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A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas…

化学物理 · 物理学 2014-12-05 Y. Fu , S. Poizeau , A. Bertei , C. Qi , A. Mohanram , J. D. Pietras , M. Z. Bazant

Increasing evidence suggests that the presence of mobile ions in perovskite solar cells can cause a current-voltage curve hysteresis. Steady state and transient current-voltage characteristics of a planar metal halide CH$_3$NH$_3$PbI$_3$…

应用物理 · 物理学 2018-04-24 N. E. Courtier , J. M. Foster , S. E. J. O'Kane , A. B. Walker , G. Richardson

The line tension of an electrolyte wetting a non-polar substrate is computed analytically and numerically. The results show that, depending on the value of the apparent contact angle, positive or negative line tension values may be…

化学物理 · 物理学 2014-11-06 Aaron Dörr , Steffen Hardt

We consider transport of dilute two-dimensional electrons, with temperature between Fermi and Debye temperatures. In this regime, electrons form a nondegenerate plasma with mobility limited by potential disorder. Different kinds of…

介观与纳米尺度物理 · 物理学 2009-06-11 D. S. Novikov

Lattice models are crucial for studying thermodynamic properties in many physical, biological and chemical systems. We investigate Lattice Restricted Primitive Model (LRPM) of electrolytes with different discretization parameters in order…

统计力学 · 物理学 2009-11-11 Maxim N. Artyomov , Anatoly B. Kolomeisky

The Debye temperature, T${_\theta}$=(h/2${\pi}$)/k${_B}$$\omega$$_\theta$, where the Debye frequency $\omega$$_\theta$ is integrated characteristic frequency of full phonon spectrum, $\alpha$$^2$($\omega$)F($\omega$). In the BCS theory,…

超导电性 · 物理学 2020-08-04 E. F. Talantsev

We consider laminar flow of incompressible electrolytes in long, straight channels driven by pressure and electro-osmosis. We use a Hilbert space eigenfunction expansion to address the general problem of an arbitrary cross section and…

流体动力学 · 物理学 2007-05-23 N. A. Mortensen , L. H. Olesen , H. Bruus

We present transport measurements of electrons on the surface of liquid helium in a microchannel device in which a constriction may be formed by a split-gate electrode. The surface electron current passing through the microchannel first…

介观与纳米尺度物理 · 物理学 2015-05-28 David Rees , Isao Kuroda , Claire Marrache-Kikuchi , Moritz Hofer , Paul Leiderer , Kimitoshi Kono

A new type of laser photodetachment (LPD) technique has been developed for the measurement of electron sheath thickness around an electrostatic probe and for the measurement of the length of collection region of photodetached electrons…

The low-temperature thermal properties of dielectric crystals are governed by acoustic excitations with large wavelengths that are well described by plane waves. This is the Debye model, which rests on the assumption that the medium is an…

统计力学 · 物理学 2015-05-13 Giulio Monaco , Stefano Mossa

Accurate theoretical results for interdigitated array of electrodes (IDAE) in semi-infinite cells can be found in the literature. However, these results are not always applicable when using finite cells. In this study, theoretical…

化学物理 · 物理学 2016-02-23 Cristian Guajardo , Sirimarn Ngamchana , Werasak Surareungchai

Ultrafast diffraction is the cutting-edge technique to extract the atomic temperature at femtosecond timescales, and further related quantities - in particular, electron-phonon coupling strength at elevated electronic temperatures. The…

材料科学 · 物理学 2026-05-15 N. Medvedev , M. Kopecky , J. Chalupsky , L. Juha

A solid ionic conductor with cation conductivity in the interelectrode region is studied. Due to their large size, the anions are considered fixed and form a homogeneous neutralizing electric background. The model can be used to describe…

统计力学 · 物理学 2022-07-04 I. Kravtsiv , G. Bokun , M. Holovko , N. Prokopchuk , D. di Caprio

The interfaces between metal electrodes and liquid electrolytes are prototypical in electrochemistry. That is why it is crucial to have a molecular and dynamical understating of such interfaces for both electrical properties and chemical…

化学物理 · 物理学 2023-10-06 Linnéa Andersson , Chao Zhang

We study the propagation of monochromatic surface waves on a turbulent flow. The flow is generated in a layer of liquid metal by an electromagnetic forcing. This forcing creates a quasi two-dimensional (2D) turbulence with strong vertical…

流体动力学 · 物理学 2015-11-19 Pablo Gutiérrez , Sébastien Aumaitre

A recently proposed local second contact value theorem [Henderson D., Boda D., J. Electroanal. Chem., 2005, 582, 16] for the charge profile of an electric double layer is used in conjunction with the existing Monte Carlo data from the…

软凝聚态物质 · 物理学 2012-07-16 L. B. Bhuiyan , D. Henderson , S. Sokołowski

Palladium diselenide (PdSe2) is a recently isolated layered material that has attracted a lot of interest for the pentagonal structure, the air stability and the electrical properties largely tunable by the number of layers. In this work,…

应用物理 · 物理学 2020-08-25 A. Di Bartolomeo , F. Urban , A. Pelella , A. Grillo , M. Passacantando , X. Liu , F. Giubileo

An effect of membrane surface charge on mechanical properties of the phospholipid bilayer membrane and pores formation is considered. It is shown that the outer and inner surfaces of the phospholipid membrane is always subject to tension,…

生物物理 · 物理学 2017-09-28 M. Pekker , M. N. Shneider , M. Keidar

Study of the dephasing in electronic systems is not only important for probing the nature of their ground states, but also crucial to harnessing the quantum coherence for information processing. In contrast to well-studied conventional…

介观与纳米尺度物理 · 物理学 2017-07-14 Jian Liao , Yunbo Ou , Haiwen Liu , Ke He , Xucun Ma , Qi-Kun Xue , Yongqing Li

The distribution of ions at the air/water interface plays a decisive role in many natural processes. It is generally understood that polarizable ions with low charge density are surface-active, implying they sit on top of the water surface.…

化学物理 · 物理学 2022-10-05 Yair Litman , Kuo-Yang Chiang , Takakazu Seki , Yuki Nagata , Mischa Bonn