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We analyze atomic photoexcitation into the discrete states by twisted photons, or photons carrying extra orbital angular momentum along their direction of propagation. From the angular momentum and parity considerations, we are able to…

原子物理 · 物理学 2018-03-07 Andrei Afanasev , Carl E. Carlson , Maria Solyanik

Tracking the multifarious ultrafast electronic and structural changes occurring in a molecule during a photochemical transformation is a challenging endeavor that benefits from recent experimental and computational progress in time-resolved…

Excitons are two-particle correlated bound states that are formed due to Coulomb interaction between single-particle holes and electrons. In the solid-state, cooperative interactions with surrounding quasiparticles can strongly tailor the…

Thermally activated delayed fluorescence (TADF) emitters consisting of donor and acceptor molecules are potentially highly interesting for electroluminescence (EL) applications. Their strong fluorescence emission is considered to be due to…

We report the direct observation of quantum coupling in individual quantum dot molecules and its manipulation using static electric fields. A pronounced anti-crossing of different excitonic transitions is observed as the electric field is…

介观与纳米尺度物理 · 物理学 2007-05-23 H. J. Krenner , M. Sabathil , E. C. Clark , A. F. Kress , D. Schuh , M. Bichler , G. Abstreiter , J. J. Finley

Moir\'e superlattices provide a highly tunable and versatile platform to explore novel quantum phases and exotic excited states ranging from correlated insulators1-17 to moir\'e excitons7-10,18. Scanning tunneling microscopy has played a…

Many atomic and molecular systems of fundamental interest possess resonance frequencies in the extreme ultraviolet (XUV) where laser technology is limited and radiation sources have traditionally lacked long-term phase coherence. Recent…

Photoinduced phase transitions from insulating to metallic states, accompanied by structural re-arrangements, have been recently reported in complex transition-metal oxides. However, the optical control of a purely electronic phase…

Conical intersections (CI) between molecular potential energy surfaces with non-vanishing non-adiabatic couplings generally occur in any molecule consisting of at least three atoms. They play a fundamental role in describing the molecular…

Ionization with ultrashort pulses in the extreme ultraviolet (XUV) regime can be used to prepare an ion in a superposition of spin--orbit substates. In this work, we study the coherence properties of such a superposition, created by…

The open inner-shell electronic structure of lanthanides with large magnetic moments gives rise to a rich spectrum of transitions available for laser cooling, trapping, and coherent control. Despite this, the large number of ultraviolet…

The photoinduced switching of Fe(II)-based spin-crossover complexes from singlet to quintet takes place at ultrafast time scales. This a priori spin-forbidden transition triggered numerous time-resolved experiments of solvated samples to…

We analyze electronically excited nuclear wave functions and their coherence when subjecting a molecule to the action of natural, pulsed incoherent solar-like light, and to that of ultrashort coherent light assumed to have the same center…

量子物理 · 物理学 2015-06-12 Alex C. Han , Moshe Shapiro , Paul Brumer

We theoretically investigate the role of complex dipole phase in the attosecond probing of charge migration. The iodobromoacetylene ion (ICCBr$^+$) is considered as an example, in which one can probe charge migration by accessing both the…

化学物理 · 物理学 2022-02-23 Yuki Kobayashi , Daniel M. Neumark , Stephen R. Leone

Accurate photodissociation cross sections have been computed for transitions from the X $^1\Sigma^+$ ground electronic state of CS to six low-lying excited electronic states. New ab initio potential curves and transition dipole moment…

We reveal for the first time that ultraviolet (UV) observables can diagnose quantum phase transitions (QPTs). In a class of holographic models exhibiting metal-insulator transitions, we study two types of UV observables -- high-frequency…

高能物理 - 理论 · 物理学 2025-08-20 Fang-Jing Cheng , Zhe Yang , Yi Ling , Jian-Pin Wu , Zhou-Jian Cao , Peng Liu

We experimentally investigate various processes present in the photoassociative interaction of an ultracold atomic sample with shaped femtosecond laser pulses. We demonstrate the photoassociation of pairs of rubidium atoms into…

Electronic excitations and ionisations produced by electron impact are key processes in the radiation-induced damage mechanisms in materials of biological relevance, underlying important medical and technological applications, including…

化学物理 · 物理学 2021-08-04 Pablo de Vera , Isabel Abril , Rafael Garcia-Molina

Nonlinear spectroscopy in the extreme ultraviolet (EUV) and soft x-ray spectral range offers the opportunity for element selective probing of ultrafast dynamics using core-valence transitions (Mukamel et al., Acc. Chem. Res. 42, 553…