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相关论文: Accelerating core-level $GW$ calculations by combi…

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We present a scalable implementation of the $GW$ approximation using Gaussian atomic orbitals to study the valence and core ionization spectroscopies of molecules. The implementation of the standard spectral decomposition approach to the…

化学物理 · 物理学 2021-12-06 Daniel Mejia-Rodriguez , Alexander Kunitsa , Edoardo Aprà , Niranjan Govind

The analytic continuation of the GW self-energy from the imaginary to the real energy axis is a central difficulty for approaches exploiting the favourable properties of response functions at imaginary frequencies. Within a scheme merging…

材料科学 · 物理学 2019-12-16 Ivan Duchemin , Xavier Blase

We present GW calculations of molecules, ordered and disordered solids and interfaces, which employ an efficient contour deformation technique for frequency integration, and do not require the explicit evaluation of virtual electronic…

材料科学 · 物理学 2015-01-14 Marco Govoni , Giulia Galli

Many-body perturbation theory is a powerful method to simulate electronic excitations in molecules and materials starting from the output of density functional theory calculations. By implementing the theory efficiently so as to run at…

材料科学 · 物理学 2022-08-11 Victor Wen-zhe Yu , Marco Govoni

We report an all-electron, atomic orbital (AO) based, two-component (2C) implementation of the $GW$ approximation (GWA) for closed-shell molecules. Our algorithm is based on the space-time formulation of the GWA and uses analytical…

化学物理 · 物理学 2023-09-11 Arno Förster , Erik van Lenthe , Edoardo Spadetto , Lucas Visscher

The $GW$ approximation has recently gained increasing attention as a viable method for the computation of deep core-level binding energies as measured by X-ray photoelectron spectroscopy (XPS). We present a comprehensive benchmark study of…

化学物理 · 物理学 2022-06-14 Jiachen Li , Ye Jin , Patrick Rinke , Weitao Yang , Dorothea Golze

Within the framework of many-body perturbation theory based on Green's functions, the $GW$ approximation has emerged as a pivotal method for computing quasiparticle energies and excitation spectra. However, its high computational cost and…

化学物理 · 物理学 2025-12-25 Yueyang Zhang , Wei Wu , Peifeng Su

The $GW$ approximation has been recently gaining popularity among the method for simulating molecular core-level X-ray photoemission spectra. Traditionally, $GW$ core-level binding energies have been computed using either the cc-pV$n$Z or…

化学物理 · 物理学 2022-07-13 Daniel Mejia-Rodriguez , Alexander Kunitsa , Edoardo Aprà , Niranjan Govind

The GW method, which can describe accurately electronic excitations, is one of the most widely used ab initio electronic structure technique and allows the physics of both molecular and condensed phase materials to be studied. However, the…

Various many-body perturbation theory techniques for calculating electron behavior rely on {\it W}, the screened Coulomb interaction. Computing {\it W} requires complete knowledge of the dielectric response of the electronic system, and the…

材料科学 · 物理学 2021-06-30 John Vinson , Eric L. Shirley

In this paper we analyse the efficiency, precision, and accuracy of computing elastic nucleon-nucleon (NN) scattering amplitudes with the wave-packet continuum discretisation method (WPCD). This method provides approximate scattering…

核理论 · 物理学 2022-06-20 Sean B. S. Miller , Andreas Ekström , Christian Forssén

The GW approximation is widely used for reliable and accurate modeling of single-particle excitations. It also serves as a starting point for many theoretical methods, such as its use in the Bethe-Salpeter equation (BSE) and dynamical…

计算物理 · 物理学 2024-03-25 Weiwei Gao , Zhao Tang , Jijun Zhao , James R. Chelikowsky

Recently, the $GW$ approach has emerged as a valuable tool for computing deep core-level binding energies as measured in X-ray photoemission spectroscopy. However, $GW$ fails to accurately predict shake-up satellite features, which arise…

化学物理 · 物理学 2024-12-24 Jannis Kockläuner , Dorothea Golze

This paper investigates the stochastic optimization problem with a focus on developing scalable parallel algorithms for deep learning tasks. Our solution involves a reformation of the objective function for stochastic optimization in neural…

机器学习 · 计算机科学 2020-04-09 Pengzhan Guo , Zeyang Ye , Keli Xiao , Wei Zhu

The $GW$ method is widely used for calculating the electronic band structure of materials. The high computational cost of $GW$ algorithms prohibits their application to many systems of interest. We present a periodic, low-scaling and highly…

The GW approximation of many-body perturbation theory is an accurate method for computing electron addition and removal energies of molecules and solids. In a canonical implementation, however, its computational cost is $O(N^4)$ in the…

化学物理 · 物理学 2021-04-21 Jan Wilhelm , Dorothea Golze , Leopold Talirz , Jürg Hutter , Carlo A. Pignedoli

Similar to other electron correlation methods, many-body perturbation theory methods based on Green functions, such as the so-called $GW$ approximation, suffer from the usual slow convergence of energetic properties with respect to the size…

In this work, we benchmark tensor hypercontraction (THC)-accelerated fully self-consistent $GW$ (sc$GW$) and vertex-corrected self-consistent $GW$ (sc$GW\Gamma$) methods for predicting molecular first ionization potentials (IPs). The vertex…

强关联电子 · 物理学 2026-04-29 Munkhorgil Wang , Ming Wen , Pavel Pokhilko , Chia-Nan Yeh , Miguel A. Morales , Dominika Zgid

The Continuous Wavelet Transform (CWT) is an effective tool for feature extraction in acoustic recognition using Convolutional Neural Networks (CNNs), particularly when applied to non-stationary audio. However, its high computational cost…

音频与语音处理 · 电气工程与系统科学 2025-12-01 Dang Thoai Phan , Tuan Anh Huynh , Van Tuan Pham , Cao Minh Tran , Van Thuan Mai , Ngoc Quy Tran

$GW$ is an accurate method for computing electron addition and removal energies of molecules and solids. In a conventional $GW$ implementation, however, its computational cost is $O(N^4)$ in the system size $N$, which prohibits its…

化学物理 · 物理学 2021-03-22 Jan Wilhelm , Patrick Seewald , Dorothea Golze
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