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We investigate the cascade decay mechanism for ultrafast intersystem crossing mediated by the spin-orbit coupling in transition-metal complexes. A quantum-mechanical description of the cascading process that occurs after photoexcitation is…

强关联电子 · 物理学 2010-08-16 Jun Chang , A. J. Fedro , Michel van Veenendaal

Multi-electron dynamics in atoms and molecules very often occur on sub- to few-femtosecond timescales. The available intensities of extreme-ultraviolet (XUV) attosecond pulses have previously only allowed the time-resolved investigation of…

Bulk-sensitive high-resolution photoemission was carried out on a prototype 3d1 metallic Sr1-xCaxVO3. In a strong contrast to so far reported results, the bulk spectral functions are revealed to be insensitive to x. The conservation of the…

强关联电子 · 物理学 2007-05-23 A. Sekiyama , H. Fujiwara , S. Imada , H. Eisaki , S. I. Uchida , K. Takegahara , H. Harima , Y. Saitoh , S. Suga

The advent of ultrashort soft x-ray pulse sources permits the use of established gas phase spectroscopy methods to investigate ultrafast photochemistry in isolated molecules with element and site specificity. In the present study, we…

化学物理 · 物理学 2019-11-26 Ludger Inhester , Zheng Li , Xiaolei Zhu , Nikita Medvedev , Thomas J. A. Wolf

The nonlinear interaction of x-rays with matter is at the heart of understanding and controlling ultrafast molecular dynamics from an atom-specific viewpoint, providing new scientific and analytical opportunities to explore the structure…

The magnetic exchange coupling between magnetic impurities and a superconductor induce so-called Yu-Shiba-Rusinov (YSR) states which undergo a quantum phase transition (QPT) upon increasing the exchange interaction beyond a critical value.…

Femtosecond extreme ultraviolet wave packet interferometry (XUV-WPI) was applied to study resonant inter-atomic Coulombic decay (ICD) in the HeNe dimer. The high demands on phase stability and sensitivity for vibronic XUV-WPI of…

The potential of mean-field decomposition techniques in interpreting electronic transitions in molecules is explored, particularly, the usefulness of these for offering computational signatures of different classes of such excitations. When…

化学物理 · 物理学 2022-02-14 Janus J. Eriksen

Energy level structure and direct light absorption in a cylindrical quantum dot, having thin falciform cross section, are studied within the framework of the adiabatic approximation. An analytical expression for the energy spectrum of the…

介观与纳米尺度物理 · 物理学 2015-05-08 Karen G. Dvoyan , David B. Hayrapetyan , Eduard M. Kazaryan , Ani A. Tshantshapanyan

We investigate the possibility to monitor the dynamics of autoionizing states in real time and control the yields of different ionization channels in helium by simulating XUV-pump IR-probe experiments focused on the N=2 threshold. The XUV…

原子物理 · 物理学 2015-05-18 Luca Argenti , Eva Lindroth

We employ ultrafast pump-probe spectroscopy to directly monitor electron tunneling between discrete orbital states in a pair of spatially separated quantum dots. Immediately after excitation, several peaks are observed in the pump-probe…

Nonlinear wave-mixing in solids with ultrafast x-rays can provide new insight into complex electronic dynamics of materials. Here, tabletop-based attosecond noncollinear four-wave mixing (FWM) spectroscopy using one extreme ultraviolet…

High-order above-threshold ionization (HATI) spectrum in IR+XUV two-color laser fields has been investigated. We found that the quantum features corresponding to the absorption of the XUV photon is well illustrated by a peculiar dip…

原子物理 · 物理学 2018-12-05 Facheng Jin , Fei Li , Jing Chen , Xiaojun Liu , Bingbing Wang

Emergent phenomena at complex-oxide interfaces have become a vibrant field of study in the past two decades due to the rich physics and a wide range of possibilities for creating new states of matter and novel functionalities for potential…

材料科学 · 物理学 2024-06-19 C. -T. Kuo , G. Conti , J. E. Rault , C. M. Schneider , S. Nemšák , A. X. Gray

Ultrashort optical pulses can trigger a variety of non-equilibrium processes in magnetic thin films affecting electrons and spins on femtosecond timescales. In order to probe the charge and magnetic degrees of freedom simultaneously, we…

We describe numerically the ionization process induced by linearly and circularly polarized XUV attosecond laser pulses on an aligned atomic target, specifically, the excited state…

原子物理 · 物理学 2021-05-26 Juan J. Omiste , Lars Bojer Madsen

Conical intersections between electronic potential energy surfaces are paradigmatic for the study of non-adiabatic processes in the excited states of large molecules. However, since the corresponding dynamics occurs on a femtosecond…

原子物理 · 物理学 2021-06-14 Filippo Maria Gambetta , Chi Zhang , Markus Hennrich , Igor Lesanovsky , Weibin Li

The development of high-intensity ultrashort laser pulses unlocks the potential of pump-probe spectroscopy in sub-femtosecond timescale. Notably, subcycle pump pulses can generate electronic states unreachable by conventional multicycle…

强关联电子 · 物理学 2025-06-17 Kazuya Shinjo , Shigetoshi Sota , Seiji Yunoki , Takami Tohyama

Isotopic substitution in molecular systems can affect fundamental molecular properties including the energy position and spacing of electronic, vibrational and rotational levels, thus modifying the dynamics associated to their coherent…

With an expected energy of 7.6(5) eV, $^{229}$Th possesses the lowest excited nuclear state in the landscape of all presently known nuclei. The energy corresponds to a wavelength of about 160 nm and would conceptually allow for an optical…

仪器与探测器 · 物理学 2017-04-27 Benedict Seiferle , Lars von der Wense , Mustapha Laatiaoui , Peter G. Thirolf