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The phase separation of oppositely-charged polyelectrolytes in solution is of current interest . In this work we study the driving force for polyelectrolyte complexation using molecular dynamics simulations. We calculate the potential of…

生物大分子 · 定量生物学 2020-01-08 Aditya N. Singh , Arun Yethiraj

A crucial aspect in the simulation of electrochemical interfaces consists in treating the distribution of electronic charge of electrode materials that are put in contact with an electrolyte solution. Recently, it has been shown how a…

材料科学 · 物理学 2024-07-16 Andrea Grisafi , Mathieu Salanne

Nonnegative tensors arise very naturally in many applications that involve large and complex data flows. Due to the relatively small requirement in terms of memory storage and number of operations per step, the (shifted) higher-order power…

数值分析 · 数学 2019-08-27 Stefano Cipolla , Michela Redivo-Zaglia , Francesco Tudisco

We develop a computational method based on Dissipative Particle Dynamics (DPD) that introduces solvent hydrodynamic interactions to coarse-grained models of solutes, such as ions, molecules, or polymers. DPD-solvent (DPDS) is a fully…

软凝聚态物质 · 物理学 2024-05-24 Tine Curk

We derive a new formulation to calculate the excess chemical potential of a fraction of $N_1$ particles interacting with $N_2$ particles of a different species. The excess chemical potential is calculated numerically from first principles…

天体物理学 · 物理学 2008-11-26 Christophe Winisdoerffer , Gilles Chabrier , Gilles Zérah

An extended first-principles molecular dynamics (FPMD) method based on Kohn-Sham scheme is proposed to elevate the temperature limit of the FPMD method in the calculation of dense plasmas. The extended method treats the wave functions of…

等离子体物理 · 物理学 2016-09-08 Shen Zhang , Hongwei Wang , Wei Kang , Ping Zhang , Xian-Tu He

We study multivariate numerical integration of smooth functions in weighted Sobolev spaces with dominating mixed smoothness $\alpha\geq 2$ defined over the $s$-dimensional unit cube. We propose a new quasi-Monte Carlo (QMC)-based quadrature…

数值分析 · 数学 2019-12-09 Josef Dick , Takashi Goda , Takehito Yoshiki

Despite the modern level of development of computational chemistry methods and techno-logical progress, fast and accurate determination of solvation free energy remains a huge problem for physical chemists. In this paper, we describe two…

Molecular dynamics (MD) simulations allow atomistic insights into chemical and biological processes. Accurate MD simulations require computationally demanding quantum-mechanical calculations, being practically limited to short timescales…

Smoothed particle hydrodynamics (SPH) discretization techniques are generalized to develop a method, smoothed particle interpolation (SPI), for solving initial value problems of systems of non-hydrodynamical nature. Under this approach, SPH…

天体物理学 · 物理学 2009-10-22 Pablo Laguna

Hybrid particle-field molecular dynamics combines standard molecular potentials with density-field models into a computationally efficient methodology that is well-adapted for the study of mesoscale soft matter systems. Here, we introduce a…

计算物理 · 物理学 2020-07-06 Sigbjørn Løland Bore , Michele Cascella

A new algorithm is introduced to integrate the equations of rotational motion. The algorithm is derived within a leapfrog framework and the quantities involved into the integration are mid-step angular momenta and on-step orientational…

计算物理 · 物理学 2007-05-23 Igor P. Omelyan

The accurate prediction of solvation free energy is of significant importance as it governs the behavior of solutes in solution. In this work, we apply a variety of machine learning techniques to predict and analyze the alchemical free…

化学物理 · 物理学 2024-11-11 Mingjun Han , Yukai Zhang , Taotao Yu , Guodong Du , ChiYung Yam , Ho-Kin Tang

Machine learning potentials have emerged as a means to enhance the accuracy of biomolecular simulations. However, their application is constrained by the significant computational cost arising from the vast number of parameters compared to…

Coarse-grained modeling and efficient computer simulations are critical to the study of complex molecular processes with many degrees of freedom and multiple spatiotemporal scales. Variational implicit-solvent model (VISM) for biomolecular…

化学物理 · 物理学 2022-10-26 Shuang Liu , Zirui Zhang , Li-Tien Cheng , Bo Li

Theory of solutions in energy representation (ER method) developed by Matubayasi and Nakahara provides with an approximate way of calculating solvation free energies (or, identically, the excess chemical potentials) from atomistic…

统计力学 · 物理学 2015-02-17 Andrey I. Frolov

The transport of excess protons and hydroxide ions in water underlies numerous important chemical and biological processes. Accurately simulating the associated transport mechanisms ideally requires utilizing ab initio molecular dynamics…

化学物理 · 物理学 2023-08-15 Austin O. Atsango , Tobias Morawietz , Ondrej Marsalek , Thomas E. Markland

The development and implementation of increasingly accurate methods for electronic structure calculations mean that, for many atomistic simulation problems, treating light nuclei as classical particles is now one of the most serious…

材料科学 · 物理学 2016-02-12 Venkat Kapil , Joost VandeVondele , Michele Ceriotti

Multiscale and inhomogeneous molecular systems are challenging topics in the field of molecular simulation. In particular, modeling biological systems in the context of multiscale simulations and exploring material properties are driving a…

计算物理 · 物理学 2017-12-06 Horacio V. Guzman , Christoph Junghans , Kurt Kremer , Torsten Stuehn

Magnetic field in the solar corona is usually extrapolated from photospheric vector magnetogram using a nonlinear force-free field (NLFFF) model. NLFFF extrapolation needs a considerable effort to be devoted for its numerical realization.…

太阳与恒星天体物理 · 物理学 2015-06-04 Chaowei Jiang , Xueshang Feng