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The temperature dependence of the band gap is crucial to a semiconductor. Bulk black phosphorus (BP) is known to exhibit an anomalous behavior. Through optical spectroscopy, here we show that the temperature effect on BP band gap gradually…

With a semiconducting band gap and high charge carrier mobility, two-dimensional (2D) black phosphorus (BP), often referred to as phosphorene, holds significant promise for next generation electronics and optoelectronics. However, as a 2D…

材料科学 · 物理学 2015-02-10 Xiaolong Liu , Joshua D. Wood , Kan-Sheng Chen , EunKyung Cho , Mark C. Hersam

Artificial semiconductor heterostructures played a pivotal role in modern electronic and photonic technologies, providing a highly effective mean for the manipulation and control of carriers, from the visible to the far-infrared. Despite…

介观与纳米尺度物理 · 物理学 2018-05-01 Leonardo Viti , Miriam S. Vitiello

Black phosphorus nitrogen (BP-N) is an attractive high-energy-density material. However, high-pressure synthesized BP-N will decompose at low-pressure and cannot be quenched to ambient conditions. Finding a method to stabilize it at 0 GPa…

材料科学 · 物理学 2025-01-03 Guo Chen , Chengfeng Zhang , Yuanqin Zhu , Bingqing cao , Jie Zhang , Xianlong Wang

We realize p-p'-p junctions in few-layer black phosphorus (BP) devices, and use magneto-transport measurements to study the equilibration and transmission of edge states at the interfaces of regions with different charge densities. We…

介观与纳米尺度物理 · 物理学 2020-12-03 J. Yang , K. Wang , S. Che , Z. J. Tuchfeld , K. Watanabe , T. Taniguchi , D. Shcherbakov , S. Moon , D. Smirnov , R. Chen , M. Bockrath , C. N. Lau

We study the effect of impurity scattering effect in black phosphorurene (BP) in this work. For single impurity, we calculate impurity induced local density of states (LDOS) in momentum space numerically based on tight-binding Hamiltonian.…

介观与纳米尺度物理 · 物理学 2016-07-27 Y. L. Zou , J. T. Song , C. X. Bai , K. Chang

Defects are inevitably present in two-dimensional (2D) materials and usually govern their various properties. Here a comprehensive density functional theory-based investigation of 7 kinds of point defects in a recently produced {\gamma}…

材料科学 · 物理学 2021-03-15 Andrey A. Kistanov , Vladimir R. Nikitenko , Oleg V. Prezhdo

Negative compressibility generated by many-body effects in 2D electronic systems can enhance gate capacitance. We observe capacitance enhancement in a newly emerged 2D layered material, atomically thin black phosphorus (BP). The…

介观与纳米尺度物理 · 物理学 2016-04-05 Yingying Wu , Xiaolong Chen , Zefei Wu , Shuigang Xu , Tianyi Han , Jiangxiazi Lin , Yuan Cai , Yuheng He , Chun Cheng , Ning Wang

Zinc phosphide (Zn3P2) has had a long history of scientific interest largely because of its potential for earth-abundant photovoltaics. To realize high-efficiency Zn3P2 solar cells, it is critical to understand and control point defects in…

材料科学 · 物理学 2023-11-01 Zhenkun Yuan , Yihuang Xiong , Geoffroy Hautier

We demonstrate that encapsulation of atomically thin black phosphorus (BP) by hexagonal boron nitride (h-BN) sheets is very effective for minimizing the interface impurities induced during fabrication of BP channel material for quantum…

介观与纳米尺度物理 · 物理学 2016-07-12 Gen Long , Shuigang Xu , Junying Shen , Jianqiang Hou , Zefei Wu , Tianyi Han , Jiangxiazi Lin , Wing Ki Wong , Yuan Cai , Rolf Lortz , Ning Wang

Recently, black phosphorus (BP) has joined the two dimensional material family as a promising candidate for photonic applications, due to its moderate bandgap, high carrier mobility, and compatibility with a diverse range of substrates.…

Few-layer black phosphorus (BP), as the most alluring graphene analogue owing to its similar structure as graphene and thickness dependent direct band-gap, has now triggered a new wave of research on two-dimensional (2D) materials based…

The two-dimensional semiconductor phosphorene has attracted extensive research interests for potential applications in optoelectronics, spintronics, catalysis, sensors, and energy conversion. To harness phosphorene's potential requires a…

材料科学 · 物理学 2021-07-13 Biswas Rijal , Anne Marie Z. Tan , Christoph Freysoldt , Richard G. Hennig

We investigated polarization dependence of the Raman modes in black phosphorus (BP) using five different excitation wavelengths. The crystallographic orientation was determined by comparing polarized optical microscopy with high-resolution…

介观与纳米尺度物理 · 物理学 2015-11-10 Jungcheol Kim , Jae-Ung Lee , Jinhwan Lee , Hyo Ju Park , Zonghoon Lee , Changgu Lee , Hyeonsik Cheong

We show that the optical and electronic properties of nanocrystalline silicon can be efficiently tuned using impurity doping. In particular, we give evidence, by means of ab-initio calculations, that by properly controlling the doping with…

其他凝聚态物理 · 物理学 2009-11-13 Federico Iori , Elena Degoli , Rita Magri , Ivan Marri , G. Cantele , D. Ninno , F. Trani , O. Pulci , Stefano Ossicini

Since its discovery, the environmental instability of exfoliated black phosphorus (2D bP) has emerged as a challenge that hampers its wide application in chemistry, physics, and materials science. Many studies have been carried out to…

Atomic structure of single-crystalline black phosphorus was studied by high resolution synchrotron-based photoelectron diffraction (XPD). The results show that the topmost phosphorene layer in the black phosphorus is slightly displaced…

材料科学 · 物理学 2016-02-03 Luis Henrique de Lima , Lucas Barreto , Richard Landers , Abner de Siervo

By means of a multi-scale first-principles approach, a description of the local electronic structure of two-dimensional and narrow phosphorene sheets with various types of modifications is presented. First, a rational argument based on the…

材料科学 · 物理学 2016-02-03 Alejandro Lopez-Bezanilla

Using hybrid density functional theory combined with a semiempirical van der Waals dispersion correction, we have investigated the structural and electronic properties of vacancies and self-interstitials in defective few-layer phosphorene.…

材料科学 · 物理学 2015-08-21 V. Wang , Y. Kawazoe , W. T. Geng

The latest achievements in the fabrication of black phosphorus thin layers, towards the technological breakthrough of a phosphorene atomically thin layer, are paving the way for a their employment in electronics, optics, and…

光学 · 物理学 2016-12-21 I. Kriegel , S. Toffanin , F. Scotognella