相关论文: Complete homochirality induced by the nonlinear au…
Helical motifs are ubiquitious in macromolecular systems. The mechanism of spontaneous emergence of helicity is unknown, especially in cases where torsional interactions are absent. Emergence of helical order needs coordinated organization…
By modifying and generalizing known supersymmetric models we are able to find four different sets of one-dimensional Hamiltonians for the inverted harmonic oscillator. The first set of Hamiltonians is derived by extending the supersymmetric…
A problem of inducing a required sign of chirality in a racemic mixture of enantiomers of a chiral molecule is analyzed. As an example, a racemic mixture (vapor) of left- and right-handed enantiomers of hydrogen peroxide (H2O2) molecule is…
An inverse problem framework for constructing reaction systems with prescribed properties is presented. Kinetic transformations are defined and analysed as a part of the framework, allowing an arbitrary polynomial ordinary differential…
A fully resolvable quantum many-body Hamiltonian is introduced that mimics the behavior of the autocatalytic chemical reaction A+B <-> 2B involving two different molecular species, A and B. The model also describes two nonlinearly-coupled…
The emergence of biomolecular homochirality is a critically important question about life phenomenon and the origins of life. In a previous paper (arXiv:1309.1229), I tentatively put forward a new hypothesis that the emergence of a single…
Life is homochiral and homochirality is a fundamental feature of living systems on Earth. While the exact mechanism that led to homochirality is still not fully understood, any realistic scenario on the origins of life needs to address the…
Autocatalysis is a deceptively simple concept, referring to the situation that a chemical species $X$ catalyzes its own formation. From the perspective of chemical kinetics, autocatalysts show a regime of super-linear growth. Given a…
The entanglement produced by a bilinear Hamiltonian in continuous variables has been thoroughly studied and widely used. In contrast, the physics of entanglement resulting from nonlinear interaction described by partially degenerate…
A continuous train of irregularly spaced spikes, peculiar of homoclinic chaos, transforms into clusters of regularly spaced spikes, with quiescent periods in between (bursting regime), by feeding back a low frequency portion of the…
(abridged) We review recent studies of chirality using circularly polarized light, along with the birth and evolution of life and planetary systems. Terrestrial life consists almost exclusively of one enantiomer, left-handed amino acids.…
Electron transmission through chiral molecules induced by circularly polarized light can be very different for mirror-image structures, a peculiar fact given that the electronic energy spectra of the systems are identical. We propose that…
Results of recent experiment reinstate feasibility to the hypothesis that biomolecular homochirality originates from beta decay. Coupled with hints that this process occurred extraterrestrially suggests aluminum-26 as the most likely…
Chirality, nonreciprocity, and quantum correlations are at the center of a wide range of intriguing effects and applications across natural sciences and emerging quantum technologies. However, the direct link combining these three essential…
Amino acids occurring in proteins are, with rare exceptions, exclusively of the L-configuration. Among the many scenarios put forward to explain the origin of this chiral homogeneity (i.e., homochirality), one involves the asymmetric…
We study numerically the dynamics of acetanilide (ACN) molecules placed on a flat surface of a multilayer hexagonal boron nitride structure. We demonstrate that the ACN molecules, being achiral in three dimensions, become chiral after being…
Achieving intrinsic optical chirality requires breaking all mirror symmetries of an object, and maximum chirality, which allows interaction with only one helicity of light, is particularly promising for applications such as chiral sensing,…
A thermodynamic argument has been developed which relates the chirality of the constituents of a mixture of enantiomers to the system excess volume, and thereby to its Gibbs free enthalpy. A specific connection is shown between the excess…
Molecular chirality is conventionally understood as space-inversion-symmetry breaking in the equilibrium structure of molecules. Less well known is that achiral molecules can be made chiral through extreme rotational excitation. Here, we…
A nonrelativistic Hamiltonian describing interaction between a mechanical degree of freedom and radiation pressure is commonly used as an ultimate tool for studying system behavior in opto-mechanics. This Hamiltonian is derived from the…