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The ordering kinetics of standing cylinder-forming polystyrene-block-poly (methyl methacrylate) block copolymers (molecular weight: 39 kg/mol) close to the order-disorder transition is experimentally investigated following the temporal…

软凝聚态物质 · 物理学 2026-01-15 Gabriele Seguini , Fabio Zanenga , Gianluca Cannetti , Michele Perego

Understanding growth evolution and thereby implementing precise microstructural tuning of two-dimensional (2D) conjugated coordination polymers (cCPs) is crucial to achieve efficient electronic conduction towards their full potential and to…

We studied solvent-driven ordering dynamics of block copolymer films supported by a densely cross-linked polymer network designed as organic hard mask (HM) for lithographic fabrications. The ordering of microphase separated domains at low…

软凝聚态物质 · 物理学 2014-05-14 Anja Stenbock-Fermor , Armin W. Knoll , Alexander Böker , Larisa Tsarkova

The surface morphologies of poly(chloro-p-xylylene) films were measured using atomic force microscopy and analyzed within the frame work of the dynamic scaling theory. The evolution of polymer films grown with fixed experimental parameters…

统计力学 · 物理学 2009-11-13 I. J. Lee , Mira Yun , Sang-Min Lee , Ja-Yeon Kim

Self-consistent field theory (SCFT) and strong segregation theory (SST) are used to explore the parameter space governing the self-assembly of cylinder forming block copolymers (BCPs) on a modulated substrate. The stability of in-plane…

材料科学 · 物理学 2018-11-16 Karim Gadelrab , Alfredo Alexander-Katz

Using self-consistent field and density-functional theories, we first investigate colloidal self-assembling of colloid/polymer films confined between two soft surfaces grafted by polymers. With the increase of colloidal concentrations, the…

软凝聚态物质 · 物理学 2007-05-23 Chun-lai Ren , Yu-qiang Ma

We study block copolymers (BCP) on patterned substrates, where the top polymer film surface is not constrained but is a free interface that adapts its shape self-consistently. In particular, we investigate the combined effect of the free…

软凝聚态物质 · 物理学 2016-02-18 Xingkun Man , David Andelman , Henri Orland

We investigate the ordered morphologies occurring in thin-films diblock copolymer. For temperatures above the order-disorder transition and for an arbitrary two-dimensional surface pattern, we use a Ginzburg-Landau expansion of the free…

软凝聚态物质 · 物理学 2007-05-23 Yoav Tsori , David Andelman

Mechanical stretching behavior of poly(styrene-b-ethylene-co-butylene-b-styrene) (SEBS) triblock copolymer (87 wt% polyethylene-co-butylene (PEB) block, 13 wt% polystyrene (PS) block) was investigated by three different stretching and in…

We report pressure-dependent transient picosecond and continuous-wave photomodulation studies of disordered and ordered films of 2-methoxy-5-(2-ethylhexyloxy) poly(para-phenylenevinylene). Photoinduced absorption (PA) bands in the…

强关联电子 · 物理学 2015-05-20 K. Aryanpour , C. -X. Sheng , E. Olejnik , B. Pandit , D. Psiachos , S. Mazumdar , Z. V. Vardeny

We report on sexithiophene films, about 150nm thick, grown by thermal evaporation on single crystal oxides and, as comparison, on Si/SiO2. By heating the entire deposition chamber at 100 C we obtain standing-up oriented molecules all over…

材料科学 · 物理学 2015-05-13 Carmela Aruta , Pasquale D'Angelo , Mario Barra , Giovanni Ausanio , Antonio Cassinese

The crystal growth of isotactic polystyrene (it-PS) is investigated in very thin, 11 nm thick films. The it-PS crystals grown in the thin films show quite different morphology from that in the bulk. With decreasing crystallization…

软凝聚态物质 · 物理学 2016-08-31 Ken Taguch , Hideki Miyaji , Kunihide Izumi , Akitaka Hoshino , Yoshihisa Miyamoto , Ryohei Kokawa

Simulations and experiments of nanorods (NRs) show that co-assembly with block copolymer (BCP) melts leads to the formation of a superstructure of side-to-side NRs perpendicular to the lamellar axis. A mesoscopic model is validated against…

软凝聚态物质 · 物理学 2020-04-14 Javier Diaz , Marco Pinna , Andrei V. Zvelindovsky , Ignacio Pagonabarraga , Roy Shenhar

We develop thin films of blends of polystyrene (PS) with the thermoresponsive polymer poly(N-isopropylacrylamide) (PNIPAM) (PS/PNIPAM) and its diblock copolymer polystyrene-b-poly(N-isopropylacrylamide) (PS/PS-b-PNIPAM) in different blend…

Block copolymer (BCP) melts play a critical role in the design of thermoplastics, owing in large part to the creation of alternating nano-scale domains of soft and stiff components. Considerable attention has been given to the…

软凝聚态物质 · 物理学 2026-03-31 Krista G. Schoonover , Gaurav Rawat , Emily B. Pentzer , Michael S. Dimitriyev

Homogeneous nucleation process of polyethylene (PE) is studied with full-atom molecular dynamic simulation. To account the complex shape with low symmetry and the peculiar intra-chain conformational order of polymer, we introduce a shape…

软凝聚态物质 · 物理学 2017-12-13 Xiaoliang Tang , Junsheng Yang , Tingyu Xu , Fucheng Tian , Chun Xie , Liangbin Li

Polymer blends offer an exciting material for various potential applications due to their tunable properties by varying constituting components and their relative composition. Our simulation results unravel an intrinsic relationship between…

软凝聚态物质 · 物理学 2016-10-13 Ashok Kumar Dasmahapatra

We present NanoImprint lithography experiments and modeling of thin films of block copolymers (BCP). The NanoImprint lithography is used to align perpendicularly lamellar phases, over distances much larger than the natural lamellar…

Co-assembly of inorganic nanoparticles (NPs) and nanostructured polymer matrix represents an intricate interplay of enthalpic or entropic forces. Particle size largely affects the phase behavior of the nanocomposite. Theoretical studies…

软凝聚态物质 · 物理学 2022-04-25 Le Ma , Hejin Huang , Peter Ercius , Alfredo Alexander-Katz , Ting Xu

We present some results of Monte Carlo simulations for the deposition of particles of different sizes on a two-dimensional substrate. The particles are linear, height one, and can be deposited randomly only in the two, $x$ and $y$…

统计力学 · 物理学 2010-06-15 F. L. Forgerini , W. Figueiredo
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