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In this investigation, we conducted density functional theory simulations to explore the mechanical responses of single-layer GeP, GeAs, SiP and SiAs. In particular, we explored the possibility of band-gap engineering in these 2D structures…

计算物理 · 物理学 2018-06-19 Bohayra Mortazavi , Timon Rabczuk

In this research work, the 2D structure of the germanene layer is compounded with 2D group-III phosphides: AlP and GaP. The planar structure of AlP and low-buckled GaP have been taken to form the bilayer patterns. In each case, three…

系统与控制 · 电气工程与系统科学 2022-01-11 Md. Rayid Hasan Mojumder

Today, 2D semiconductor materials have been extended into the nitrogen group: phosphorene, arsenene, antimonene and even nitrogene. Motivated by them, based upon first-principles density functional calculations, we propose a new…

介观与纳米尺度物理 · 物理学 2016-03-11 Hang Xiao , Feng Hao , Xiangbiao Liao , Xiaoyang Shi , Yayun Zhang , Xi Chen

The existence of two novel hybrid two-dimensional (2D) monolayers, 2D B3C2P3 and 2D B2C4P2, has been predicted based on the density functional theory calculations. It has been shown that these materials possess structural and thermodynamic…

Phosphorene, a well-studied 2D allotrope of phosphorus, features unique properties such as widely tunable bandgap, high carrier mobility, and remarkable intrinsic in-plane anisotropy. Utilizing these structural and electronic properties, we…

材料科学 · 物理学 2024-04-12 Saibabu Madas , Subhendu Kahaly , Mousumi Upadhyay Kahaly

In this letter, we show that a new class of two-dimensional phosphorus allotropes can be constructed via assembling the previously proposed ultrathin metastable phosphorus nanotube into planar structures in different stacking orientations.…

材料科学 · 物理学 2018-05-02 Zhenqing Li , Chaoyu He , Tao Ouyang , Chunxiao Zhang , Cao Tang , Rudolf A. Romer , Jianxin Zhong

Most recently, a brand new phosphorus allotrope called green phosphorus has been predicted, which has a direct band gap up to 2.4 eV, and its single-layer form termed green phosphorene shows high stability. Here the mechanical properties…

材料科学 · 物理学 2018-06-18 Guang Yang , Tianxing Ma , Xihong Peng

In this paper we present a thorough first-principles based density functional theory study of the structural stability, electronic, magnetic, and optical properties of pristine and doped gallium phosphide (GaP) monolayers. The pristine GaP…

材料科学 · 物理学 2023-09-26 Khushboo Dange , Rachana Yogi , Alok Shukla

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

介观与纳米尺度物理 · 物理学 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

Three two-dimensional phosphorus nitride (PN) monolayer sheets (named as $\alpha$-, $\beta$-, and $\gamma$-PN, respectively) with fantastic structures and properties are predicted based on first-principles calculations. The $\alpha$-PN and…

材料科学 · 物理学 2015-10-02 ShuangYing Ma , Chaoyu He , L. Z. Sun , Haiping Lin , Youyong Li , K. W. Zhang

We propose previously unknown allotropes of phosphorus carbide (PC) in the stable shape of an atomically thin layer. Different stable geometries, which result from the competition between sp2 bonding found in graphitic C and sp3 bonding…

材料科学 · 物理学 2016-05-25 Jie Guan , Dan Liu , Zhen Zhu , David Tomanek

Due to the strong quantum confinement effect, few-layer {\gamma}-InSe exhibits a layer-dependent bandgap, spanning the visible and near infrared regions, and thus recently draws tremendous attention. As a two-dimensional material, the…

介观与纳米尺度物理 · 物理学 2018-03-20 Chaoyu Song , Fengren Fan , Ningning Xuan , Shenyang Huang , Guowei Zhang , Chong Wang , Zhengzong Sun , Hua Wu , Hugen Yan

Phosphorene, an emerging elemental two-dimensional (2D) direct band gap semiconductor with fascinating structural and electronic properties distinctively different from other 2D materials such as graphene and MoS2, is promising for novel…

材料科学 · 物理学 2015-04-21 Yongqing Cai , Qingqing Ke , Gang Zhang , Yuan Ping Feng , Vivek B Shenoy , Yong-Wei Zhang

Controlling a thickness dependence of electronic properties for two-dimensional (2d) materials is among primary goals for their large-scale applications. Herein, employing a first-principles computational approach, we predict that Si…

材料科学 · 物理学 2018-02-14 Oleksandr I. Malyi , Kostiantyn V. Sopiha , Ihor Radchenko , Ping Wu , Clas Persson

The existence of a new two dimensional CN2 structure was predicted using ab-initio molecular dynamics (AIMD) and density-functional theory calculations. It consists tetragonal and hexagonal rings with C-N and N-N bonds arranged in a…

材料科学 · 物理学 2021-01-29 Qun Wei , Ying Yang , Alexander Gavrilov , Xihong Peng

We perform systematic investigation on the geometric, energetic and electronic properties of group IV-VI binary monolayers (XY), which are the counterparts of phosphorene, by employing density functional theory based electronic structure…

介观与纳米尺度物理 · 物理学 2016-04-19 C. Kamal , Aparna Chakrabarti , Motohiko Ezawa

Binary metallic phosphide, Nb2P5, belongs to technologically important class of materials. Quite surprisingly, a large number of physical properties of Nb2P5, including elastic properties and their anisotropy, acoustic, electronic (DOS,…

材料科学 · 物理学 2021-03-31 M. I. Naher , S. H. Naqib

Using first-principles full-potential density functional calculations, we predict that mechanically tunable band-gap is realizable in ZnS monolayer in graphene-like honeycomb structure by application of in-plane homogeneous biaxial strain.…

材料科学 · 物理学 2012-10-12 Harihar Behera , Gautam Mukhopadhyay

The field of topological mechanics has recently emerged due to the interest in robustly transporting various types of energy in a flaw and defect-insensitive fashion. While there have been a significant number of studies based on…

材料科学 · 物理学 2021-12-08 Jin-Wu Jiang , Harold S. Park

Edge atomic configuration often plays an important role in dictating the properties of finite-sized two-dimensional (2D) materials. By performing ab initio calculations, we identify a highly stable zigzag edge of phosphorene, which is the…

材料科学 · 物理学 2017-03-29 Junfeng Gao , Xiangjun Liu , Gang Zhang , Yong-Wei Zhang
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