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The electron transport properties of a four-terminal molecular device are computed within the framework of density functional theory and non-equilibrium Keldysh theory. The additional two terminals lead to new properties, including a…

介观与纳米尺度物理 · 物理学 2009-09-01 Kamal K. Saha , Wenchang Lu , J. Bernholc , Vincent Meunier

Non-equilibrium Green's functions (NEGF) formalism combined with extended Huckel (EHT) and charging model are used to study electrical conduction through single-molecule junctions. Analyzed molecular complex is composed of asymmetric…

介观与纳米尺度物理 · 物理学 2009-11-11 Kamil Walczak , Sergey Edward Lyshevski

The interrelationship between a material's structure and its properties lies at the heart of materials-related research. Finding how the changes of one affect the other is of primary importance in theoretical and computational materials…

介观与纳米尺度物理 · 物理学 2024-06-14 Hao Wang , Kah-Meng Yam , Zhuoling Jiang , Na Guo , Chun Zhang

This work builds upon previous studies of nonlinear dynamics in low-pressure capacitively coupled radio-frequency discharges, focusing on the electron power absorption mechanism in discharges with various geometric asymmetries. We present a…

等离子体物理 · 物理学 2025-04-29 Katharina Noesges , Thomas Mussenbrock

We investigate whether the entropic regularisation of the strictly-correlated-electrons problem can be used to build approximations for the kinetic correlation energy functional at large coupling strengths and, more generally, to gain new…

化学物理 · 物理学 2019-12-13 Augusto Gerolin , Juri Grossi , Paola Gori-Giorgi

We present a quaternion inspired formalism specifically developed to evaluate the intensity of the electrical current that traverses a single molecule connected to two semi-infinite electrodes as the applied external bias is varied. The…

介观与纳米尺度物理 · 物理学 2012-01-18 Augusto C. L. Moreira , Celso P. de Melo

Molecule-electrode interfaces in molecular electronic junctions are prone to chemical reactions, structural changes, and localized heating effects caused by electric current. These can be exploited for device functionality or may be…

介观与纳米尺度物理 · 物理学 2020-04-22 Riley J. Preston , Vincent F. Kershaw , Daniel S. Kosov

In this work we investigate the effects of the electron-electron interaction between a molecular junction and the metallic leads in time-dependent quantum transport. We employ the recently developed embedded Kadanoff-Baym method [Phys. Rev.…

介观与纳米尺度物理 · 物理学 2015-06-03 P. Myöhänen , R. Tuovinen , T. Korhonen , G. Stefanucci , R. van Leeuwen

We investigate the origin of asymmetry in various measured current-voltage (I-V) characteristics of molecules with no inherent spatial asymmetry, with particular focus on a recent break junction measurement. We argue that such asymmetry…

介观与纳米尺度物理 · 物理学 2009-11-10 F. Zahid , A. W. Ghosh , M. Paulsson , E. Polizzi , S. Datta

Here we present a theoretical analysis of inelastic effects on thermoelectric properties of molecular-scale junction in both linear and nonlinear response regimes. Considered device is composed of molecular quantum dot (with discrete energy…

介观与纳米尺度物理 · 物理学 2015-06-25 Kamil Walczak

We introduce a theoretical approach based on scattering theory and total energy methods that treats transport non-linearities, conformational changes and charging effects in molecular wires in a unified way. We apply this approach to…

介观与纳米尺度物理 · 物理学 2009-11-07 Eldon Emberly , George Kirczenow

An accurate non-gradient-expansion based correction to Thomas--Fermi is developed using solvable model. The used model is a system of $N$ non-interacting electrons moving independently in the Coulomb field of the nuclear charge. The…

量子物理 · 物理学 2015-06-04 Alexey Sergeev , Raka Jovanovic , Sabre Kais , Fahhad H Alharbi

Semiclassical spin-coherent kinetic equations can be derived from quantum theory with many different approaches (Liouville equation based approaches, nonequilibrium Green's functions techniques, etc.). The collision integrals turn out to be…

介观与纳米尺度物理 · 物理学 2013-06-24 Janik Kailasvuori , Matthias C. Lüffe

The charge inversion phenomenon is studied by molecular dynamics simulations, focusing on size and valence asymmetric salts, and a threshold of surface charge density for charge inversion. The charge inversion criteria by the…

软凝聚态物质 · 物理学 2009-11-10 Motohiko Tanaka

The linear transport properties of a model molecular transistor with electron-electron and electron-phonon interactions were investigated analytically and numerically. The model takes into account phonon modulation of the electronic energy…

介观与纳米尺度物理 · 物理学 2007-05-23 P. S. Cornaglia , D. R. Grempel , H. Ness

We present a combined theoretical approach to study the nonequilibrium transport properties of nanoscale systems coupled to metallic electrodes and exhibiting strong electron-phonon interactions. We use the Keldysh Green function formalism…

介观与纳米尺度物理 · 物理学 2015-05-20 R. C. Monreal , F. Flores , A. Martin-Rodero

Vibrationally inelastic electron transport through a flexible molecular junction is investigated. The study is based on a mechanistic model for a biphenyl molecule between two metal electrodes. Employing methods from electron-molecule…

介观与纳米尺度物理 · 物理学 2023-07-26 Martin Cizek , Michael Thoss , Wolfgang Domcke

Asymmetric line shapes can occur in the transmission function describing electron transport in the vicinity of a minimum caused by quantum interference effects. Such asymmetry can be used to increase the thermoelectric efficiency of…

介观与纳米尺度物理 · 物理学 2015-05-28 Robert Stadler , Troels Markussen

We study quantum corrections to conductivity in a 2D system with a smooth random potential and strong spin-orbit splitting of the spectrum. We show that the interference correction is positive and down to the very low temperature can exceed…

介观与纳米尺度物理 · 物理学 2007-05-23 Alexander P. Dmitriev , Igor V. Gornyi , Valentin Yu. Kachorovskii

Experiments studying vibrational effects on electronic transport through single molecules have observed several seemingly inconsistent behaviors, ranging from up to 30 harmonics of a vibrational frequency in one experiment, to an absence of…

介观与纳米尺度物理 · 物理学 2007-05-23 Vivek Aji , J. E. Moore , C. M. Varma