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We present a quantitative confocal-microscopy study of the transient and final microstructure of particle-stabilised emulsions formed via demixing in a binary liquid. To this end, we have developed an image-analysis method that relies on…

软凝聚态物质 · 物理学 2010-11-04 Job H J Thijssen , Paul S Clegg

Freeze-thaw cycles can be regularly observed in nature in water and are essential in industry and science. Objects present in the medium will interact with either an advancing solidification front during freezing or a retracting…

软凝聚态物质 · 物理学 2026-04-30 Wilfried Raffi , Jochem G. Meijer , Detlef Lohse

Freezing of dispersions is omnipresent in science and technology. While the passing of a freezing front over a solid particle is reasonably understood, this is not so for soft particles. Here, using an oil-in-water emulsion as a model…

流体动力学 · 物理学 2023-05-29 Jochem G. Meijer , Pallav Kant , Duco Van Buuren , Detlef Lohse

We present confocal microscopy studies of novel particle-stabilized emulsions. The novelty arises because the immiscible fluids have an accessible upper critical solution temperature. The emulsions have been created by beginning with…

软凝聚态物质 · 物理学 2009-11-11 P. S. Clegg , E. M. Herzig , A. B. Schofield , T. S. Horozov , B. P. Binks , M. E. Cates , W. C. K. Poon

The issue of the stability of Pickering emulsions is tackled at a mesoscopic level using dissipative particle dynamics simulations within the Adiabatic Biased Molecular Dynamics framework. We consider the early stage of the coalescence…

软凝聚态物质 · 物理学 2017-02-08 François Sicard , Alberto Striolo

This paper explores structural, interfacial and thermal properties of two types of Pickering emulsions containing alpha-cyclodextrin inclusion complexes: on one hand, emulsions were obtained between aqueous solutions of alpha-cyclodextrin…

软凝聚态物质 · 物理学 2018-10-02 Raul Diaz-Salmeron , Ismail Chaab , Florent Carn , Madeleine Djabourov , Kawthar Bouchemal

Soft, amorphous solids such as tissues, foams, and emulsions are composed of deformable particles. However, the effect of single-particle deformability on the collective behavior of soft solids is still poorly understood. We perform…

软凝聚态物质 · 物理学 2021-06-02 John D. Treado , Dong Wang , Arman Boromand , Michael P. Murrell , Mark D. Shattuck , Corey S. O'Hern

A mixture of hard-sphere particles and model emulsion droplets is studied with a Brownian dynamics simulation. We find that the addition of nonwetting emulsion droplets to a suspension of pure hard spheres can lead to both gas-liquid and…

软凝聚态物质 · 物理学 2015-03-13 Andrea Fortini

An important strategy to stabilize emulsions is to arrest coalescence of the constituent droplets with an opposing rheological force. Colloidal particles adsorbed on the surface of emulsion droplets in a Pickering emulsion become…

软凝聚态物质 · 物理学 2019-03-04 Zhaoyu Xie , Christopher J. Burke , Badel Mbanga , Patrick T. Spicer , Timothy J. Atherton

There is a large debate on the destabilization mechanism of emulsions. We present a simple technique using mechanical compression to destabilize oil-in-water emulsions. Upon compression of the emulsion, the continuous aqueous phase is…

Solidification of complex liquids is pertinent to numerous natural and industrial processes. Here, we examine the freezing of a W/O/W double-emulsion, i.e., water-in-oil compound droplets dispersed in water. We show that the solidification…

软凝聚态物质 · 物理学 2024-02-27 Jochem G. Meijer , Pallav Kant , Detlef Lohse

Gravitational settling of a droplet in air onto a soft substrate is a ubiquitous event relevant to many natural processes and engineering applications. We study this phenomenon by developing a three-phase lubrication model of droplet…

流体动力学 · 物理学 2022-02-02 Stéphane Poulain , Andreas Carlson

The structural evolution of suspensions upon freezing is studied with optical microscopy in a suspended droplet configuration. Droplets have millimeter size and consist in an aqueous mixture of silica particles while the surroundings phase…

软凝聚态物质 · 物理学 2018-05-10 Mathieu Nespoulous , Renaud Denoyel , Mickaël Antoni

Particles added to a fluid interface can be used as a surface stabilizer in the food, oil and cosmetic industries. As an alternative to rigid particles, it is promising to consider highly deformable particles that can adapt their…

软凝聚态物质 · 物理学 2016-10-27 Hadi Mehrabian , Jens Harting , Jacco H. Snoeijer

Binary mixture of oppositely charged of colloids can be used to stabilize water-in-oil or oil-in-water emulsions. A Monte Carlo simulation study to address the effect of charge ratio of colloids on the stability of Pickering emulsions is…

软凝聚态物质 · 物理学 2015-12-09 Sam David Christdoss Pushpam , Madivala G. Basavaraj , Ethayaraja Mani

The efficiency of soft particles to stabilize emulsions is examined by measuring their desorption free energy, i.e., the mechanical work required to detach the particle from a fluid interface. Here, we consider rubber-like elastic as well…

软凝聚态物质 · 物理学 2020-08-20 Hadi Mehrabian , Jacco H. Snoeijer , Jens Harting

We investigate the mechanical behavior of particle-stabilized droplets using micropipette aspiration. We observe that droplets stabilized with amphiphilic dumbbell-shaped particles exhibit a two-stage response to increasing suction…

软凝聚态物质 · 物理学 2017-01-25 Niveditha Samudrala , Jin Nam , Raphael Sarfati , Robert W. Style , Eric R. Dufresne

The ordering of particles in the drying process of a colloidal suspension is crucial in determining the properties of the resulting film. For example, microscopic inhomogeneities can lead to the formation of cracks and defects that can…

软凝聚态物质 · 物理学 2021-10-04 Maarten Wouters , Othmane Aouane , Marcello Sega , Jens Harting

Particle-stabilized emulsions are commonly used in various industrial applications. These emulsions can present in different forms, such as Pickering emulsions or bijels, which can be distinguished by their different topologies and…

软凝聚态物质 · 物理学 2015-02-10 Stefan Frijters , Florian Günther , Jens Harting

Cooled oil emulsion droplets in aqueous surfactant solution have been observed to flatten into a remarkable host of polygonal shapes with straight edges and sharp corners, but different driving mechanisms - (i) a partial phase transition of…

软凝聚态物质 · 物理学 2019-09-25 Pierre A. Haas , Diana Cholakova , Nikolai Denkov , Raymond E. Goldstein , Stoyan K. Smoukov
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