相关论文: Pauli principle in polaritonic chemistry
The connection between the intrinsic angular momentum (spin) of particles and the quantum statistics is established by considering the response of identical particles to a common background radiation field. For this purpose, the Hamiltonian…
We have explained and comprehensively illustrated in Part I that the generalized Pauli constraints suggest a natural extension of the concept of active spaces. In the present Part II, we provide rigorous derivations of the theorems involved…
Two bound, entangled fermions form a composite boson, which can be treated as an elementary boson as long as the Pauli principle does not affect the behavior of many such composite bosons. The departure of ideal bosonic behavior is…
The Pauli exclusion principle plays an important role in many-body fermion systems preventing them from collapsing by repulsion. For example, the Pauli principle causes a repulsive potential at short distances between two $\alpha$…
In the last decade, much theoretical research has focused on studying the strong coupling between organic molecules (or quantum emitters, in general) and light modes. The description and prediction of polaritonic phenomena emerging in this…
An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…
In recent years tremendous progress in the field of light-matter interactions has unveiled that strong coupling to the modes of an optical cavity can alter chemistry even at room temperature. Despite these impressive advances, many…
It has been conjectured that the Pauli exclusion principle alone may be responsible for a particular geometric arrangement of confined systems of identical fermions even when there is no interaction between them. These geometric structures,…
Quantum state tomography is a fundamental problem in quantum computing. Given $n$ copies of an unknown $N$-qubit state $\rho \in \mathbb{C}^{d \times d},d=2^N$, the goal is to learn the state up to an accuracy $\epsilon$ in trace distance,…
Quantum gravity may modify the fundamental symmetries that govern identical particles. In particular, noncommutative spacetime frameworks predict deformations of Bose and Fermi statistics. Here we develop a relativistic quantum field theory…
Whether it occurs in superconductors, helium-3 or inside a neutron star, fermionic superfluidity requires pairing of fermions, particles with half-integer spin. For an equal mixture of two states of fermions ("spin up" and "spin down"),…
A manifestation of the Pauli Exclusion Principle is observed when fermions are trapped in the ground state of a 2D harmonic oscillator trap at very low temperatures. This non-interaction of fermions results in the formation of Pauli…
Despite recent numerical evidence, one of the fundamental theoretical mysteries of polaritonic chemistry is how and if collective strong coupling can induce local changes of the electronic structure to modify chemical properties. Here we…
Recent experiments have demonstrated that polariton formation provides a novel strategy for modifying local molecular processes when a large ensemble of molecules is confined within an optical cavity. Herein, a numerical strategy based on…
The Mott effect describes the dissolution of bound states in a dense partially ionized plasma. It happens when the ionization potential depression, owing to effects of correlation and degeneracy, compensates the binding energy of the bound…
We investigate the control of interacting matter through strong coupling to a single electromagnetic mode, such as the photon mode in a Fabry-Perot or split-ring cavity. For this purpose, we analyze the exact effective theory for the…
Low-lying collective states in nuclei are investigated in the framework of the interacting boson model using an ensemble of random many-body interactions. It is shown that whenever the number of bosons is sufficiently large compared to the…
Polaritonic chemistry investigates the possible modification of chemical and photochemical reactions by means of strong light-matter coupling in optical cavities, as demonstrated in numerous experiments over the last few years. These…
Fermionic natural occupation numbers (NON) do not only obey Pauli's famous exclusion principle but are even further restricted to a polytope by the generalized Pauli constraints, conditions which follow from the fermionic exchange…
The state of a system in classical mechanics can be uniquely reconstructed if we know the positions and the momenta of all its parts. In 1958 Pauli has conjectured that the same holds for quantum mechanical systems. The conjecture turned…