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Intercalation of metal atoms at the SiC(0001)-graphene (Gr) interface can provide confined 2D metal layers with interesting properties. The intercalated Pb monolayer (ML) has shown the coexistence of the Gr(10x10)-moire and a stripe phase,…

材料科学 · 物理学 2024-12-10 Lin-Lin Wang , Shen Chen , Marek Kolmer , Yong Han , Michael C. Tringides

Intercalation is an established technique for tailoring the electronic structure of epitaxial graphene. Moreover, it enables the synthesis of otherwise unstable two-dimensional (2D) layers of elements with unique physical properties…

介观与纳米尺度物理 · 物理学 2022-06-29 Bharti Matta , Philipp Rosenzweig , Olaf Bolkenbaas , Kathrin Küster , Ulrich Starke

Intercalation is a robust approach for modulating the properties of epitaxial graphene on SiC and stabilizing two-dimensional (2D) intercalant layers at the graphene/SiC interface. In this work, we present synchrotron-based angle resolved…

介观与纳米尺度物理 · 物理学 2025-05-14 Bharti Matta , Philipp Rosenzweig , Kathrin Küster , Craig Polley , Ulrich Starke

A scalable platform to synthesize ultrathin heavy metals may enable high efficiency charge-to-spin conversion for next-generation spintronics. Here we report the synthesis of air-stable, epitaxially registered monolayer Pb underneath…

Graphene on SiC intercalated with two-dimensional metal layers, such as Pt, offers a versatile platform for applications in spintronics, catalysis, and beyond. Recent studies have demonstrated that Pt atoms can intercalate at the…

材料科学 · 物理学 2025-02-28 Letizia Ferbel , Stefano Veronesi , Antonio Rossi , Stiven Forti , Camilla Coletti , Stefan Heun

Confinement epitaxy beneath graphene stabilizes exotic material phases by restricting vertical growth and altering lateral diffusion, conditions unattainable on bare substrates. However, achieving long-range interfacial order while…

介观与纳米尺度物理 · 物理学 2026-02-19 Zamin Mamiyev , Niclas Tilgner , Narmina O. Balayeva , Dietrich R. T. Zahn , Thomas Seyller , Christoph Tegenkamp

Graphene on silicon carbide (SiC) bears great potential for future graphene electronic applications because it is available on the wafer-scale and its properties can be custom-tailored by inserting various atoms into the graphene/SiC…

材料科学 · 物理学 2018-11-07 T. A. de Jong , E. E. Krasovskii , C. Ott , R. M. Tromp , S. J. van der Molen , J. Jobst

Alkali metal intercalation of graphene layers has been of particular interest due to potential applications in electronics, energy storage, and catalysis. Rubidium (Rb) is one of the largest alkali metals and the one less investigated as…

Metal nanostructures confined between sp2 hybridized 2D materials and solid supports are attracting attention for their potential application in new nanotechnologies. Model studies under well-defined conditions are valuable for…

Recent intensive research on two-dimensional materials (2DMs) rekindle the interest in the intercalation of various atoms and molecules into layered compounds as a tool to manufacture 2DMs and tune their optoelectronic, magnetic and…

介观与纳米尺度物理 · 物理学 2025-07-10 Arkady V. Krasheninnikov , Yung-Chang Lin , Kazu Suenaga

The creation of atomically thin layers of non-exfoliable materials remains a crucial challenge, requiring the development of innovative techniques. Here, confinement epitaxy is exploited to realize two-dimensional gallium via intercalation…

Intercalation of atomic species through epitaxial graphene layers began only a few years following its initial report in 2004. The impact of intercalation on the electronic properties of the graphene is well known; however, the intercalant…

The influence of graphene on the assembly of intercalated material is studied using low-temperature scanning tunneling microscopy. Intercalation of Pt under monolayer graphene on Pt(111) induces a substrate reconstruction that is…

介观与纳米尺度物理 · 物理学 2019-02-28 Johannes Halle , Nicolas Néel , Jörg Kröger

The realization of air-stable 2D metals epitaxial to SiC and capped by graphene creates a potentially immense chemical space of 2D metals and alloys that could expand the variety of solid-state excitations unique to 2D metals beyond what is…

材料科学 · 物理学 2020-11-04 Yuanxi Wang , Vincent H. Crespi

We develop a strategy for graphene growth on Ru(0001) followed by silicon-layer intercalation that not only weakens the interaction of graphene with the metal substrate but also retains its superlative properties. This G/Si/Ru architecture,…

Magnesium intercalated 'quasi-freestanding' bilayer graphene on 6H-SiC(0001) (Mg-QFSBLG) has many favorable properties (e.g., highly n-type doped, relatively stable in ambient conditions). However, intercalation of Mg underneath monolayer…

Intercalation has proven to be a powerful tool for tailoring the electronic properties of freestanding graphene layers as well as for stabilizing the intercalated material in a two-dimensional configuration. This work examines Si…

We demonstrate the fabrication of an ultra thin gallium film, also known as gallenene, beneath epitaxial graphene on 6H-SiC under ambient conditions triggered by liquid gallium intercalation. Gallenene has been fabricated using the liquid…

Two-dimensional (2D) magnetic materials integrated with graphene offer a compelling platform for next-generation spintronic devices, yet nickel in its 2D form remains largely unexplored, due to fundamental synthesis limitations. Here, we…

Functional manipulation of graphene is an important topic in view of both fundamental researches and practical applications. In this study, we show that intercalation of 5$d$ transition metals in epitaxial graphene on SiC is a promising…

介观与纳米尺度物理 · 物理学 2019-03-06 Minsung Kim , Cai-Zhuang Wang , Michael C. Tringides , Myron Hupalo , Kai-Ming Ho
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