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We provide a unified theoretical approach to the quantum dynamics of absorption of single photons and subsequent excitonic energy transfer in photosynthetic light-harvesting complexes. Our analysis combines a continuous mode <n>-photon…

化学物理 · 物理学 2018-02-20 Herman C. H. Chan , Omar E. Gamel , Graham R. Fleming , K. Birgitta Whaley

We present a rigorous theoretical description of excitonic dynamics in molecular light-harvesting aggregates photoexcited by weak-intensity radiation of arbitrary properties. While the interaction with light is included up to the second…

化学物理 · 物理学 2021-01-01 Veljko Janković , Tomáš Mančal

The recently suggested possibility that weak vibronic transitions can be excitonically enhanced in light-harvesting complexes is studied in detail. A vibronic exciton dimer model which includes ground state vibrations is investigated using…

化学物理 · 物理学 2014-10-09 Jan Schulze , Magne Torbjörnsson , Oliver Kühn , Tõnu Pullerits

In this paper we consider dynamics of a molecular system subjected to external pumping by a light source. Within a completely quantum mechanical treatment, we derive a general formula, which enables to asses effects of different light…

生物物理 · 物理学 2012-01-30 Tomas Mancal , Leonas Valkunas

The dynamics of pigment-pigment and pigment-protein interactions in light-harvesting complexes is studied with a novel approach which combines molecular dynamics (MD) simulations with quantum chemistry (QC) calculations. The MD simulations…

生物物理 · 物理学 2009-11-07 Ana Damjanovic , Ioan Kosztin , Klaus Schulten

In this work we study the first step in photosynthesis for the limiting case of a single photon interacting with photosystem II (PSII). We model our system using quantum trajectory theory, which allows us to consider not only the average…

生物物理 · 物理学 2022-08-10 Robert L. Cook , Liwen Ko , K. Birgitta Whaley

We present a theory that efficiently describes the quantum dynamics of an electronic excitation that is coupled to a continuous, highly structured phonon environment. Based on a stochastic approach to non-Markovian open quantum systems, we…

量子物理 · 物理学 2009-11-05 Jan Roden , Alexander Eisfeld , Wolfgang Wolff , Walter T. Strunz

Non-Hermitian quantum systems, governed by nonunitary evolution, offer powerful tools for manipulating quantum states through engineered loss. A prime example is coherent absorption, where quantum states undergo phase-dependent partial or…

We explore energy transfer in a generic three-level system, which is coupled to three non-equilibrium baths. Built on the concept of quantum heat engine, our three-level model describes non-equilibrium quantum processes including…

量子物理 · 物理学 2016-02-17 Dazhi Xu , Chen Wang , Yang Zhao , Jianshu Cao

We describe a method for simulating exciton dynamics in protein-pigment complexes, including effects from charge transfer as well as fluorescence. The method combines the hierarchical equations of motion, which are used to describe quantum…

化学物理 · 物理学 2022-11-23 Thomas P. Fay , David T. Limmer

Until recently it was believed that photosynthesis, a fundamental process for life on earth, could be fully understood with semi-classical models. However, puzzling quantum phenomena have been observed in several photosynthetic…

We present a continuous-variable experimental analysis of a two-photon Fock state of free-propagating light. This state is obtained from a pulsed non-degenerate parametric amplifier, which produces two intensity-correlated twin beams.…

量子物理 · 物理学 2007-05-23 Alexei Ourjoumtsev , Rosa Tualle-Brouri , Philippe Grangier

We demonstrate and study the enhancement of intermediate-field two-photon absorption by shaped femtosecond pulses having spectral phases of antisymmetric nature. The intermediate-field regime corresponds to pulse intensities, where the…

原子物理 · 物理学 2015-05-14 Lev Chuntonov , Leonid Rybak , Andrey Gandman , Zohar Amitay

We investigate the dynamics of a single two-level atom, which interacts with pulses propagating in two spatial-modes (right and left) and frequency-continuum. Using Heisenberg equations of motion, we present the explicit analytical…

量子物理 · 物理学 2012-08-08 Yimin Wang , Jiří Minář , Valerio Scarani

Excitation of a model photosynthetic molecular aggregate by incoherent sunlight is systematically examined. For a closed system, the excited state coherence induced by the sunlight oscillates with an average amplitude that is inversely…

化学物理 · 物理学 2014-08-25 Jan Olšina , Arend G. Dijkstra , Chen Wang , Jianshu Cao

We investigate a quantum dot (QD) system coupled to a vibrational environment with a super-Ohmic spectral density and weakly to a leaky cavity mode, a model relevant for semiconductor-based single-photon sources. The phonon coupling induces…

介观与纳米尺度物理 · 物理学 2024-12-31 Sebastian Toivonen , Kimmo Luoma

Light harvesting as the first step in photosynthesis is of prime importance for life on earth. For a theoretical description of photochemical processes during light harvesting, spectral densities are key quantities. They serve as input…

化学物理 · 物理学 2021-08-25 Sayan Maity , Pooja Sarngadharan , Vangelis Daskalakis , Ulrich Kleinekathöfer

Experimental and theoretical evidence point out to the crucial role of specific resonant intramolecular vibrational modes in the interpretation of long-lived coherences observed in two-dimensional spectra of some natural and synthetic light…

化学物理 · 物理学 2020-07-15 Leonardo F. Calderón , Leonardo A. Pachón

We discuss a model of quantum photosynthesis with degeneracy in the light-harvesting system. We consider interaction of excitons in chromophores with light and phonons (vibrations of environment). These interactions have dipole form but are…

生物物理 · 物理学 2016-03-24 S. V. Kozyrev , I. V. Volovich

We report two-photon resonance fluorescence of an individual semiconductor artificial atom. By non-linearly driving a single quantum dot via a two-photon transition, we probe the linewidth of the two-photon processes and show that, similar…

介观与纳米尺度物理 · 物理学 2016-04-20 P. -L. Ardelt , M. Koller , T. Simmet , L. Hanschke , A. Bechtold , A. Regler , J. Wierzbowski , H. Riedl , K. Müller , J. J. Finley
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