纳米颗粒 - 向列相液晶复合材料相平衡的热力学建模
材料科学
2013-11-22 v1 软凝聚态物质
摘要
本文提出了对棒状向列相液晶与硬球纳米颗粒混合物的相平衡的理论研究。采用平均场热力学模型，其中相互作用被认为与接触数成正比，而接触数又与各组分的面积及面积分数成正比。研究表明，随着颗粒半径的增加，颗粒对各向同性 - 向列相转变的影响减弱；且对于大半径颗粒，混溶性随颗粒半径的增加而提高。
引用
@article{arxiv.1310.8653,
title = {Thermodynamic Modelling of Phase Equilibrium in Nanoparticles-Nematic Liquid Crystals Composites},
author = {Ezequiel R. Soulé and Linda Reven and Alejandro D. Rey},
journal= {arXiv preprint arXiv:1310.8653},
year = {2013}
}
备注
This is an Author's Accepted Manuscript of an article published in "Molecular Crystals and Liquid Crystals" (see reference), available online at: http://www.tandfonline.com/doi/abs/10.1080/15421406.2011.609447