相关论文: On the distributed resistor-constant phase element…
As a generalization of integer-order calculus, fractional calculus has seen tremendous applications in the past few years especially in the description of anomalous viscoelastic properties, transport processes in complex media as well as in…
The dispersion coefficient of the constant phase element (CPE) is typically treated as an empirical fitting parameter in the analysis of impedance spectroscopy data, with no clear physical meaning. Here we seek to establish a energy-based…
This paper uses both experimental and numerical approaches to revisit the concept of current transfer length (CTL) in second-generation high-temperature superconductor coated conductors with a current flow diverter (CFD) architecture. The…
I discuss the strong link between the transmission line (TL) equation and the TL circuit model for the charging of an electrolyte-filled pore of finite length. In particular, I show how Robin and Neumann boundary conditions to the TL…
In this article, the piecewise-linear finite element method (FEM) is applied to approximate the solution of time-fractional diffusion equations on bounded convex domains. Standard energy arguments do not provide satisfactory results for…
We examine the stability of a 1D electrical transmission line in the simultaneous presence of PT-symmetry and fractionality. The array contains a binary gain/loss distribution $\gamma_{n}$ and a fractional Laplacian characterized by a…
We present theoretical models for the time-dependent voltage of an electrochemical cell in response to a current step, including effects of diffuse charge (or "space charge") near the electrodes on Faradaic reaction kinetics. The full model…
Analytical equations were found for interdigitated electrodes, which considered reversible electrode reactions and pure diffusion within confined spaces. A conformal transformation, obtained by the use of Jacobian elliptic functions, was…
The traditional transmission coefficient present in the original Landauer formulation, which is valid for quasi-static scenarios with working frequencies below the inverse of the electron transit time, is substituted by a novel…
We establish, in general terms, the conditions to be satisfied by a time-fractional approach formulation of the Poisson-Nernst-Planck model in order to guarantee that the total current across the sample be solenoidal, as required by the…
The Fractional Diffusion Equation (FDE) is a mathematical model that describes anomalous transport phenomena characterized by non-local and long-range dependencies which deviate from the traditional behavior of diffusion. Solving this…
Over the past decade, Finite Element Method (FEM) has served as a foundational numerical framework for approximating the terms of Time Series Expansion (TSE) as solutions to transient Partial Differential Equation (PDE). However, the…
A closed expression is derived for the probability distribution of the transfer matrix of a particle moving in a one-dimensional system with delta-correlated, weak disorder. The change in the distribution as a function of wire length is…
We develop a mathematical framework to analyze electrochemical impedance spectra in terms of a distribution of diffusion times (DDT) for a parallel array of random finite-length Warburg (diffusion) or Gerischer (reaction-diffusion) circuit…
An analytical solution to the problem of formation and propagation of large amplitude shock electromagnetic waves in strip transmission line (TL) based on the distributed semiconductor diode was obtained. This solution correctly takes into…
Consider the linear Boltzmann equation of radiative transfer in a half-space, with constant scattering coefficient $\sigma$. Assume that, on the boundary of the half-space, the radiation intensity satisfies the Lambert (i.e. diffuse)…
Electrochemical devices often charge both through Faradaic reactions and electric double layer formation. Here, we study these coupled processes in a model system of a long electrolyte-filled pore subject to a small suddenly-applied…
Batteries, supercapacitors, and several other electrochemical devices charge by accumulating ions in the pores of electrolyte-immersed porous electrodes. The charging of such devices has long been interpreted using equivalent circuits and…
The transient diffusion-limited current at a disk electrode following a change in interfacial ion concentration induced by a potential step is analyzed with direct relevance to chronoamperometric measurements. The mixed-boundary diffusion…
Tensor networks are employed to characterize the current fluctuations in one-dimensional diffusion-reaction systems. The representative system under study is a semiconducting material where holes and electrons constitute two types of charge…