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Using first-principles electronic structure calculations, we have extensively studied the electronic and magnetic properties of alkali sodium superoxide (NaO2) in comparison with that of potassium superoxide (KO2) both at high and low…

材料科学 · 物理学 2024-02-19 Sarajit Biswas , Pratim Banerjee , Molly De Raychaudhury

While unusual normal state properties, such as non-Fermi liquid behavior of the resistivity, are commonly associated with strong quantum fluctuations, evidence for its presence inside the superconducting dome are much scarcer. In this…

We investigated the temperature-dependent evolution of the electronic structure of the Jeff,1/2 Mott insulator Sr2IrO4 using optical spectroscopy. The optical conductivity spectra $\sigma(\omega)$ of this compound has recently been found to…

强关联电子 · 物理学 2009-10-23 S. J. Moon , Hosub Jin , W. S. Choi , J. S. Lee , S. S. A. Seo , J. Yu , G. Cao , T. W. Noh , Y. S. Lee

Using polarized neutron diffraction and x-ray resonant magnetic scattering (XRMS) techniques, multiple phase transitions were revealed in an underdoped, non-superconducting Eu(Fe$_{1-x}$Ir$_{x}$)$_{2}$As$_{2}$ ($\mathit{x}$ = 0.06) single…

强关联电子 · 物理学 2016-08-06 W. T. Jin , Y. Xiao , Y. Su , S. Nandi , W. H. Jiao , G. Nisbet , S. Demirdis , G. H. Cao , Th. Brückel

The effect of substituting iron and zinc for cobalt in CaBaCo$_4$O$_7$ has been investigated using neutron diffraction and x-ray absorption spectroscopy. The orthorhombic distortion present in the parent compound CaBaCo$_4$O$_7$ decreases…

材料科学 · 物理学 2020-09-01 V. Cuartero , J. Blasco , G. Subías , J. García , J. A. Rodríguez-Velamazán , C. Ritter

We use synchrotron x-ray diffraction and electrical transport under pressure to probe both the magnetism and the structure of single crystal NiS2 across its Mott-Hubbard transition. In the insulator, the low-temperature antiferromagnetic…

强关联电子 · 物理学 2011-09-02 Yejun Feng , R. Jaramillo , A. Banerjee , J. M. Honig , T. F. Rosenbaum

We report on a 59Co NMR investigation of the trigonal cobaltate Ca3Co2O6 carried out on a single crystal, providing precise determinations of the electric field gradient and chemical shift tensors, and of the internal magnetic fields at the…

强关联电子 · 物理学 2015-05-20 G. Allodi , R. De Renzi , S. Agrestini , C. Mazzoli , M. R. Lees

The possible existence of topological insulators in cubic pyrochlore iridates A$_{2}$Ir$_{2}$O$_{7}$ (A = Y or rare-earth elements) is investigated by taking into account the strong spin-orbit coupling and trigonal crystal field effect. It…

强关联电子 · 物理学 2015-03-14 Bohm-Jung Yang , Yong Baek Kim

We report a Fe K\beta x-ray emission spectroscopy study of local magnetic moments in the rare-earth doped iron pnictide Ca_{1-x}RE_xFe_2As_2 (RE=La, Pr, and Nd). In all samples studied the size of the Fe local moment is found to decrease…

超导电性 · 物理学 2013-01-28 H. Gretarsson , S. R. Saha , T. Drye , J. Paglione , Jungho Kim , D. Casa , T. Gog , W. Wu , S. R. Julian , Young-June Kim

We present a muon spin relaxation study of the Mott transition in BaCoS_2 using two independent control parameters: (i) pressure p to tune the electronic bandwidth and (ii) Ni-substitution x on the Co site to tune the band filling. For both…

The checkerboard lattice, with alternating 'crossed' plaquettes, serves as the two dimensional analog of the pyrochlore lattice. The corner sharing plaquette structure leads to a hugely degenerate ground state, and no magnetic order, for…

强关联电子 · 物理学 2017-01-24 Nyayabanta Swain , Pinaki Majumdar

Iridates provide a fertile ground to investigate correlated electrons in the presence of strong spin-orbit coupling. Bringing these systems to the proximity of a metal-insulator quantum phase transition is a challenge that must be met to…

Muon-spin relaxation results on the pyrochlore iridate Nd$_2$Ir$_2$O$_7$ are reported. Spontaneous coherent muon-spin precession below the metal-insulator transition (MIT) temperature of about 33 K is observed, indicating the appearance of…

The insulator-metal transition in single crystal La(5/8-y)Pr(y)Ca(3/8)MnO3 with y=0.35 was studied using synchrotron x-ray diffraction, electric resistivity, magnetic susceptibility, and specific heat measurements. Despite the dramatic drop…

凝聚态物理 · 物理学 2009-10-31 V. Kiryukhin , B. G. Kim , V. Podzorov , S-W. Cheong , T. Y. Koo , J. P. Hill , I. Moon , Y. H. Jeong

The Mott insulator Ca$_2$RuO$_4$ exhibits a rare insulator-to-metal transition (IMT) induced by DC current. While structural changes associated with this transition have been tracked by neutron diffraction, Raman scattering, and x-ray…

Three low-valence layered nickelates with general formula La$_3$Ni$_2$O$_{7-\delta}$ ($\delta$=0.0, 0.5, 1) are studied by ab initio techniques. Both the insulating and metallic limits are analyzed, together with the compound at the Mott…

强关联电子 · 物理学 2012-06-29 Victor Pardo , Warren E. Pickett

We investigate the metal-to-insulator phase transition driven by the density-density electronic interaction in the quarter-filled model on a cubic lattice with two orbitals split by a crystal field. We show that a systematic consideration…

强关联电子 · 物理学 2023-05-30 M. Vandelli , J. Kaufmann , V. Harkov , A. I. Lichtenstein , K. Held , E. A. Stepanov

We report on the structural, magnetic, and electronic properties of two new double-perovskites synthesized under high pressure; Pb2CaOsO6 and Pb2ZnOsO6. Upon cooling below 80 K, Pb2CaOsO6 simultaneously undergoes a metal--insulator…

We investigate the effect of partial replacement of extended 5d Ir4+ sites by localized 3d Cr3+ moments on the magnetocaloric properties of Y2Ir2O7 (YIO) pyrochlore iridates. We find that Y2Ir2-xCrxO7 (YICO) undergoes cluster glass…

强关联电子 · 物理学 2021-10-08 Vinod Kumar Dwivedi , Prabhat Mandal , Soumik Mukhopadhyay

We show that metal-insulator transition in Pr0.5Ca0.5Mn1-xCrxO3 (x = 0.015-0.025) is unstable against thermal cycling. Insulator-metal transition shifts down and low temperature resistivity increases each time when the sample is cycled…

材料科学 · 物理学 2009-11-07 R. Mahendiran , B. Raveau , M. Hervieu , C. Michel , A. Maignan