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Chemical reactions at ultracold temperatures are expected to be dominated by quantum mechanical effects. Although progress towards ultracold chemistry has been made through atomic photoassociation, Feshbach resonances and bimolecular…

原子物理 · 物理学 2017-03-20 M. McDonald , B. H. McGuyer , F. Apfelbeck , C. -H. Lee , I. Majewska , R. Moszynski , T. Zelevinsky

We investigate the effect of far-off-resonant trapping light on ultracold bosonic RbCs molecules. We use kHz-precision microwave spectroscopy to measure the differential AC Stark shifts between the ground and first excited rotational levels…

Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The $v=12, J=0-3$ rovibrational levels of H$_2$ ($X^1\Sigma_g^+$), lying only $2000$ cm$^{-1}$ below the first dissociation limit, were…

原子物理 · 物理学 2015-09-30 M. L. Niu , E. J. Salumbides , W. Ubachs

Rovibrational quantum states in the $X^1\Sigma_g^+$ electronic ground state of H$_2$ are prepared in the $v=13$ vibrational level up to its highest bound rotational level $J=7$, and in the highest bound vibrational level $v=14$ (for $J=1$)…

化学物理 · 物理学 2021-06-09 K. -F. Lai , M. Beyer , E. J. Salumbides , W. Ubachs

We formulate the theory for a diatomic molecule in a spatially degenerate electronic state interacting with a non-resonant laser field and investigate its rovibrational structure in the presence of the field. We report on \textit{ab initio}…

We report on photoassociation spectroscopy probing the $c^3\Sigma_{1}^+$ potential of the bi-alkali NaCs molecule, identifying eleven vibrational lines between $v' = 0$ and $v' = 25$ of the excited $c^3\Sigma_{1}^+$ potential, and resolving…

Photodissociation cross sections for the SH$^+$ radical are computed from all rovibrational (RV) levels of the ground electronic state X$~^3\Sigma^-$ for wavelengths from threshold to 500~\AA. The five electronic transitions, $2~ ^3\Sigma^-…

地球与行星天体物理 · 物理学 2016-05-04 E. C. McMillan , G. Shen , J. F. McCann , B. M. McLaughlin , P. C. Stancil

We have performed microwave spectroscopy of sodium least-bound molecular states, improving the precision of the knowledge of their energies at zero magnetic field by almost three orders of magnitude. Our experimental observations give us…

原子物理 · 物理学 2026-01-06 Manon Ballu , Zhibin Yao , Bastien Mirmand , David Papoular , Hélène Perrin , Aurélien Perrin

The collision of molecules at ultracold temperatures is of great importance for understanding the chemical interactions at the quantum regime. While much theoretical work has been devoted to this, experimental data are only available…

量子气体 · 物理学 2018-01-30 Xin Ye , Mingyang Guo , Maykel L. González-Martínez , Goulven Quéméner , Dajun Wang

We utilize the dark state in a {\Lambda}-type three-level system to cool an ensemble of 85Rb atoms in an optical lattice [Morigi et al., Phys. Rev. Lett. 85, 4458 (2000)]. The common suppression of the carrier transition of atoms with…

原子物理 · 物理学 2021-01-13 Chang Huang , Shijie Chai , Shau-Yu Lan

We present experimental observations of seven vibrational levels $v'=20-26$ of the $1^{3}\Sigma_{g}^{+}$ excited state of Li$_2$ molecules by the photoassociation (PA) of a degenerate Fermi gas of $^6$Li atoms. For each vibrational level,…

We report on the realization of an ultracold mixture of lithium atoms in the ground state and ytterbium atoms in the excited metastable 3P2 state. Such a mixture can support broad magnetic Feshbach resonances which may be utilized for the…

We report the creation and characterization of a near quantum-degenerate gas of polar $^{40}$K-$^{87}$Rb molecules in their absolute rovibrational ground state. Starting from weakly bound heteronuclear KRb Feshbach molecules, we implement…

We investigate the formation of weakly bound, electronically excited, heteronuclear 6Li40K* molecules by single-photon photoassociation in a magneto-optical trap. We performed trap loss spectroscopy within a range of 325 GHz below the…

We report the production of a high phase-space density mixture of $^{87}$Rb and $^{133}$Cs atoms in a levitated crossed optical dipole trap as the first step towards the creation of ultracold RbCs molecules via magneto-association. We…

原子物理 · 物理学 2011-07-29 H. W. Cho , D. J. McCarron , D. L. Jenkin , M. P. Köppinger , S. L. Cornish

We study the rovibronic transitions in NaK$_2$ between its electronic ground state $1^2A'$ and its second excited state $3^2A'$, to identify possible pathways for the creation of ultracold ground-state triatomic molecules. Our methodology…

量子气体 · 物理学 2026-01-16 Baraa Shammout , Leon Karpa , Silke Ospelkaus , Eberhard Tiemann , Olivier Dulieu

We investigate magic-wavelength trapping of ultracold bialkali molecules in the vicinity of weak optical transitions from the vibrational ground state of the X$^1\Sigma^+$ potential to low-lying rovibrational states of the b$^3\Pi_0$…

量子物理 · 物理学 2021-04-14 Q. Guan , S. L. Cornish , S. Kotochigova

Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

原子物理 · 物理学 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

Precise measurement of the particle number, spatial distribution and internal state is fundamental to all proposed experiments with ultracold molecules both in bulk gases and optical lattices. Here, we demonstrate in-situ detection of…

Rapid progress in atomic, molecular, and optical (AMO) physics techniques enabled the creation of ultracold samples of molecular species and opened opportunities to explore chemistry in the ultralow temperature regime. In particular, both…

化学物理 · 物理学 2020-05-04 Yu Liu , David D. Grimes , Ming-Guang Hu , Kang-Kuen Ni