model that Niels Bohr suggested in 1913 celebrated its greatest victories in connection with one-electron atoms. Among them were the isotopic spectral effect and what became known as Rydberg atoms, insights that were fully…

We develop a model of molecular binding based on the Bohr-Sommerfeld description of atoms together with a constraint taken from conventional quantum mechanics. The model can describe the binding energy curves of H2, H3 and other molecules…

We present a new dimensional scaling transformation of the Schrodinger equation for the two electron bond. This yields, for the first time, a good description of the two electron bond via D-scaling. There also emerges, in the large-D limit,…

An historical overview is given of the relevant steps that allowed the genesis of the quantum theory of the chemical bond, starting from the appearance of the new quantum mechanics and following later developments till approximately 1931.…

Evidence is recalled of the strong opposition of Niels Bohr, at the time of the Old Quantum Theory 1.913-25, to the Lichtquanten hypothesis of Einstein. Some episodes with H.A. Kramers, J.C. Slater and W. Heisenberg are recollected; Bohr's…

We review Bohr's atomic model and its extension by Sommerfeld from a mathematical perspective of wave mechanics. The derivation of quantization rules and energy levels is revisited using semiclassical methods. Sommerfeld-type integrals are…

The old quantum theory of Bohr and Sommerfeld was abandonned for the wrong reason. Its contradictions were caused not by the orbit concept but by a mental barrier--the inconceivability that an electron might collide with the atomic nucleus.…

Bohr's atomic model, its relationship to the radiation spectrum of the hydrogen atom and the inherent hypotheses are revisited. It is argued that Bohr could have adopted a different approach, focusing his analyzes on the stationary orbit of…

Despite many successes of quantum electrodynamics (QED), we do not presently have a good understanding of this field of physics. QED has all of the foundational problems that standard non-relativistic quantum mechanics has, and further ones…

The largest failure of the old, Bohr-Sommerfeld quantum theory was with the helium atom. It brought about the theory's demise. I show that this failure does not originate, as commonly believed, with the orbit concept per se. Instead, it was…

In this review we first discuss extension of Bohr's 1913 molecular model and show that it corresponds to the large-D limit of a dimensional scaling (D-scaling) analysis, as developed by Herschbach and coworkers. In a separate but synergetic…

Analytic consideration of the Bohr-Oppenheimer (BO) approximation for diatomic molecules is proposed: accurate analytic interpolation for potential curve consistent with its rovibrational spectra is found. It is shown that in the…

Superconductors have often been described as `giant atoms'. The simplest description of atoms that heralded their quantum understanding was proposed by Bohr in 1913. The Bohr atom starts from some simple assumptions and deduces that the…

A brief account of the world view of classical physics is given first. We then recapitulate as to why the Copenhagen interpretation of the quantum mechanics had to renounce most of the attractive features of the clasical world view such as…

A complete history of early atomic models would fill volumes, but a reasonably coherent tale of the path from mechanical atoms to the quantum can be told by focusing on the relevant work of three great contributors to atomic physics, in the…

A trial function is presented for the $H_2$ molecule which provides the most accurate (the lowest) Bohr-Oppenheimer ground state energy among few-parametric trial functions (with $\leq 14$ parameters). It includes the electronic correlation…

Recently it was shown that classical "relativistic" particle dynamics was implicit in physics going back to Maxwell. The demonstration utilized a simple modification of a 1906 thought experiment by which Einstein established the mass…

In the first part of this work we apply Bohr (old or naive quantum atomic) theory for analysis of the remarkable electro-dynamical problem of magnetic monopoles. We reproduce formally exactly some basic elements of the Dirac magnetic…

We present a hybrid quantum classical neural network that can be trained to perform electronic structure calculation and generate potential energy curves of simple molecules. The method is based on the combination of parameterized quantum…

According to the correspondence principle, classical mechanics and quantum mechanics agree in the semiclassical limit, although presently it has become more and more clear how intriguing would be to try to fix a boundary between them. Here…