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Interacting bosonic quasiparticles are the cornerstone for exploring many-body physics and nonlinear quantum phenomena in correlated light-matter systems. Strongly interacting dipolar excitons in van der Waals heterostructures have…

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

化学物理 · 物理学 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

We present a perturbation approach rooted in time-dependent density-functional theory to calculate electron hole (eh)-pair excitation spectra during the non-adiabatic vibrational damping of adsorbates on metal surfaces. Our analysis for the…

化学物理 · 物理学 2017-11-22 Simon P. Rittmeyer , Jörg Meyer , Karsten Reuter

Strong coupling of molecular vibrations to an infrared cavity mode affects their nature by creating dressed polariton states. We show how the single and double vibrational polariton manifolds may be controlled by varying the cavity coupling…

量子物理 · 物理学 2016-05-10 Prasoon Saurabh , Shaul Mukamel

Volkov states are exact solutions of the Dirac equation in the presence of an arbitrary plane wave. Volkov states, as well as free photon states, are not stable in the presence of the background plane-wave field but "decay" as…

高能物理 - 唯象学 · 物理学 2021-07-28 T. Podszus , A. Di Piazza

We propose a novel approach to calculate dynamical processes at ultrafast time scale in molecules in which vibrational and electronic motions are strongly mixed. The relevant electronic orbitals and their interactions are described by a…

强关联电子 · 物理学 2009-11-07 L. Arrachea , A. A. Aligia , G. E. Santoro

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

介观与纳米尺度物理 · 物理学 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

We consider the N-body problem in a layered geometry containing cold polar molecules with dipole moments that are polarized perpendicular to the layers. A harmonic approximation is used to simplify the hamiltonian and bound state properties…

量子气体 · 物理学 2012-04-02 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

Dipole-dipole interaction between two two-level `atoms' in photonic crystal nanocavity is investigated based on finite-difference time domain algorithm. This method includes both real and virtual photon effects and can be applied for…

量子物理 · 物理学 2011-12-30 Yong-Gang Huang , Gengyan Chen , Chong-Jun Jin , W. M. Liu , Xue-Hua Wang

We propose a very sensitive method for measuring the electric dipole moment of the electron using polar molecules embedded in a cryogenic solid matrix of inert-gas atoms. The polar molecules can be oriented in the $\hat{\rm{z}}$ direction…

原子物理 · 物理学 2018-01-29 A. C. Vutha , M. Horbatsch , E. A. Hessels

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

化学物理 · 物理学 2024-06-19 Lorenz S. Cederbaum

In this work, we present a proof-of-concept investigation of non-equilibrium chemical reaction dynamics at a molecule-electrode interface, driven out of equilibrium by an applied votage bias and mediated by a confined, enhanced vacuum…

化学物理 · 物理学 2025-12-15 Yaling Ke

A nonadiabatic scheme for the description of the coupled electron and nuclear motions in the ozone molecule was proposed recently. An initial coherent nonstationary state was prepared as a superposition of the ground state and the excited…

原子与分子团簇 · 物理学 2015-06-18 A. Perveaux , D. Lauvergnat , B. Lasorne , F. Gatti , M. A. Robb , G. J. Halász , Á. Vibók

Instead of starting from a theoretically motivated form of the color dipole cross section in the dipole picture of deep inelastic scattering, we start with a parametrization of the deep inelastic structure function for electromagnetic…

高能物理 - 唯象学 · 物理学 2015-06-19 Yu Seon Jeong , C. S. Kim , Minh Vu Luu , Mary Hall Reno

We introduce a general approach for the simulation of quantum vibrational states of (symmetric and asymmetric) double-well potentials in molecules and materials for thermodynamic and spectroscopic applications. The method involves solving…

We present an ab initio method for computing vibro-polariton and phonon-polariton spectra of molecules and solids coupled to the photon modes of optical cavities. We demonstrate that if interactions of cavity photon modes with both nuclear…

化学物理 · 物理学 2025-12-23 John Bonini , Iman Ahmadabadi , Johannes Flick

Inspired by the recent experimental observation of strongly coupled polaritons in a Moir\'e heterobilayer, we study a model of dipole-interacting excitons localized on sites of a lattice and coupled to planar cavity photons. We calculate…

强关联电子 · 物理学 2022-03-25 Alexander Edelman , Peter B. Littlewood

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

化学物理 · 物理学 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

Strong coupling of molecules to the vacuum field of micro cavities can modify the potential energy surfaces opening new photophysical and photochemical reaction pathways. While the influence of laser fields is usually described in terms of…

量子物理 · 物理学 2016-02-08 Markus Kowalewski , Kochise Bennett , Shaul Mukamel

Novel equations for the electric dipole polarizability $\alpha_{_{E1}}$ of low-lying excited states in atomic nuclei -- and the related $(-2)$ moment of the total photo-absorption cross section, $\sigma_{_{-2}}$ -- are inferred in terms of…

核理论 · 物理学 2024-03-12 José Nicolás Orce , Cebo Ngwetsheni