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In this work, we propose a method of selecting the most desirable combinations of material for a perovskite solar cell design utilizing the genetic algorithm. Solar cells based on the methylammonium lead halide, CH3NH3PbX3, attract…

材料科学 · 物理学 2020-11-17 Eungkyun Kim , Indranil Bhattacharya

In the search for stable lead (Pb) free perovskites, Vacancy ordered double perovskite (VODP), A$_2$BX$_6$ has emerged as a promising class of materials for solar harvesting owing to their nontoxicity, better stability, and unique…

材料科学 · 物理学 2023-09-13 Supriti Ghorui , Jiban Kangsabanik , M. Aslam , Aftab Alam

Hybrid perovskites (CH3NH3PbI3) is one of the most promising novel materials for solar harvesting. Toxicity of lead (Pb), however, has always remained a concern. We investigated the electronic structure of complete replacement of Pb by…

材料科学 · 物理学 2016-10-18 Jiban Kangsabanik , Vikram , Aftab Alam

The scalability of highly efficient organic-inorganic perovskite solar cells (PSCs) is one of the remaining challenges of solar module manufacturing. Various scalable methods have been explored to strive for uniform perovskite films of high…

Hybrid organic/inorganic perovskites have emerged as efficient semiconductor materials for applications in photovoltaic solar cells with conversion efficiency above 20 \%. Recent experiments have synthesized ultra-thin two-dimensional (2D)…

材料科学 · 物理学 2018-12-12 Alejandro Molina-Sánchez

Lead-free double perovskite halides are emerging optoelectronic materials that are alternatives to lead-based perovskite halides. Recently, single-crystalline double perovskite halides were synthesized, and their intriguing functional…

Halide perovskites are recently emerged as one of the frontline optoelectronic materials for device applications and have been extensively studied in past few years. Among these while, lead-based materials were most widely explored,…

Metal halide perovskite solar cells being one of the fastest emerging technologies for renewable energy still has to become more industry friendly in a way that will allow using it for thin film modules or tandems with conventional silicon…

Organic-inorganic hybrid perovskites are considered to be most promising photovoltaic materials. Highest efficiencies of perovskite solar cells have been achieved by using appropriate cation and anion mixtures. Mixed perovskite solar cells…

化学物理 · 物理学 2019-12-23 Gee Yeong Kim , Alessandro Senocrate , Yaru Wang , Davide Moia , Joachim Maier

Organic-inorganic hybrid perovskites such as methylammonium lead iodide (CH3NH3PbI3) are game-changing semiconductors for solar cells and light-emitting devices owing to their exceptionally long carrier lifetime and diffusion length.…

Perovskite solar cells (PSCs) with superior performance have been recognized as a potential candidate in photovoltaic technologies. However, the defects in active perovskite layer induce non-radiative recombination which restricts the…

Recent technical and commercial successes of existing thin film solar cell technologies motivates exploration of next-generation photovoltaic (PV) absorber materials. Of particular scientific interest are compounds like CuSbSe$_2$, which do…

材料科学 · 物理学 2015-05-12 Adam Welch , Lauryn Baranowski , Pawel Zawadzki , Stephan Lany , Colin Wolden , Andriy Zakutayev

Using density-functional theory calculations, we analyze the optical absorption properties of lead (Pb)-free metal halide perovskites (AB$^{2+}$X$_3$) and double perovskites (AB$^+$B$^{3+}$X$_6$) (A = Cs or monovalent organic ion, B$^{2+}$…

材料科学 · 物理学 2017-06-19 Weiwei Meng , Xiaoming Wang , Zewen Xiao , Jianbo Wang , David Mitzi , Yanfa Yan

Organic-inorganic semiconductors, which adopt the perovskite crystal structure, have perturbed the landscape of contemporary photovoltaics research. In this Account, we discuss the internal motion of methylammonium lead iodide…

材料科学 · 物理学 2016-05-31 Jarvist M. Frost , Aron Walsh

Organic-inorganic coupling in the hybrid lead-halide perovskite is a central issue in rationalizing the outstanding photovoltaic performance of these emerging materials. Here we compare and contrast the evolution of structure and dynamics…

2D quantum confined hybrid materials are of great interest from a solid state physics standpoint because of the rich multibody phenomena hosted, their tunability and easy synthesis allowing to create material libraries. In addition, from a…

Achieving control over the transport properties of charge-carriers is a crucial aspect of realizing high-performance electronic materials. In metal-halide perovskites, which offer convenient manufacturing traits and tunability for certain…

Organic-inorganic halide perovskite solar cells have attracted much attention due to their low-cost fabrication, flexibility, and high-power conversion efficiency. More recent efforts show that the reduction from three- to two-dimensions…

材料科学 · 物理学 2021-09-03 Rahul Singh , Prashant Singh , Ganesh Balasubramania

Lead-free tin-based perovskites are highly appealing for the next generation of solar cells due to their intriguing optoelectronic properties. However, the tendency of Sn2+ oxidation to Sn4+ in the tin-based perovskites induces serious film…

化学物理 · 物理学 2022-06-15 Hejin Yan , Bowen Wang , Xuefei Yan , Qiye Guan , Hongfei Chen , Zheng Shu , Dawei Wen , Yongqing Cai

We introduce a pioneering strategy to enhance the environmental stability of perovskite thin films, a critical step forward in advancing their application in optoelectronics. Through the innovative application of matrix encapsulation…