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相关论文: Thermodynamic properties of diatomic molecules sys…

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An algebraic model based on Lie-algebraic techniques is applied to the analysis of thermodynamic vibrational properties of diatomic molecules. The local anharmonic effects are described by a Morse-like potential and corresponding anharmonic…

统计力学 · 物理学 2007-05-23 Maia Angelova , A. Frank

In this paper we present a closed-form expression of the vibrational partition function for the one-dimensional q-deformed Morse potential energy model. Through this function the related thermodynamic functions are derived and studied in…

量子物理 · 物理学 2018-02-06 Abdelmalek Boumali

An algebraic model based on Lie-algebraic and discrete symmetry techniques is applied to the analysis of thermodynamic vibrational properties of molecules. The local anharmonic effects are described by a Morse-like potential and the…

统计力学 · 物理学 2017-08-23 Maia Angelova , A. Frank

Within the framework of non-relativistic quantum mechanics, the ro-vibrational energy spectra of the improved deformed exponential-type potential model are obtained using the Greene-Aldrich approximation scheme and an appropriate coordinate…

化学物理 · 物理学 2020-01-15 Uduakobong S. Okorie , Akpan N. Ikot , Ephraim O. Chukwuocha

In this research article, thermal properties of energy dependent Kratzer potential (EDKP) for CO diatomic molecule is presented. The non-relativistic energy spectra earlier obtained by Ikot et al. [7] for EDKP was utilized to numerically…

化学物理 · 物理学 2021-11-19 Collins Edet , Uduakobong Okorie , Akpan Ikot

In this study, we apply the parametric Nikiforov-Uvarov method to obtain the bound state solution of Schrodinger wave equation in the presence of Kratzer plus generalized Morse potential (KPGM). The energy eigen equation and the…

A Generalized Morse Potential (GMP) is an extension of the Morse Potential (MP) with an additional exponential term and an additional parameter that compensate for MP's erroneous behavior in the long range part of the interaction potential.…

化学物理 · 物理学 2022-10-26 Saad Qadeer , Garrett D. Santis , Panos Stinis , Sotiris S. Xantheas

For diatomic molecules and chains bound anharmonically by interactions such a the Lennard Jones and Morse potentials, we obtain analytical expressions for thermodynamic observables including the mean bond length, thermally averaged internal…

统计力学 · 物理学 2016-05-20 D. J. Priour , Christopher Watenpool

Lie-algebraic and quantum-algebraic techniques are used in the analysis of thermodynamic properties of molecules and solids. The local anharmonic effects are described by a Morse-like potential associated with the $su(2)$ algebra. A…

统计力学 · 物理学 2007-05-23 Maia Angelova

The Deng-Fan-Eckart (DFE) potential is as good as the Morse potential in studying atomic interaction in diatomic molecules. By using the improved Pekeris-type approximation, to deal with the centrifugal term, we obtain the bound-state…

化学物理 · 物理学 2020-09-22 C. O. Edet , U. S. Okorie , G. Osobonye , A. N. Ikot , G. J. Rampho , R. Sever

Accurate free-energy calculations are essential for predicting thermodynamic properties and phase stability, but existing methods are limited: phonon-based approaches neglect anharmonicity and liquids, while molecular dynamics (MD) is…

材料科学 · 物理学 2025-11-19 Ekaterina Spirande , Timofei Miryashkin , Andrei Kolmakov , Alexander Shapeev

In this work, the thermodynamic property of pseudoharmonic potential in the presence of external magnetic and AB fields is investigated. We used effective Boltzmann factor within the superstatistics formalism to obtain the thermodynamic…

量子物理 · 物理学 2019-10-28 A. N. Ikot , U. S. Okorie , G. Osobonye , P. O. Amadi , C. O. Edet , G. J. Rampho , R. Sever

The Variational Method is applied within the context of Supersymmetric Quantum Mechanics to provide information about the energy and eigenfunction of the lowest levels of a Hamiltonian. The approach is illustrated by the case of the Morse…

高能物理 - 理论 · 物理学 2009-10-31 Elso Drigo Filho , Regina Maria Ricotta

In this work, we investigate the quantum dynamics of a particle subject to the Morse potential within the framework of Dunkl quantum mechanics. By employing the Dunkl derivative operator, which introduces reflection symmetry, we construct a…

量子物理 · 物理学 2025-06-30 B. Hamil , B. C. Lütfüoğlu , A. N. Ikot , U. S. Okorie

It is shown that the energy spectrum of the pure vibrational levels of the molecule consisting of two atoms interacting with each other via the modified Rosen-Morse potential, the analytical expressions for the vibrational partition…

化学物理 · 物理学 2019-02-19 Ikhtier Umirzakov

A unified approach is used to study vibrational properties of periodic systems with first-principles methods and including anharmonic effects. Our approach provides a theoretical basis for the determination of phonon-dependent quantities at…

材料科学 · 物理学 2014-06-12 Bartomeu Monserrat , N. D. Drummond , R. J. Needs

The thermodynamical properties of a generalized Dicke model are calculated and related with the critical properties of its energy spectrum, namely the quantum phase transitions (QPT) and excited state quantum phase transitions (ESQPT). The…

We propose an accurate and efficient method to compute vibrational spectra of molecules, based on exact diagonalization of an algebraically calculated matrix based on powers of Morse coordinate. The present work focuses on the 1D potential…

化学物理 · 物理学 2009-11-13 Andrea Bordoni , Nicola Manini

This is the first in a series of articles in which we study the rotating Morse potential model for diatomic molecules in the tridiagonal J-matrix representation. Here, we compute the bound states energy spectrum by diagonalizing the finite…

化学物理 · 物理学 2011-11-10 I. Nasser , M. S. Abdelmonem , H. Bahlouli , A. D. Alhaidari

Here we present a theoretical analysis of inelastic effects on thermoelectric properties of molecular-scale junction in both linear and nonlinear response regimes. Considered device is composed of molecular quantum dot (with discrete energy…

介观与纳米尺度物理 · 物理学 2015-06-25 Kamil Walczak
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