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The nudged elastic band (NEB) method is a commonly used approach for the calculation of minimum energy pathways of kinetic processes. However, the final paths obtained rely heavily on the nature of the initially chosen path. This often…

材料科学 · 物理学 2019-04-30 Jason M. Munro , Vincent S. Liu , Venkatraman Gopalan , Ismaila Dabo

The discovery of a minimum energy pathway (MEP) between metastable states is crucial for scientific tasks including catalyst and biomolecular design. However, the standard nudged elastic band (NEB) algorithm requires hundreds to tens of…

材料科学 · 物理学 2025-12-18 Pranav Kakhandiki , Sathya Chitturi , Daniel Ratner , Sean Gasiorowski

We show that neural networks can be optimized to represent minimum energy paths as continuous functions, offering a flexible alternative to discrete path-search methods such as Nudged Elastic Band (NEB). Our approach parameterizes reaction…

机器学习 · 计算机科学 2025-07-10 Kalyan Ramakrishnan , Lars L. Schaaf , Chen Lin , Guangrun Wang , Philip Torr

We present a modified version of the nudged elastic band (NEB) algorithm to find minimum energy paths con-necting two known configurations. We show that replacing the harmonic band-energy term with a discretized version of the…

计算物理 · 物理学 2024-06-19 Davide Mandelli , Michele Parrinello

The minimum energy path (MEP) describes the mechanism of reaction, and the energy barrier along the path can be used to calculate the reaction rate in thermal systems. The nudged elastic band (NEB) method is one of the most commonly used…

数值分析 · 数学 2025-03-24 Xuanyu Liu , Huajie Chen , Christoph Ortner

The nudged elastic band (NEB) method is one of the most widely used techniques for determining minimum-energy reaction pathways and activation barriers between known initial and final states. However, conventional implementations face steep…

计算物理 · 物理学 2025-10-21 Qiuhan Jia , Jiuyang Shi , Jian Sun

Accurate determination of transition states is central to an understanding of reaction kinetics. Double-endpoint methods where both initial and final states are specified, such as the climbing image nudged elastic band (CI-NEB), identify…

化学物理 · 物理学 2026-04-08 Rohit Goswami , Miha Gunde , Hannes Jónsson

Efficient algorithms for the calculation of minimum energy paths of magnetic transitions are implemented within the geodesic nudged elastic band (GNEB) approach. While an objective function is not available for GNEB and a traditional line…

A modification of the nudged elastic band (NEB) method is presented that enables stable optimisations to be run using both the limited-memory quasi-Newton (L-BFGS) and slow-response quenched velocity Verlet (SQVV) minimisers. The…

其他凝聚态物理 · 物理学 2009-11-10 Semen A. Trygubenko , David J. Wales

In this work, we propose a multi-scale protocol for routine theoretical studies of chemical reaction mechanisms. The initial reaction paths of our investigated systems are sampled using the Nudged-Elastic Band (NEB) method driven by a cheap…

化学物理 · 物理学 2023-07-26 Tomislav Piskor , Peter Pinski , Thilo Mast , Vladimir V. Rybkin

We present the incorporation of a surrogate Gaussian Process Regression (GPR) atomistic model to greatly accelerate the rate of convergence of classical Nudged Elastic Band (NEB) calculations. In our surrogate model approach, the cost of…

We present a modified nudged elastic band routine that can reduce the number of force calls by more than 50% for bands with non-uniform convergence. The method, which we call "dyNEB", dynamically and selectively optimizes states based on…

化学物理 · 物理学 2023-08-04 Per Lindgren , Georg Kastlunger , Andrew A. Peterson

The nudged elastic band (NEB) and Dimer methods are standard tools for computing minimum-energy paths and index-one saddle points in atomistic transition problems. They are increasingly driven by surrogate or learned force models, whose…

数值分析 · 数学 2026-05-26 Yifan Yu , Yangshuai Wang

The Chain-of-states(CoS) methods like nudge elastic band(NEB) method can be used to determine the minimum energy path (MEP) and transition state (TS) between two end local minima. However, the CoS methods are inefficient for difficult cases…

化学物理 · 物理学 2019-04-16 Sky , Zhang , Hai Xiao , Jun Li

The modeling of solid-state transformations, such as polymorphic transitions and chemical reactions in molecular crystals, is vital for many applications including drug design or the development of new synthesis methods. However, a…

化学物理 · 物理学 2025-06-17 Natalia Goncharova , Johannes Hoja

Popular methods for identifying transition paths between energy minima, such as the nudged elastic band and string methods, typically do not incorporate potential energy curvature information, leading to slow relaxation to the minimum…

计算物理 · 物理学 2019-03-11 Stela Makri , Christoph Ortner , James R. Kermode

Characterizing conformational transitions in physical systems remains a fundamental challenge, as traditional sampling methods struggle with the high-dimensional nature of molecular systems and high-energy barriers between stable states.…

化学物理 · 物理学 2025-09-22 Magnus Petersen , Gemma Roig , Roberto Covino

Path optimization methods have been widely used and highly successful for the analysis of chemical reactions. Yet, they can fail to capture intrinsically multidimensional features of potential energy surfaces (PES). We introduce the nudged…

统计力学 · 物理学 2026-04-23 Uday Sankar Manoj , Nicole Drew , Ismaila Dabo , Lukas Muechler

We present the Branch-and-Bound Performance Estimation Programming (BnB-PEP), a unified methodology for constructing optimal first-order methods for convex and nonconvex optimization. BnB-PEP poses the problem of finding the optimal…

最优化与控制 · 数学 2023-06-09 Shuvomoy Das Gupta , Bart P. G. Van Parys , Ernest K. Ryu

Because inorganic solid electrolytes are one of the key components for application to all-solid-state batteries, high-ionic-conductivity materials must be developed. Therefore, we propose a method of efficiently evaluating the activation…

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