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相关论文: Periodic copolymers at selective interfaces: A Lar…

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A copolymer is a chain of repetitive units (monomers) that are almost identical, but they differ in their degree of affinity for certain solvents. This difference leads to striking phenomena when the polymer fluctuates in a nonhomogeneous…

概率论 · 数学 2010-11-11 Francesco Caravenna , Giambattista Giacomin

Motivated by the problem of domain formation in chromosomes, we studied a co--polymer model where only a subset of the monomers feel attractive interactions. These monomers are displaced randomly from a regularly-spaced pattern, thus…

生物大分子 · 定量生物学 2018-02-13 Matteo Negri , Marco Gherardi , Guido Tiana , Marco Cosentino Lagomarsino

In this chapter we review the rich behavior of polymer chains embedded in a quenched random environment. We first consider the problem of a Gaussian chain free to move in a random potential with short-ranged correlations. We derive the…

无序系统与神经网络 · 物理学 2007-05-23 Yadin Y. Goldschmidt , Yohannes Shiferaw

We present using simple scaling arguments and one step replica symmetry breaking a theory for the localization of semiflexible polymers in a quenched random environment. In contrast to completely flexible polymers, localization of…

软凝聚态物质 · 物理学 2009-11-10 Arti Dua , Thomas A. Vilgis

The results obtained from molecular dynamics simulations of the friction at an interface between polymer melts and weakly attractive crystalline surfaces are reported. We consider a coarse-grained bead-spring model of linear chains with…

软凝聚态物质 · 物理学 2012-06-12 Nikolai V. Priezjev

This paper describes directed polymer on general time-correlated random field. Law of large numbers, existence and smoothness of limiting free energies are proved at all temperature. We also display the delocalized-localized transition, via…

概率论 · 数学 2024-12-20 Jiaming Chen

We deduce the qualitative phase diagram of a long flexible neutral polymer chain immersed in a poor solvent near an attracting surface using phenomenological arguments. The actual positions of the phase boundaries are estimated numerically…

统计力学 · 物理学 2009-11-07 R. Rajesh , Deepak Dhar , Debaprasad Giri , Sanjay Kumar , Yashwant Singh

Letting free polymers diffuse from solution into a crosslinked polymer gel is often a crucial processing step in the synthesis of multiphase polymer-based gels, e.g., core-shell microgels. Here we use coarse-grained molecular dynamics…

软凝聚态物质 · 物理学 2024-12-17 Jude Ann Vishnu , Torsten Gereon Linder , Sebastian Seiffert , Friederike Schmid

Polymer chains decorated with a fraction of monomers capable of forming reversible bonds form transient polymer networks that are important in soft and biological systems. If chains are flexible and the attractive monomers are all of the…

软凝聚态物质 · 物理学 2023-10-18 Lorenzo Rovigatti , Francesco Sciortino

We consider the stochastic evolution of a (1 + 1)-dimensional polymer in the depinned regime. At equilibrium the system exhibits a double well structure: the polymer lies(essentially) either above or below the repulsive line. As a…

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

软凝聚态物质 · 物理学 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

Polymer chains with hard-core interaction on a two-dimensional lattice are modeled by directed random walks. Two models, one with intersecting walks (IW) and another with non-intersecting walks (NIW) are presented, solved and compared. The…

凝聚态物理 · 物理学 2016-08-31 G. Forgacs , K. Ziegler

We consider $(1+1)$-dimensional directed polymers in a random potential and provide sufficient conditions guaranteeing joint localization. Joint localization means that for typical realizations of the environment, and for polymers started…

概率论 · 数学 2022-11-14 Yuri Bakhtin , Douglas Dow

We use the lattice model of directed walks to investigate the conformational as well as the adsorption properties of a semiflexible homopolymer chain immersed in a good solvent in two and three dimensions. To account for the stiffness in…

统计力学 · 物理学 2009-11-07 P. K. Mishra , S. Kumar , Y. Singh

To study the localization of random heteropolymers at an interface separating two selective solvents within the model of Garel, Huse, Leibler and Orland, Europhys. Lett. {\bf 8} 9 (1989), we propose an approach based on a disorder-dependent…

凝聚态物理 · 物理学 2015-06-25 Cecile Monthus

Dimerization and subsequent aggregation of polymers and biopolymers often occur under nonequilibrium conditions. When the initial state of the polymer is not collapsed or the final folded native state, the dynamics of dimerization can…

软凝聚态物质 · 物理学 2024-11-19 Sangita Mondal , Ved Mahajan , Biman Bagchi

We present an approach to studying directed polymers in interaction with a defect line and subject to a force, which pulls them away from the line. We consider in particular the case of inhomogeneous interactions. We first give a formula…

无序系统与神经网络 · 物理学 2009-11-11 G. Giacomin , F. L. Toninelli

Using molecular dynamics simulation of a standard bead-spring model we investigate the density crossover scaling of strictly two-dimensional self-avoiding polymer chains focusing on properties related to the contact exponent set by the…

软凝聚态物质 · 物理学 2015-06-03 N. Schulmann , H. Meyer , J. P. Wittmer , A. Johner , J. Baschnagel

Polymers confined to a narrow channel are subject to strong entropic forces that tend to drive the molecules apart. In this study, we use Monte Carlo computer simulations to study the segregation behavior of two flexible hard-sphere…

软凝聚态物质 · 物理学 2021-01-27 James M. Polson , Qinxin Zhu

Using extensive Monte Carlo simulations we study the phase diagram of a symmetric binary (AB) polymer blend confined into a thin film as a function of the film thickness D. The monomer-wall interactions are short ranged and antisymmetric,…

统计力学 · 物理学 2009-10-31 M. Mueller , K. Binder