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Similarly-charged polyelectrolytes are known to attract each other and aggregate into bundles when the charge density of the polymers exceeds a critical value that depends on the valency of the counterions. The dynamics of aggregation of…

软凝聚态物质 · 物理学 2016-09-22 Anvy Moly Tom , R. Rajesh , Satyavani Vemparala

Exact results for conformational statistics of compact polymers are derived from the two-flavour fully packed loop model on the square lattice. This loop model exhibits a two-dimensional manifold of critical fixed points each one…

统计力学 · 物理学 2009-10-31 Jesper Lykke Jacobsen , Jane' Kondev

We study self-avoiding walks on the square lattice restricted to a square box of side $L$ weighted by a length fugacity without restriction of their end points. This models a confined polymer in dilute solution. The model admits a phase…

统计力学 · 物理学 2022-07-22 C. J. Bradly , A. L. Owczarek

We present simulations on charged polymers in poor solvent. First we investigate in detail the dilute concentration range with and without imposed extension constraints. The resulting necklace polymer conformations are analyzed in detail.…

软凝聚态物质 · 物理学 2016-08-16 Hans Jörg Limbach , Christian Holm , Kurt Kremer

Long linear polymers in dilute solutions are known to undergo a collapse transition from a random coil (expand itself) to a compact ball (fold itself up) when the temperature is lowered, or the solvent quality deteriorates. A natural model…

概率论 · 数学 2015-06-12 Gia Bao Nguyen , Nicolas Petrelis

Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…

软凝聚态物质 · 物理学 2023-06-07 Souradeep Ghosh , Soumik Mitra , Arindam Kundagrami

We study the phase transitions of a random copolymer chain with quenched disorder. We apply a replica variational approach based on a Gaussian trial Hamiltonian in terms of the correlation functions of monomer Fourier coordinates. This…

无序系统与神经网络 · 物理学 2009-10-30 A. Moskalenko , Yu. A. Kuznetsov , K. A. Dawson

This work is inspired by a remark of de Gennes about polyelectrolytes, which are charged polymers. A common model for a polymer is a self-avoiding or self-repelling random walk or Brownian motion. For polyelectrolytes, the repelling…

概率论 · 数学 2026-04-10 Carl Mueller , Shiquan Li

We study quenched distributions on random walks in a random potential on integer lattices of arbitrary dimension and with an arbitrary finite set of admissible steps. The potential can be unbounded and can depend on a few steps of the walk.…

概率论 · 数学 2011-12-15 Firas Rassoul-Agha , Timo Seppalainen , Atilla Yilmaz

Stretching dynamics of polymers in microfluidics is of particular interest for polymer scientists. As a charged polymer, a polyelectrolyte can be deformed from its coiled equilibrium configuration to an extended chain by applying uniform or…

软凝聚态物质 · 物理学 2014-11-18 Farnoush Farahpour , Fathollah Varnik , Mohammad Reza Ejtehadi

Similarly-charged polymers in solution, known as polyelectrolytes, are known to form aggregated structures in the presence of oppositely charged counterions. Understanding the dependence of the equilibrium phases and the dynamics of the…

软凝聚态物质 · 物理学 2017-07-03 Anvy Moly Tom , Ravindran Rajesh , Satyavani Vemparala

We study the energy structure and the transfer of an extra electron or hole along periodic polymers made of $N$ monomers, with a repetition unit made of $P$ monomers, using a Tight-Binding wire model, where a site is a monomer (e.g., in…

软凝聚态物质 · 物理学 2018-09-19 K. Lambropoulos , C. Vantaraki , P. Bilia , M. Mantela , C. Simserides

Single partially confined collapsed polymers are studied in two dimensions. They are described by self-avoiding random walks with nearest-neighbour attractions below the $\Theta$-point, on the surface of an infinitely long cylinder. For the…

统计力学 · 物理学 2009-11-07 Hsiao-Ping Hsu , Peter Grassberger

We consider the model for the distribution of a long homopolymer in a potential field. The typical shape of the polymer depends on the temperature parameter. We show that at a critical value of the temperature the transition occurs from a…

概率论 · 数学 2009-02-18 M. Cranston , L. Koralov , S. Molchanov , B. Vainberg

The conformational properties of flexible and semiflexible polymers exposed to active noise are studied theoretically. The noise may originate from the interaction of the polymer with surround- ing active (Brownian) particles or from the…

软凝聚态物质 · 物理学 2024-06-03 Thomas Eisenstecken , Gerhard Gompper , Roland G. Winkler

A brief review of our recent studies aiming at a better understanding of the scaling behaviour of polymers in disordered environments is given. The main emphasis is on a simple generic model where the polymers are represented by…

软凝聚态物质 · 物理学 2014-11-19 V. Blavatska , N. Fricke , W. Janke

We investigate conformations and dynamics of a polymer considering its monomers to be active Brownian particles. This active polymer shows very intriguing physical behavior which is absent in an active Rouse chain. The chain initially…

软凝聚态物质 · 物理学 2020-04-13 Shalabh K. Anand , Sunil P. Singh

In these proceedings, we first summarize some general properties of phase transitions in the presence of quenched disorder, with emphasis on the following points: the need to distinguish typical and averaged correlations, the possible…

无序系统与神经网络 · 物理学 2008-03-12 Cecile Monthus , Thomas Garel

A living polymers transition is found in molecular dynamics simulations of a charge-symmetric size-asymmetric electrolyte with no anisotropic interactions. The fluid has strong polymeric character at low temperatures, where it consists of…

统计力学 · 物理学 2007-05-23 Sorin Bastea

We study equilibrium statistics of single semi-flexible polymer chain in the presence of defects. The defects are lying along a line in the two and three dimensions and the monomers are interacting with the onsite potential of the defects.…

软凝聚态物质 · 物理学 2020-09-21 Pramod Kumar Mishra