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The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…

统计力学 · 物理学 2020-07-01 Sheldon Goldstein , Joel L. Lebowitz , Roderich Tumulka , Nino Zanghi

We briefly review Boltzmann-Gibbs and nonextensive statistical mechanics as well as their connections with Fokker-Planck equations and with existing central limit theorems. We then provide some hints that might pave the road to the proof of…

统计力学 · 物理学 2009-09-29 Constantino Tsallis

We investigate the overdamped stochastic dynamics of a particle in an asymptotically flat external potential field, in contact with a thermal bath. For an infinite system size, the particles may escape the force field and diffuse freely at…

统计力学 · 物理学 2020-06-24 Erez Aghion , David A. Kessler , Eli Barkai

A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way…

高能物理 - 理论 · 物理学 2015-04-08 Yu-Lei Feng , Yi-Xin Chen

We develop a generalized theory of (meta)equilibrium statistical mechanics in the thermodynamic limit valid for both smooth and fractal phase spaces. In the former case, our approach leads naturally to Boltzmann-Gibbs standard…

统计力学 · 物理学 2009-11-11 V. Garcia-Morales , J. Pellicer

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

量子物理 · 物理学 2025-10-08 Smitarani Mishra , Shaon Sahoo

We study the consequences of introducing quantum group invariance in the formalism of nonextensive quantum statistical mechanics. We find that the corresponding thermodynamical system is equivalent to a Bose-Einstein gas in the…

凝聚态物理 · 物理学 2016-08-31 Marcelo R. Ubriaco

A multi-parametric version of the nonadditive entropy $S_{q}$ is introduced. This new entropic form, denoted by $S_{a,b,r}$, possesses many interesting statistical properties, and it reduces to the entropy $S_q$ for $b=0$, $a=r:=1-q$ (hence…

统计力学 · 物理学 2016-02-17 Evaldo M. F. Curado , Piergiulio Tempesta , Constantino Tsallis

For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…

统计力学 · 物理学 2009-11-10 A. Carati

We examine the question of whether the formal expressions of equilibrium statistical mechanics can be applied to time independent non-dissipative systems that are not in true thermodynamic equilibrium and are nonergodic. By assuming the…

统计力学 · 物理学 2007-11-09 Stephen R. Williams , Denis J. Evans

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

统计力学 · 物理学 2025-10-31 O. B. Ericok , J. K. Mason

We study a particle immersed in a heat bath, in the presence of an external force which decays at least as rapidly as $1/x$, for example a particle interacting with a surface through a Lennard-Jones or a logarithmic potential. As time…

统计力学 · 物理学 2019-01-09 Erez Aghion , David A. Kessler , Eli Barkai

We describe a particular approach for the construction of a nonequilibrium statistical ensemble formalism for the treatment of dissipative many-body systems. This is the so-called Nonequilibrium Statistical Operator Method, based on the…

统计力学 · 物理学 2016-08-31 R. Luzzi , A. R. Vasconcellos , J. G. Ramos

Understanding thermodynamics and statistical mechanics in the full general relativistic context is an open problem. I give tentative definitions of equilibrium state, mean values, mean geometry, entropy and temperature, which reduce to the…

广义相对论与量子宇宙学 · 物理学 2013-05-01 Carlo Rovelli

Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…

统计力学 · 物理学 2017-09-12 Robert H. Swendsen

During the past dozen years there have been numerous articles on a relation between entropy and probability which is non-additive and has a parameter $q$ that depends on the nature of the thermodynamic system under consideration. For $q=1$…

统计力学 · 物理学 2009-11-07 Michael Nauenberg

We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth $U_0$ around the origin. When the temperature is small compared to the trap depth ($\xi=k_B T/U_0 \ll 1$), there exists a range of…

统计力学 · 物理学 2020-10-21 Lucianno Defaveri , Celia Anteneodo , David A. Kessler , Eli Barkai

Thermodynamical properties of canonical and grand-canonical ensembles of the half-filled two-site Hubbard model have been discussed within the framework of the nonextensive statistics (NES). For relating the physical temperature $T$ to the…

统计力学 · 物理学 2009-11-10 Hideo Hasegawa

In this paper we propose a novel approach to construct macroscopic balance equations and constitutive equations describing various irreversible phenomena. It is based on the general principles of non-equilibrium thermodynamics and consists…

统计力学 · 物理学 2014-11-27 Liu Hong , Zaibao Yang , Yi Zhu , Wen-An Yong

After a brief review of the present status of nonextensive statistical mechanics, we present a conjectural scenario where mixing (characterized by the entropic index $q_{mix} \le 1$) and equilibration (characterized by the entropic index…

统计力学 · 物理学 2015-06-24 Constantino Tsallis , Ernesto P. Borges , Fulvio Baldovin