相关论文: A generalized molecular theory for nematic liquid …
The physics of nematic liquid crystals has been subject of intensive research since the late 19th century. However, because of the limitations of chemistry the focus has been centered around uni- and biaxial nematics associated with…
In this study, one of the mean-field theories in nematics, the Maier-Saupe theory (MST), is generalized within Tsallis Thermostatistics (TT). The variation of the order parameter versus temperature has been investigated and compared with…
Statistical theory of the dielectric susceptibility of polar liquid crystals is proposed. The molecules are not uniaxial but similar to cones. It is assumed that the permanent dipole moment of a molecule is parallel to the axis of the…
A theory of thermotropic nematic liquid crystals in which molecules form internally ordered clusters is presented. The formulation is based on the same mean field approximation and form of the anisotropic potential used in the Maier-Saupe…
The influence of the dimerization process on the nematic ordering is investigated by using a nonextensive thermostatistics, namely Tsallis thermostatistics(TT). A theoretical model taking into account the dimerization influence on the…
Nematic liquid crystals exhibit configurations in which the underlying ordering changes markedly on macroscopic length scales. Such structures include topological defects in the nematic phase and tactoids within nematic-isotropic…
In this work, a theoretical study of phase equilibrium in mixtures of a calamitic nematic liquid crystal and hard spherical nanoparticles is presented. A mean-field thermodynamic model is used, where the interactions are considered to be…
Nematic liquid crystals have been known for more than a century, but it was not until the 60s-70s that, with the development of room temperature nematics, they became widely used in applications. Polar nematic phases have been long-time…
A rigorous theory of liquid-crystal transitions is developed starting from the Liouville equation. The starting point is an all-atom description and a set of order parameter field variables that are shown to evolve slowly via Newton's…
The general Ericksen-Leslie system for the flow of nematic liquid crystals is reconsidered in the non-isothermal case aiming for thermodynamically consistent models. The non-isothermal model is then investigated analytically. A fairly…
A continuum theory is employed to numerically study the equilibrium orientation and defect structures of a circular cylindrical particle with flat ends under a homeotropic anchoring condition in a uniform nematic medium. Different aspect…
The structure of a molecular liquid, in both the nematic liquid crystalline and isotropic phases, around a cylindrical macroparticle, is studied using density functional theory. In the nematic phase the structure of the fluid is highly…
Liquid crystals consisting of biaxial particles can exhibit a much richer phase behavior than their uniaxial counterparts. Usually, one has to rely on simulation results to understand the phase diagram of these systems, since very few…
A generalized model taking into account the photoisomerization influence on the nematic ordering is presented. This generalized theory is used to investigate the effect of the nonextensivity on the concentration dependence of the long-range…
Liquid crystals are assemblies of rod-like molecules which self-organize to form mesophases, in-between ordinary liquids and anisotropic crystals. At each point, the molecules collectively orient themselves along a privileged direction,…
Recent advances in classical density functional theory are combined with stochastic process theory and rare event techniques to formulate a theoretical description of nucleation, including crystallization, that can predict nonclassical…
Based on static and dynamical density functional theory, a phase-field-crystal model is derived which involves both the translational density and the orientational degree of ordering as well as a local director field. The model exhibits…
Various possibilities of polar self-organisation in low molar mass nematic, smectic and columnar liquid crystals are discussed with particular focus on the underlying molecular symmetries and interactions. Distinction is made between vector…
We introduce a new class of non-isothermal models describing the evolution of nematic liquid crystals and prove their consistency with the fundamental laws of classical Thermodynamics. The resulting system of equations captures all…
A statistical theory of cholesteric liquid crystals composed of short rigid biaxial molecules is presented. It is derived in the thermodynamic limit at a small density and a small twist. The uniaxial (biaxial) cholesteric phase is regarded…