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In this work, we investigate and compare the electronic structures of SrTiO3 and KTaO3 under ultraviolet (UV) light induced electron doping. Using angle-resolved photoemission spectroscopy (ARPES), the evolution of the surface electronic…

Zinc oxynitride (ZnO$_x$N$_y$) has recently emerged as a highly promising band gap-tunable semiconductor material for optoelectronic applications. In this study, a novel DC reactive sputtering protocol was developed to fabricate…

材料科学 · 物理学 2023-02-17 Kiran Jose , J. G. Anjana , Venu Anand , Aswathi R. Nair

Negative compressibility is a sign of thermodynamic instability of open or non-equilibrium systems. In quantum materials consisting of multiple mutually coupled subsystems, the compressibility of one subsystem can be negative if it is…

We investigate numerically the impact of the electron-phonon scattering on the optical properties of a perovskite material (CH3NH3PbI3). Using non-equilibrium Green functions formalism, we calculate the local density-of-states for several…

The structural, vibrational, and optical properties of Rb$_2$TeBr$_6$ have been investigated under high pressure using synchrotron X-ray diffraction, Raman spectroscopy, photoluminescence (PL), and optical absorption measurements. At…

Nanostructures have become an attractive subject due to many applications, particularly the photonic bandgap effect observed in photonic crystals. Nevertheless, the fabrication of such structures remains a challenge because of accurate…

光学 · 物理学 2008-01-29 F. Lacour , A. Sabac , M. Spajer

In optoelectronic applications, metal halide perovskites (MHPs) are compelling materials because of their highly tuneable and intensely competitive optical properties. Colloidal synthesis enables the controlled formation of various…

Atomistically detailed computational studies of nanocrystals, such as those derived from the promising lead-halide perovskites, are challenging due to the large number of atoms and lack of symmetries to exploit. Here, focusing on…

材料科学 · 物理学 2022-10-05 Giulia Biffi , Yeongsu Cho , Roman Krahne , Timothy C. Berkelbach

The electronic orbital characteristics at the band edges plays an important role in determining the electrical, optical and defect properties of perovskite photovoltaic materials. It is highly desirable to establish the relationship between…

材料科学 · 物理学 2020-06-01 Gang Tang , Vei Wang , Yajun Zhang , Philippe Ghosez , Jiawang Hong

Understanding the atomic structure and structural instability of organic-inorganic hybrid perovskites is the key to appreciate their remarkable photoelectric properties and failure mechanism. Here, using low-dose imaging technique by…

We develop techniques to study the temperature dependent localization, thermalization, and the effects of phonon scattering on the excitons in halide perovskites from the analysis of the emission spectra. The excitonic Urbach edge, when…

材料科学 · 物理学 2022-11-23 Kingshuk Mukhuti , Arnab Mandal , Basabendra Roy , Sayan Bhattacharyya , Bhavtosh Bansal

Solid solutions of perovskite oxides (KNbO3)1-x+(La2NiMnO6)x (x=0, 0.1, 0.2 and 0.3) with a variation of band gap (1.33-3.6 eV) have been introduced as a promising photovoltaic absorber. The structural characterization of the prepared…

材料科学 · 物理学 2018-09-21 Md S. Sheikh , A. Dutta , T. K. Bhowmik , S. K. Ghosh , S. K. Rout , T. P. Sinha

Metal-halide perovskites are promising materials for future optoelectronic applications. One intriguing property, important for many applications, is the tunability of the band gap via compositional engineering. While experimental reports…

材料科学 · 物理学 2019-06-27 Shuxia Tao , Ines Schmidt , Geert Brocks , Junke Jiang , Ionut Tranca , Klaus Meerholz , Selina Olthof

Defects in halide perovskites play an essential role in determining the efficiency and stability of the resulting optoelectronic devices. Here, we present a systematic study of intrinsic point defects in six primary metal halide…

材料科学 · 物理学 2022-01-03 Haibo Xue , Geert Brocks , Shuxia Tao

In the rapidly progressing field of organometal halide perovskites, the dimensional reduction could open up new opportunities for device applications. Herein, taking the recently synthesized trimethylsulfonium lead triiodide…

介观与纳米尺度物理 · 物理学 2020-06-08 Muhammad Ejaz Khan , Juho Lee , Seongjae Byeon , Yong-Hoon Kim

We report a method for fabricating nanogaps directly with electron beam lithography (EBL). The primary resolution-limit of EBL, electron back-scattering, is reduced dramatically by using a thin-film as a substrate. We show that this…

介观与纳米尺度物理 · 物理学 2009-11-11 Michael D. Fischbein , Marija Drndic

A density functional theory study of the structural and electronic properties and relative stability of narrow SP3 silicon nanotubes of different growth orientations is presented. All nanotubes studied and their corresponding wire…

介观与纳米尺度物理 · 物理学 2012-12-05 Alon Hever , Jonathan Bernstein , Oded Hod

Experimental measurements clearly reveal the presence of bulk superconductivity in the CsPbxBi4-xTe6 (0.3=<x=<1.0) materials, i.e. the first member of the thermoelectric series of Cs[PbmBi3Te5+m], these materials have the layered…

超导电性 · 物理学 2015-12-09 R. X. Zhang , H. X. Yang , H. F. Tain , G. F. Chen , S. L. Wu , L. L. Wei , J. Q. Li

Halide perovskites perform remarkably in optoelectronic devices including tandem photovoltaics. However, this exceptional performance is striking given that perovskites exhibit deep charge carrier traps and spatial compositional and…

Corner-shared ABX$_3$ perovskites have long featured prominently in solid-state chemistry and condensed matter physics. Still, the joint understanding of their two main subgroups-halides and oxides-has not been fully developed. Indeed,…

材料科学 · 物理学 2021-09-01 Xin-Gang Zhao , Zhi Wang , Oleksandr I. Malyi , Alex Zunger