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The great tunability of the properties of halide perovskites presents new opportunities for optoelectronic applications as well as significant challenges associated with exploring combinatorial chemical spaces. In this work, we develop a…

材料科学 · 物理学 2021-09-23 Arun Mannodi-Kanakkithodi , Maria K. Y. Chan

Expanding the pool of stable halide perovskites with attractive optoelectronic properties is crucial to addressing current limitations in their performance as photovoltaic (PV) absorbers. In this article, we demonstrate how a…

材料科学 · 物理学 2023-10-23 Jiaqi Yang , Panayotis Manganaris , Arun Mannodi-Kanakkithodi

Halide perovskites have been extensively studied as materials of interest for optoelectronic applications. There is a major emphasis on ways to tailor the stability, defect behavior, electronic band structure, and optical absorption in…

材料科学 · 物理学 2023-09-29 Jiaqi Yang , Arun Mannodi-Kanakkithodi

Stability is one of the key issues in mixed-halide perovskite alloys which are promising in emergent optoelectronics. Previous density-functional-theory (DFT) and machine learning studies indicate that the formation-energy convex hulls of…

Halide perovskites have emerged as one of the most interesting materials for optoelectronic applications due to their favorable properties, such as defect-tolerance and long charge carrier lifetimes, which are attributed to their dynamic…

材料科学 · 物理学 2023-11-20 Julia Wiktor , Erik Fransson , Dominik Kubicki , Paul Erhart

Halide perovskites (HPs) are widely viewed as promising photovoltaic and light-emitting materials for their suitable band gaps in the visible spectrum. Density functional theory (DFT) calculations employing (semi)local exchange-correlation…

材料科学 · 物理学 2022-12-06 Jiyuan Yang , Tianyuan Zhu , Shi Liu

Among emerging energy materials, halide and chalcogenide perovskites have garnered significant attention over the last decade owing to the abundance of their constituent species, low manufacturing costs, and their highly tunable…

材料科学 · 物理学 2025-11-11 Rushik Desai , Junyeong Ahn , Alejandro Strachan , Arun Mannodi-Kanakkithodi

The electronic structure and energetic stability of A$_2$BX$_6$ halide compounds with the cubic and tetragonal variants of the perovskite-derived K$_2$PtCl$_6$ prototype structure are investigated computationally within the frameworks of…

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

材料科学 · 物理学 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

Organic-inorganic metal halide perovskites (HaPs) are intensively studied for their light-harvesting properties. Owing to the interplay between strong electron-electron interaction and spin-orbit coupling (SOC), their quantitative…

材料科学 · 物理学 2021-11-02 Cecilia Vona , Dmitrii Nabok , Claudia Draxl

The structural, electrical, optical, and mechanical characteristics of the lead-free halide double perovskites Cs2NaTlX6 X = F, Cl, Br are calculated by utilizing PBE functional within generalized gradient approximation GGA under the…

材料科学 · 物理学 2023-02-07 Mohammed Mehedi Hasan , Nazmul Hasan , Alamgir Kabir

Accurate prediction of electronic band gaps in halide perovskites using density functional theory is crucial for optoelectronic applications. Standard hybrid functionals like HSE and PBE0 are becoming computationally accessible, yet can…

In recent years, hybrid organic-inorganic metal halides have been at the forefront of materials research. Typically, the functional (e.g., optoelectronic) properties of hybrid halides are derived from the inorganic structural part, whereas…

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

材料科学 · 物理学 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

Two critical limitations of organic-inorganic lead halide perovskite materials for solar cells are their poor stability in humid environments and inclusion of toxic lead. In this study, high-throughput density functional theory (DFT)…

材料科学 · 物理学 2019-04-12 Ryan Jacobs , Guangfu Luo , Dane Morgan

Metal halide perovskite semiconductors have outstanding optoelectronic properties. Although these perovskites are defect-tolerant electronically, defects hamper their long-term stability and cause degradation. Density functional theory…

材料科学 · 物理学 2021-09-02 Haibo Xue , Geert Brocks , Shuxia Tao

Halide perovskites constitute a chemically-diverse class of crystals with great promise as photovoltaic absorber materials, featuring band gaps between about 1 and 3.5 eV depending on composition. Their diversity calls for a general…

材料科学 · 物理学 2019-10-23 Linn Leppert , Tonatiuh Rangel , Jeffrey B. Neaton

We screen a large chemical space of perovskite alloys for systems with the right properties to accommodate a morphotropic phase boundary (MPB) in their composition-temperature phase diagram, a crucial feature for high piezoelectric…

材料科学 · 物理学 2015-06-17 Rickard Armiento , Boris Kozinsky , Geoffroy Hautier , Marco Fornari , Gerbrand Ceder

Like single perovskites, halide double perovskites (HDP) have truly emerged as efficient optoelectronic materials since they display superior stability and are free of toxicity. However, challenges still exist due to either wide and…

材料科学 · 物理学 2023-09-13 Mayank Gupta , Susmita Jana , B. R. K. Nanda

Perovskite materials have become ubiquitous in many technologically relevant applications, ranging from catalysts in solid oxide fuel cells to light absorbing layers in solar photovoltaics. The thermodynamic phase stability is a key…

材料科学 · 物理学 2018-06-05 Wei Li , Ryan Jacobs , Dane Morgan
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