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We investigate the possibility of forming deeply bound ultracold RbCs molecules by a two-color photoassociation experiment. We compare the results with those for Rb_2 in order to understand the characteristic differences between…

原子物理 · 物理学 2010-06-16 Subhas Ghosal , Richard J. Doyle , Christiane P. Koch , Jeremy M. Hutson

The relativistic configuration interaction valence bond method has been used to calculate permanent and transition electric dipole moments of the KRb heteronuclear molecule as a function of internuclear separation. The permanent dipole…

软凝聚态物质 · 物理学 2009-11-10 S. Kotochigova , P. S. Julienne , E. Tiesinga

We study the combination of hyperfine and Zeeman structure in the spin-orbit coupled $A^1\Sigma_u^+-b^3\Pi_u$ complex of $^{87}\textrm{Rb}_2$. For this purpose, absorption spectroscopy at a magnetic field around $B=1000\:\textrm{G}$ is…

量子气体 · 物理学 2016-12-07 Markus Deiß , Björn Drews , Johannes Hecker Denschlag , Eberhard Tiemann

We report the observation and analysis of the $3\,^3\Pi_{\Omega}$ double-minimum electronic excited state of $^{39}$K$^{85}$Rb. The spin-orbit components ($0^{+}, 0^{-}, 1$ and 2) of this state are investigated based on potentials developed…

We report on the creation of ultracold 84Sr2 molecules in the electronic ground state. The molecules are formed from atom pairs on sites of an optical lattice using stimulated Raman adiabatic passage (STIRAP). We achieve a transfer…

量子气体 · 物理学 2012-09-18 Simon Stellmer , Benjamin Pasquiou , Rudolf Grimm , Florian Schreck

We report on high-resolution spectroscopy of ultracold fermionic \nak~Feshbach molecules, and identify a two-photon pathway to the rovibrational singlet ground state via a resonantly mixed \Bcres intermediate state. Photoassociation in a…

量子气体 · 物理学 2015-08-28 Jee Woo Park , Sebastian A. Will , Martin W. Zwierlein

Two-color photoassociation of ground state $^6$Li$^{87}$Rb molecules via the $\mathrm{B}^1\Pi$ electronic state using short pulses near a magnetic Feshbach resonance is studied theoretically. A near-resonant magnetic field is applied to mix…

原子物理 · 物理学 2014-02-04 Marko Gacesa , Subhas Ghosal , Jason Byrd , Robin Côté

We report here on the production of an ultracold gas of tightly bound Rb2 molecules in the ro-vibrational triplet ground state, close to quantum degeneracy. This is achieved by optically transferring weakly bound Rb2 molecules to the…

量子物理 · 物理学 2009-11-13 F. Lang , K. Winkler , C. Strauss , R. Grimm , J. Hecker Denschlag

We report the creation of ultracold samples of $^{39}$K$^{133}$Cs molecules in their rovibrational ground state. By investigating potentially suitable excited states using one- and two-photon spectroscopy, we have identified a pathway to…

Processes that break molecular bonds are typically observed with molecules occupying a mixture of quantum states and successfully described with quasiclassical models, while a few studies have explored the distinctly quantum mechanical…

原子物理 · 物理学 2018-10-10 S. S. Kondov , C. -H. Lee , M. McDonald , B. H. McGuyer , I. Majewska , R. Moszynski , T. Zelevinsky

Photoassociation of two ultracold rubidium atoms and the subsequent formation of stable molecules in the singlet ground and lowest triplet states is investigated theoretically. The method employs laser pulses inducing transitions via…

原子物理 · 物理学 2007-05-23 Christiane P. Koch , Ronnie Kosloff , Françoise Masnou-Seeuws

Photoionization spectroscopy of cold cesium dimers obtained by photoassociation of cold atoms in a magneto-optical trap is reported here. In particular, we report on the observation and on the spectroscopic analysis of all the excited…

We use coupled-channel calculations to explore the nature of near-threshold bound states in a simplified model of Rb+KRb. This is a prototype for systems with very strong coupling at short range and chaotic behavior for the short-range…

原子物理 · 物理学 2026-05-01 James F. E. Croft , Brian K. Kendrick , Jeremy M. Hutson

We report the observation of microwave coherent control of rotational states of ultracold $^{85}$Rb$^{133}$Cs molecules formed in their vibronic ground state by short-range photoassociation. Molecules are formed in the single rotational…

原子物理 · 物理学 2020-07-10 Zhonghua Ji , Ting Gong , Yonglin He , Jeremy M. Hutson , Yanting Zhao , Liantuan Xiao , Suotang Jia

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

量子物理 · 物理学 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

Sub-Doppler, saturation dip, spectra of lines in the $v_1 + v_3$, $v_1 + 2v_4$ and $v_3 + 2v_4$ bands of $^{14}$NH$_3$ have been measured by frequency comb-referenced diode laser absorption spectroscopy. The observed spectral line widths…

化学物理 · 物理学 2016-11-03 Sylvestre Twagirayezu , Gregory E. Hall , Trevor J. Sears

We propose high-spin $\Sigma$-state polar molecules assembled from ultracold atoms to probe charge-parity violating physics beyond the Standard Model. We identify YbCr as a prime candidate to search for the electric dipole moment of the…

量子气体 · 物理学 2026-03-16 Alessio Ciamei , Adam Koza , Marcin Gronowski , Michał Tomza

We report the measurement of the 1$^{1}\Sigma\longrightarrow$ 2$^{1}\Sigma$ transition of CaH$^+$ by resonance-enhanced photodissociation of CaH$^+$ that is co-trapped with laser-cooled Ca$^+$ . We observe four resonances that we assign to…

原子物理 · 物理学 2016-09-30 Rene Rugango , Aaron T. Calvin , Smitha Janardan , Gang Shu , Kenneth R. Brown

We have produced ultracold heteronuclear YbRb$^*$ molecules in a combined magneto-optical trap by photoassociation. The formation of electronically excited molecules close to the dissociation limit was observed by trap loss spectroscopy in…

量子物理 · 物理学 2016-01-20 N. Nemitz , F. Baumer , F. Münchow , S. Tassy , A. Görlitz

We employ two-photon spectroscopy to study the vibrational states of the triplet ground state potential ($a^3\Sigma^+$) of the $^{23}$Na$^{6}$Li molecule. Pairs of Na and Li atoms in an ultracold mixture are photoassociated into an excited…