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We have produced ultracold heteronuclear KRb molecules by the process of photoassociation in a two-species magneto-optical trap. Following decay of the photoassociated KRb*, the molecules are detected using two-photon ionization and…

We report the first observation of photoassociation to the 2(1)Sigma(g)(+) state of 85Rb2 . We have observed two vibrational levels (v'=98, 99) below the 5s1/2+5p1/2 atomic limit and eleven vibrational levels (v'=102-112) above it. The…

原子物理 · 物理学 2015-06-11 M. A. Bellos , R. Carollo , D. Rahmlow , J. Banerjee , E. E. Eyler , P. L. Gould , W. C. Stwalley

Ultracold LiCs molecules in the absolute ground state X$^1\Sigma^+$, v"=0, J"=0 are formed via a single photo-association step starting from laser-cooled atoms. The selective production of v"=0, J"=2 molecules with a 50-fold higher rate is…

量子物理 · 物理学 2010-08-09 J. Deiglmayr , A. Grochola , M. Repp , K. Mörtlbauer , C. Glück , J. Lange , O. Dulieu , R. Wester , M. Weidemüller

The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…

原子物理 · 物理学 2011-04-15 Mamadou Ndong , Christiane P. Koch

We spectroscopically investigate the hyperfine, rotational and Zeeman structure of the vibrational levels $\text{v}'=0$, $7$, $13$ within the electronically excited $c^3\Sigma_g^+$ state of $^{87}\text{Rb}_2$ for magnetic fields of up to…

We have studied the X 1{\Sigma}+ and B 1{\Pi} states of 7Li85Rb using Laser Induced Fluorescence (LIF) spectroscopy and Fluorescence Excitation Spectroscopy (FES). We extract molecular constants for levels v" = 0-2 of the X 1{\Sigma}+ state…

原子物理 · 物理学 2011-11-04 Sourav Dutta , Adeel Altaf , D. S. Elliott , Yong P. Chen

We propose and experimentally investigate a scheme for narrow-line cooling of KRb molecules in the rovibrational ground state. We show that the spin-forbidden $\mathrm{X^1\Sigma^+} \rightarrow \mathrm{b^3\Pi_{0^+}}$ transition of KRb is…

原子物理 · 物理学 2015-06-17 J. Kobayashi , K. Aikawa , K. Oasa , S. Inouye

We have produced ultracold, polar RbCs* molecules via photoassociation in a laser-cooled mixture of Rb and Cs atoms. Using a model of the RbCs* molecular interaction which reproduces the observed rovibrational structure, we infer decay…

原子物理 · 物理学 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , David DeMille , Thomas Bergeman

Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

Starting from an ultracold sample of ground-state $^{23}$Na$^{87}$Rb molecules, we investigate the lowest ro-vibrational level of the $b^3\Pi$ state with high resolution laser spectroscopy. This electronic spin-forbidden $X^1\Sigma^+…

原子物理 · 物理学 2021-11-17 Junyu He , Junyu Lin , Romain Vexiau , Nadia Bouloufa , Olivier Dulieu , Dajun Wang

We have investigated rovibronic levels of the strongly mixed $b^3\Pi_1-c^3\Sigma^+_1-B^1\Pi_1$ states [the 2(1), 3(1), and 4(1) states in Hund's case (c) notation] of $^{85}$Rb$^{133}$Cs in the energy range of 13950$-$14200 cm$^{-1}$ using…

原子物理 · 物理学 2018-10-24 Toshihiko Shimasaki , Jin-Tae Kim , Yuqi Zhu , David DeMille

We demonstrate detection of NaRb Feshbach molecules at high magnetic field by combining molecular photodissociation and absorption imaging of the photofragments. The photodissociation process is carried out via a spectroscopically selected…

原子物理 · 物理学 2020-12-02 Fan Jia , Zhichao Guo , Lintao Li , Dajun Wang

We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by…

Using a non-selective broadband detection scheme we discovered an efficient mechanism of formation of ultracold Cs$_2$ molecules in deeply bound levels ($v=1-9$) of their electronic ground state X$^1 \Sigma_g^+$. They are formed by a…

We study, both theoretically and experimentally, the dynamical polarizability $\alpha(\omega)$ of $\textrm{Rb}_2$ molecules in the rovibrational ground state of $\mathrm{a}^3\Sigma_u^+$. Taking all relevant excited molecular bound states…

Using an ultracold gas of $^{87}$Rb$^{133}$Cs molecules, we perform hyperfine-resolved spectroscopy of transitions from the vibronic ground state to the lowest rovibrational states of the electronic state $\mathrm{b}\,^3\Pi_0$, as a…

We demonstrate the production of ultracold polar RbCs molecules in their vibronic ground state, via photoassociation of laser-cooled atoms followed by a laser-stimulated state transfer process. The resulting sample of $X ^1\Sigma^+ (v=0)$…

原子物理 · 物理学 2009-11-11 J. M. Sage , S. Sainis , T. Bergeman , D. DeMille

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

We report on the anomalously high line strength of a single rotational level in the ultracold photoassociation of two 85Rb atoms to form 85Rb2. The v' = 111, J' = 5 level belongs to the Hund's case (c) 2 (0g+) state, which correlates to the…

原子物理 · 物理学 2013-02-27 R. Carollo , M. A. Bellos , D. Rahmlow , J. Banerjee , E. E. Eyler , P. L. Gould , W. C. Stwalley

Using microwave detected, microwave-optical double resonance, we have measured the homogeneous linewidths of individual rovibrational transitions in the \~A state of NH3, NH2D, NHD2, and ND3. We have used this excited state spectroscopic…