相关论文: Density fluctuations and entropy

We investigate the origin of the density depletion and enhanced density fluctuations that occur in water in the vicinity of an extended hydrophobic solute. We argue that both phenomena are remnants of the critical drying surface phase…

We find numerically that the sample to sample fluctuation of the entropy, $\Delta S$, is a tool more sensitive in distinguishing how from high temperature behaviors, than the corresponding fluctuation in the free energy. In 1+1 dimensions…

Entropy rate of sequential data-streams naturally quantifies the complexity of the generative process. Thus entropy rate fluctuations could be used as a tool to recognize dynamical perturbations in signal sources, and could potentially be…

Along recent decades, an intensive worldwide research activity is focusing both black holes and cosmos (e.g. the dark-energy phenomenon) on the basis of entropic approaches. The Boltzmann-Gibbs-based Bekenstein-Hawking entropy…

In some non-equilibrium systems, the distribution of entropy production $p(\Sigma)$ satisfies the detailed fluctuation theorem (DFT), $p(\Sigma)/p(-\Sigma)=\exp(\Sigma)$. When the distribution $p(\Sigma)$ shows time-dependency, the…

Shannon entropy in position ($S_{\rvec}$) and momentum ($S_{\pvec}$) spaces, along with their sum ($S_t$) are presented for unit-normalized densities of He, Li$^+$ and Be$^{2+}$ ions, spatially confined at the center of an impenetrable…

We propose a new concept of (S)-convergence applicable to numerical methods as well as other consistent approximations of the Euler system in gas dynamics. (S)-convergence, based on averaging in the spirit of Strong Law of Large Numbers,…

We reformulate the strong-interaction limit of electronic density functional theory in terms of a classical problem with a degenerate minimum. This allows us to clarify many aspects of this limit, and to write a general solution, which is…

We consider the possibilities for prediction of liquids' density under pressure basing on the inverse reduced fluctuations parameter, which is directly connected with the isothermal compressibility. This quantity can be determined basing on…

Reconstructing a density of states or similar distribution from moments or continued fractions is an important problem in calculating the electronic and vibrational structure of defective or non-crystalline solids. For single bands a…

We show a general phenomenon of the constrained functional value for densities satisfying general convexity conditions, which generalizes the observation in Bobkov and Madiman (2011) that the entropy per coordinate in a log-concave random…

Using arguments built on ergodicity, we derive an analytical expression for the Renyi entanglement entropies corresponding to the finite-energy density eigenstates of chaotic many-body Hamiltonians. The expression is a universal function of…

The information entropies in coordinate and momentum spaces and their sum ($S_r$, $S_k$, $S$) are evaluated for many nuclei using "experimental" densities or/and momentum distributions. The results are compared with the harmonic oscillator…

A novel formalism, called H-theory, is applied to the problem of statistical equilibrium of a hierarchical complex system with multiple time and length scales. In this approach, the system is formally treated as being composed of a small…

We review two definitions of temperature in statistical mechanics, $T_B$ and $T_G$, corresponding to two possible definitions of entropy, $S_B$ and $S_G$, known as surface and volume entropy respectively. We restrict our attention to a…

Sub-Gaussian and subexponential distributions are introduced and applied to study the fluctuation-response relation out of equilibrium. A bound on the difference in expected values of an arbitrary sub-Gaussian or subexponential physical…

In this paper, we study the superconvergence phenomenon in the free central limit theorem for identically distributed, unbounded summands. We prove not only the uniform convergence of the densities to the semicircular density but also their…

We consider the central limit theorem for stable laws in the case of the standardized sum of independent and identically distributed random variables with regular probability density function. By showing decay of different entropy…

A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…

We introduce a finite-time detailed fluctuation theorem for the environmental entropy of the form $\tilde P(\Delta S_{env}) = e^{\Delta S_{env}} \tilde P(-\Delta S_{env})$ for an appropriately weighted probability density of the external…