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相关论文: Charge- and parity-projected Hartree-Fock method f…

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We propose a mean field framework in which the charge and the parity symmetries of a single-particle state are broken. We break these symmetries to incorporate the correlation induced by the tensor force into a nuclear mean field model. We…

核理论 · 物理学 2009-11-10 Satoru Sugimoto , Kiyomi Ikeda , Hiroshi Toki

Recently, we developed a mean-field-type framework which treats the correlation induced by the tensor force. To exploit the tensor correlation we introduce single-particle states with the parity and charge mixing. To make a total wave…

核理论 · 物理学 2008-11-26 Satoru Sugimoto , Kiyomi Ikeda , Hiroshi Toki

We study the effect of the tensor correlation in the alpha clustering in 8Be. We take as the wave function of the alpha particle the one calculated by the charge- and parity-projected Hartree- Fock method, which was proposed by us recently.…

核理论 · 物理学 2008-11-26 Satoru Sugimoto , Kiyomi Ikeda , Hiroshi Toki

Background: The Hartree-Fock mean-field approximation is standard in combination with energy density functionals (EDF) that account for some dynamical correlations. Breaking and restoring the symmetries of the system allow for the inclusion…

核理论 · 物理学 2023-11-20 Joshua Cesca , Cédric Simenel

We present a symmetry projection technique for enforcing rotational and parity symmetries in nuclear-electronic Hartree-Fock wave functions, which treat electrons and nuclei on equal footing. The molecular Hamiltonian obeys rotational and…

化学物理 · 物理学 2023-11-03 Robin Feldmann , Alberto Baiardi , Markus Reiher

Coupled cluster theory is the method of choice for weakly correlated systems. But in the strongly correlated regime, it faces a symmetry dilemma, where it either completely fails to describe the system, or has to artificially break certain…

化学物理 · 物理学 2020-05-14 Yiheng Qiu , Thomas M. Henderson , Jinmo Zhao , Gustavo E. Scuseria

Projected Hartree-Fock theory provides an accurate description of many kinds of strong correlations but does not properly describe weakly-correlated systems. On the other hand, single-reference methods such as configuration interaction or…

强关联电子 · 物理学 2022-04-06 Ruiheng Song , Thomas M. Henderson , Gustavo E. Scuseria

The symmetry-projected Hartree--Fock ansatz for the electronic structure problem can efficiently account for static correlation in molecules, yet it is often unable to describe dynamic correlation in a balanced manner. Here, we consider a…

强关联电子 · 物理学 2015-06-17 Carlos A. Jiménez-Hoyos , R. Rodríguez-Guzmán , Gustavo E. Scuseria

Spin-projected Hartree-Fock is introduced as a particle-hole excitation ansatz over a symmetry-adapted reference determinant. Remarkably, this expansion has an analytic expression that we were able to decipher. While the form of the…

强关联电子 · 物理学 2016-11-08 Yiheng Qiu , Thomas M. Henderson , Gustavo E. Scuseria

We introduce a new method for deriving the time-dependent Hartree or Hartree-Fock equations as an effective mean-field dynamics from the microscopic Schroedinger equation for fermionic many-particle systems in quantum mechanics. The method…

数学物理 · 物理学 2016-11-29 Sören Petrat , Peter Pickl

This paper proposes an efficient algorithm for solving the Hartree--Fock equation combining a multilevel correction scheme with an adaptive refinement technique to improve computational efficiency. The algorithm integrates a multilevel…

数值分析 · 数学 2025-10-14 Fei Xu

We use the Hartree-Fock method to study an interacting one-dimensional electron system on a finite wire, partially depleted at the center by a smooth potential barrier. A uniform one-Tesla Zeeman field is applied throughout the system. We…

介观与纳米尺度物理 · 物理学 2012-10-29 Jiang Qian , Bertrand I. Halperin

A new method is presented to reconstruct the potential of a quantum mechanical many-body system from observational data, combining a nonparametric Bayesian approach with a Hartree-Fock approximation. A priori information is implemented as a…

核理论 · 物理学 2009-10-31 J. C. Lemm , J. Uhlig

Projected Hartree-Fock theory provides an accurate description of many kinds of strong correlation but does not properly describe weakly correlated systems. Coupled cluster theory, in contrast, does the opposite. It therefore seems natural…

强关联电子 · 物理学 2017-08-22 Ethan Qiu , Thomas M. Henderson , Gustavo E. Scuseria

We benchmark angular-momentum projected{-after-variation} Hartree-Fock calculations as an approximation to full configuration-interaction results in a shell model basis. For such a simple approximation we find reasonably good agreement…

核理论 · 物理学 2021-11-12 Stephanie M. Lauber , Hayden C. Frye , Calvin W. Johnson

Pairing correlations in symmetric nuclear matter are studied within a relativistic mean-field approximation based on a field theory of nucleons coupled to neutral ($\sigma$ and $\omega$) and to charged ($\varrho$) mesons. The Hartree-Fock…

核理论 · 物理学 2016-09-08 F. Matera , G. Fabbri , A. Dellafiore

The exchange part of energy density of the linear Dirac--Hartree--Fock (DHF) model in symmetric nuclear matter is evaluated in a parameter--free closed form and expressed as density functional. After the rearranging terms the relativistic…

核理论 · 物理学 2021-04-27 S. Gmuca , K. Petrik , J. Leja

The variational principle is used to build a model which describes open shell nuclei with ground state deformations. Hartree-Fock equations are solved by using single particle wave functions whose radial parts depend on the projection of…

核理论 · 物理学 2021-07-22 G. Co , M. Anguiano , A. M. Lallena

Projected Hartree-Fock theory (PHF) has a long history in quantum chemistry. PHF is here understood as the variational determination of an N-electron broken symmetry Slater determinant that minimizes the energy of a projected state with the…

We present a density matrix approach for computing global solutions of Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems. Equality of the upper- and…

化学物理 · 物理学 2014-02-11 Srikant Veeraraghavan , David A. Mazziotti
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