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Excluding the very shallow potential minimum of the electronic ground state, all bound electronic states of He$_2$ have Rydberg character. Their potential-energy functions are similar to those of the He$_2^+$ states to which the Rydberg…

原子物理 · 物理学 2025-08-12 M. Holdener , V. Wirth , N. A. Shahin , M. Beyer , F. Merkt

Accurate $EF{}^1\Sigma^+_g-X{}^1\Sigma^+_g$ transition energies in molecular hydrogen were determined for transitions originating from levels with highly-excited vibrational quantum number, $v=11$, in the ground electronic state.…

原子物理 · 物理学 2016-09-23 T. Madhu Trivikram , M. L. Niu , P. Wcisło , W. Ubachs , E. J. Salumbides

We carry out quantum inelastic scattering calculations of collisions of Rb atoms with inverting NH3 and ND3 molecules in the energy range between 0 and 100 cm-1, which are important for experiments using velocity-controlled molecular beams…

化学物理 · 物理学 2013-05-29 Piotr S. Żuchowski , Jeremy M. Hutson

Accurate photodissociation cross sections have been obtained for the A-X electronic transition of HeH+ using ab initio potential curves and dipole transition moments. Partial cross sections have been evaluated for all rotational transitions…

星系天体物理 · 物理学 2015-05-28 S. Miyake , C. D. Gay , P. C. Stancil

We investigate collisional loss in an ultracold mixture of $^{40}$K$^{87}$Rb molecules and $^{87}$Rb atoms, where chemical reactions between the two species are energetically forbidden. Through direct detection of the KRb$_{2}^{*}$…

原子物理 · 物理学 2021-06-01 Matthew A. Nichols , Yi-Xiang Liu , Lingbang Zhu , Ming-Guang Hu , Yu Liu , Kang-Kuen Ni

Accurate experimental values for the vibrational ground tone or fundamental vibrational energy splitting of H$_2$, HD, and D$_2$ are presented. Absolute accuracies of $2\times10^{-4}$ cm$^{-1}$ are obtained from Doppler-free laser…

We report on the production of ultracold heteronuclear YbLi* molecules in a dual-species magneto-optical trap by photoassociation (PA). The formation of the electronically excited molecules close to dissociation was observed by trap loss…

We present the first spectroscopic studies of the $C \ ^1\Sigma^+$ electronic state and the $A \ ^1\Sigma^+$ - $b \ ^3\Pi_{0^+}$ complex in $^7$Li - $^{85}$Rb. Using resonantly-enhanced, two-photon ionization, we observed $v = 7$, 9, 12, 13…

原子物理 · 物理学 2016-12-21 I. C. Stevenson , D. B. Blasing , Y. P. Chen , D. S. Elliott

Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

The vibrational branching ratios of SrOH for radiative decay to the ground electronic state, $X^{2}\Sigma^{+}$, from the first two electronically excited states, $A^{2}\Pi$ and $B^{2}\Sigma^{+}$, are determined experimentally at the…

原子物理 · 物理学 2022-08-17 Zack Lasner , Annika Lunstad , Chaoqun Zhang , Lan Cheng , John M. Doyle

Ultracold ground-state molecules can be formed from ultracold atoms via photoassociation followed by a spontaneous emission process. Typically, the molecular products are distributed over a range of final states. Here, we propose to use an…

量子物理 · 物理学 2018-12-20 Tobias Kampschulte , Johannes Hecker Denschlag

Photodissociation of a molecule produces a spatial distribution of photofragments determined by the molecular structure and the characteristics of the dissociating light. Performing this basic chemical reaction at ultracold temperatures…

原子物理 · 物理学 2018-01-24 M. McDonald , I. Majewska , C. -H. Lee , S. S. Kondov , B. H. McGuyer , R. Moszynski , T. Zelevinsky

We perform photoassociation spectroscopy in an ultracold $^{23}$Na-$^6$Li mixture to study the $c^3\Sigma^+$ excited triplet molecular potential. We observe 50 vibrational states and their substructure to an accuracy of 20 MHz, and provide…

A beam of diatomic molecules scattered off a standing wave laser mode splits according to the rovibrational quantum state of the molecules. Our numerical calculation shows that single state resolution can be achieved by properly tuned,…

量子物理 · 物理学 2009-11-06 P. Domokos , T. Kiss , J. Janszky

We report on the direct conversion of laser-cooled 41K and 87Rb atoms into ultracold 41K87Rb molecules in the rovibrational ground state via photoassociation followed by stimulated Raman adiabatic passage. High-resolution spectroscopy based…

原子物理 · 物理学 2015-05-19 K. Aikawa , D. Akamatsu , M. Hayashi , K. Oasa , J. Kobayashi , P. Naidon , T. Kishimoto , M. Ueda , S. Inouye

Long-range metastable molecules consisting of two cesium atoms in high Rydberg states have been observed in an ultracold gas. A sequential three-photon two-color photoassociation scheme was employed to form these molecules in states which…

原子物理 · 物理学 2016-11-17 Heiner Saßmannshausen , Johannes Deiglmayr

Within the framework of the quark delocalization color screening model, a systematic investigation of the anticharmed-strange pentaquark system is performed using the resonance group method. The currently estimations predict three bound…

高能物理 - 唯象学 · 物理学 2024-07-09 Xuejie Liu , Yue Tan , Xiaoyun Chen , Dianyong Chen , Hongxia Huang , Jialun Ping

The predissociation dynamics of the vibrationless level of the first Rydberg state 6s (B 2E) state of CH3I has been studied by femtosecond-resolved velocity map imaging of both the CH3 and I photofragments. The kinetic energy distributions…

原子与分子团簇 · 物理学 2017-09-13 Nicolas Thiré , Raluca Cireasa , David Staedter , Steven Pratt , Valerie Blanchet

We report the binding energy of $^{87}$Rb$^{133}$Cs molecules in their rovibrational ground state measured using an offset-free optical frequency comb based on difference frequency generation technology. We create molecules in the absolute…

We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to…