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As a step towards a more realistic modeling of vibrations in single-molecule devices, we investigate the effects of charge-dependent vibrational frequencies and anharmonic potentials on electronic transport. For weak phonon relaxation, we…

介观与纳米尺度物理 · 物理学 2007-05-23 Jens Koch , Felix von Oppen

It is often intriguing experimentally to take stock of how conformational changes in the device configuration may impact the overall charge transport behavior of single-molecule junctions. Based on the allied approach of density functional…

介观与纳米尺度物理 · 物理学 2020-02-06 Talem Rebeda Roy , Arijit Sen

We study the effect of conformations on charge transport in a thin elastic tube. Using the Kirchhoff model for a tube with any given Poisson ratio, cross-sectional shape and intrinsic twist, we obtain a class of exact solutions for its…

量子物理 · 物理学 2009-11-13 Radha Balakrishnan , Rossen Dandoloff

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

介观与纳米尺度物理 · 物理学 2011-08-19 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

介观与纳米尺度物理 · 物理学 2015-03-17 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

The realization of molecular-based electronic devices depends to a large extent on the ability to mechanically stabilize the involved molecular bonds, while making use of efficient resonant charge transport through the device. Resonant…

介观与纳米尺度物理 · 物理学 2018-09-11 David Gelbwaser-Klimovsky , Alán Aspuru-Guzik , Michael Thoss , Uri Peskin

We study a Hamiltonian system of type describing a charged particle resonant interaction with an electromagnetic wave. We consider an ensemble of particles that repeatedly pass through the resonance with the wave, and study evolution of the…

等离子体物理 · 物理学 2017-10-13 A. V. Artemyev , A. I. Neishtadt , A. A. Vasiliev , D. Mourenas

Electronic transport in a model molecular device coupled to local phonon modes is theoretically analyzed. The method allows for obtaining an accurate approximation of the system's quantum state irrespective of the electron and phonon energy…

介观与纳米尺度物理 · 物理学 2007-10-10 Antonino La Magna , Ioannis Deretzis

We demonstrate large rectification ratios (> 100) in single-molecule junctions based on a metal-oxide cluster (polyoxometalate), using a scanning tunneling microscope (STM) both at ambient conditions and at low temperature. These…

介观与纳米尺度物理 · 物理学 2015-06-25 Siya Sherif , G Rubio-Bollinger , E. Pinilla-Cienfuegos , E. Coronado , J. C. Cuevas , Nicolas Agrait

We propose a simple scheme that describes accurately essential non-equilibrium effects in nanoscale electronics devices using equilibrium transport theory. The scheme, which is based on the alignment and dealignment of the junction…

介观与纳米尺度物理 · 物理学 2012-10-01 V. M. García-Suárez , J. Ferrer

The influence of an electron-vibrational coupling on the laser control of electron transport through a molecular wire that is attached to several electronic leads is investigated. These molecular vibrational modes induce an effective…

介观与纳米尺度物理 · 物理学 2007-05-23 Jörg Lehmann , Sigmund Kohler , Volkhard May , Peter Hänggi

In quantum dots or molecules with vibrational degrees of freedom the electron-vibron coupling renormalizes the electronic charging energy. For sufficiently strong coupling, the renormalized charging energy can become negative. Here, we…

介观与纳米尺度物理 · 物理学 2015-05-13 Teemu Ojanen , Friedrich C. Gethmann , Felix von Oppen

In this perspective, the various measures of electron correlation used in wavefunction theory, density functional theory and quantum information theory are briefly reviewed. We then focus on a more traditional metric based on dominant…

化学物理 · 物理学 2023-04-07 Róbert Izsák , Aleksei V Ivanov , Nick S. Blunt , Nicole Holzmann , Frank Neese

We theoretically study the nonequilibrium thermoelectric transport properties of a strongly-correlated molecule (or quantum dot) embedded in a tunnel junction. Assuming that the coupling of the molecule to the contacts is asymmetric, we…

介观与纳米尺度物理 · 物理学 2023-02-22 Anand Manaparambil , Ireneusz Weymann

Within a quasiclassical transport theory for 2D electron system we analyze a recently observed effect of microwave rectification at the boundary between two 2D metals of different carrier densities. Nonlinear response is employed to explain…

介观与纳米尺度物理 · 物理学 2007-05-23 Natalya A. Zimbovskaya

We study the mobility of a charged colloidal particle in a constant homogeneous electric field by means of computer simulations. The simulation method combines a lattice Boltzmann scheme for the fluid with standard Langevin dynamics for the…

软凝聚态物质 · 物理学 2007-06-20 Vladimir Lobaskin , Burkhard Duenweg , Christian Holm

Molecular systems can exhibit a complex, chemically tailorable inner structure which allows for targeting of specific mechanical, electronic and optical properties. At the single-molecule level, two major complementary ways to explore these…

介观与纳米尺度物理 · 物理学 2017-04-05 Rocco Gaudenzi , Maciej Misiorny , Enrique Burzurí , Maarten R. Wegewijs , Herre S. J. van der Zant

For molecules weakly coupled to leads the exact linear Kohn-Sham (KS) conductance can be orders of magnitude larger than the true linear conductance due to the lack of dynamical exchange-correlation (xc) corrections. In this work we show…

介观与纳米尺度物理 · 物理学 2013-07-23 S. Kurth , G. Stefanucci

Despite the wide existence of vesicles in living cells as well as their important applications like drug-delivery, the underlying mechanism of vesicle fusion/fission remains under debate. Here, we develop a constrained self-consistent field…

软凝聚态物质 · 物理学 2023-05-22 Luofu Liu , Chao Duan , Rui Wang

The coupling of the charge carriers passing through a molecule bridging two bulky conductors with local vibrational modes of the molecule, gives rise to distinct features in the electronic transport properties on one hand, and to…

介观与纳米尺度物理 · 物理学 2017-02-01 A. Ueda , Y. Utsumi , Y. Tokura , O. Entin-Wohlman , A. Aharony