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Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

统计力学 · 物理学 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

The Jarzynski equality is generalized to situations in which nonequilibrium systems are subject to a feedback control. The new terms that arise as a consequence of the feedback describe the mutual information content obtained by measurement…

统计力学 · 物理学 2015-05-13 Takahiro Sagawa , Masahito Ueda

Two approaches to small-scale and quantum thermodynamics are fluctuation relations and one-shot statistical mechanics. Fluctuation relations (such as Crooks' Theorem and Jarzynski's Equality) relate nonequilibrium behaviors to equilibrium…

The celebrated Evans-Searles, respectively Gallavotti-Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper,…

数学物理 · 物理学 2025-08-05 T. Benoist , L. Bruneau , V. Jakšić , A. Panati , C. -A. Pillet

In the derivation of fluctuation relations, and in stochastic thermodynamics in general, it is tacitly assumed that we can measure the system perfectly, i.e., without measurement errors. We here demonstrate for a driven system immersed in a…

统计力学 · 物理学 2016-11-30 C. W. Wächtler , P. Strasberg , T. Brandes

We present a derivation of the Jarzynski identity and the Crooks fluctuation theorem for systems governed by deterministic dynamics that conserves the canonical distribution such as Hamiltonian dynamics, Nose-Hoover dynamics, Nose-Hoover…

统计力学 · 物理学 2009-11-11 Elisabeth Scholl-Paschinger , Christoph Dellago

For classical systems driven out of equilibrium, Crooks derived a relation (the Crooks-Jarzynski relation), whose special cases include a relation (the Crooks relation) equivalent to the Kawasaki non-linear response relation. We derive a…

统计力学 · 物理学 2014-05-26 Hiroshi Matsuoka

Two identities in statistical mechanics involving entropy differences (or ratios of density of states) at constant energy are derived. The first provides a nontrivial extension of the Jarzynski equality to the microcanonical ensemble [C.…

统计力学 · 物理学 2009-11-10 Artur B. Adib

We study two non-equilibrium work fluctuation theorems, the Crooks' theorem and the Jarzynski equality, for a test system coupled to a spatially extended heat reservoir whose degrees of freedom are explicitly modeled. The sufficient…

统计力学 · 物理学 2010-02-22 Punyabrata Pradhan , Yariv Kafri , Dov Levine

The Jarzynski equality equates the mean of the exponential of the negative of the work (per fixed temperature) done by a changing Hamiltonian on a system, initially in thermal equilibrium at that temperature, to the ratio of the final to…

高能物理 - 理论 · 物理学 2012-07-17 Don N. Page

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

Detailed fluctuation theorem, a microscopic version of the steady state fluctuation theorem, has been proposed by Jarzynski and demonstrated in the case of Hamiltonian systems weakly coupled with reservoirs. We show that an identical…

统计力学 · 物理学 2010-07-20 K. Gururaj , G. Raghavan , M. C. Valsakumar

Determining the work which is supplied to a system by an external agent, provides a crucial step in any experimental realization of transient fluctuation relations. This, however, poses a problem for quantum systems, where the standard…

统计力学 · 物理学 2014-05-15 Gentaro Watanabe , B. Prasanna Venkatesh , Peter Talkner

To define the work performed on a driven quantum system in a physically sound way has turned out to be a truly non-trivial task, except in some special cases of limited applicability. This topic has been in a focus of intense research…

统计力学 · 物理学 2012-12-27 Jukka P. Pekola , Paolo Solinas , Alexander Shnirman , Dmitri V. Averin

The validity of the Jarzynski equation for a very simple, exactly solvable quantum system is analyzed. The implications of two different definitions of work proposed in the literature are investigated. The first one derives from…

统计力学 · 物理学 2009-11-11 A. Engel , R. Nolte

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

统计力学 · 物理学 2020-10-13 Jianzhong Wu

Equilibrium thermodynamics is combined with Jarzynski's irreversible work theorem to quantify the excess entropy produced by irreversible processes. The resulting rectified form of the second law parallels the first law, in the sense that…

统计力学 · 物理学 2007-05-23 Dor Ben-Amotz , J. M. Honig

In the presence of feedback control by "Maxwell's demon," the second law of thermodynamics and the nonequilibrium equalities such as the Jarzynski equality need to be generalized. In this paper, we derive the generalized Jarzynski…

统计力学 · 物理学 2015-05-28 Takahiro Sagawa

The crucial condition in the derivation of the Jarzynski equality (JE) from the fluctuation theorem is that the time integral of the phase space contraction factor can be exactly expressed as the entropy production resulting from the heat…

统计力学 · 物理学 2015-06-25 Z. C. Tu , Zicong Zhou

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

量子物理 · 物理学 2025-08-21 Konstantin Beyer , Walter T. Strunz