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We present an X-ray Compton scattering study on aqueous Trimethylamine N-oxide (TMAO) and guanidine hydrochloride solutions (GdnHCl) as a function of temperature. Independent from the concentration of the solvent, Compton profiles almost…

We have developed x-ray diffraction measurements with high energy-resolution and accuracy to study water structure at three different temperatures (7, 25 and 66 C) under normal pressure. Using a spherically curved Ge crystal an energy…

The mechanisms of cold- and pressure-denaturation of proteins are matter of debate and are commonly understood as due to water-mediated interactions. Here we study several cases of proteins, with or without a unique native state, with or…

生物物理 · 物理学 2026-01-13 Valentino Bianco , Giancarlo Franzese

In this paper we apply hydrodynamics for systems with continuous broken symmetries to heavy ion collisions in the framework of (1+1) dimensional Bjorken model. The temperature profile with respect to proper time determined in that context…

高能物理 - 唯象学 · 物理学 2009-11-07 Y. Lallouet , D. Davesne , C. Pujol

Water and silicon are chemically dissimilar substances with common physical properties. Their liquids display a temperature of maximum density, increased diffusivity on compression, they form tetrahedral crystals and tetrahedral amorphous…

软凝聚态物质 · 物理学 2008-09-18 Valeria Molinero , Emily B. Moore

Recent x-ray Compton scattering experiments in ice have provided useful information about the quantum nature of the interaction between H$_2$O monomers. The hydrogen bond is characterized by a certain amount of charge transfer which could…

材料科学 · 物理学 2007-10-11 B. Barbiellini , A. Shukla

Water plays a fundamental role in the structure and function of proteins and other biomolecules. The thermodynamic profile of water molecules surrounding a protein are critical for ligand binding and recognition. Therefore, identifying the…

生物大分子 · 定量生物学 2024-11-26 Florian B. Hinz , Matthew R. Masters , Julia N. Kieu , Amr H. Mahmoud , Markus A. Lill

We extend Wertheim's thermodynamic perturbation theory to derive the association free energy of a multicomponent mixture for which double bonds can form between any two pairs of the molecules' arbitrary number of bonding sites. This…

软凝聚态物质 · 物理学 2021-02-26 Michael P. Howard , Zachary M. Sherman , Delia J. Milliron , Thomas M. Truskett

Most water in the universe may be superionic, and its thermodynamic and transport properties are crucial for planetary science but difficult to probe experimentally or theoretically. We use machine learning and free energy methods to…

计算物理 · 物理学 2021-11-24 Bingqing Cheng , Mandy Bethkenhagen , Chris J. Pickard , Sebastien Hamel

The Random First Order Transition (RFOT) theory of glasses provides a unified framework for explaining the observed correlations of the kinetic and thermodynamic behaviors of glass-forming liquids having a wide variety of chemical…

软凝聚态物质 · 物理学 2025-07-29 M. H. Brown , P. G. Wolynes

Interpretation of the X-ray spectra of water as evidence for its asymmetric structure has challenged the conventional symmetric nearly-tetrahedral model and initiated an intense debate about the order and symmetry of the hydrogen bond…

化学物理 · 物理学 2014-06-23 Thomas D. Kühne , Rustam Z. Khaliullin

The framework of anisotropic hydrodynamics is used in 3+1 dimensions to analyze behavior of matter produced in ultra-relativistic heavy-ion collisions. The model predictions for the hadronic transverse-momentum spectra, directed and…

核理论 · 物理学 2015-06-05 Wojciech Florkowski , Radoslaw Ryblewski

The thermodynamic dislocation theory presented in preceding papers is used here to describe shear-banding instabilities. Central ingredients of the theory are a thermodynamically defined effective configurational temperature, and a formula…

材料科学 · 物理学 2016-12-02 J. S. Langer

Entropy alone can self-assemble hard particles into colloidal crystals of remarkable complexity whose structures are the same as atomic and molecular crystals, but with larger lattice spacings. Although particle-based molecular simulation…

软凝聚态物质 · 物理学 2021-07-06 Thi Vo , Sharon C. Glotzer

We investigate the structural properties of liquid water at near ambient conditions using first-principles molecular dynamics simulations based on a semilocal density functional augmented with nonlocal van der Waals interactions. The…

软凝聚态物质 · 物理学 2016-08-01 Giacomo Miceli , Stefano de Gironcoli , Alfredo Pasquarello

Recent experimental results suggest that a particular hydrodynamic theory describes charge fluctuations at long wavelengths in the square-lattice Hubbard model. Due to the continuity equation, the correlation functions for the charge and…

强关联电子 · 物理学 2025-02-05 J. Vucicevic , S. Predin , M. Ferrero

First shells of hydration and bulk solvent plays a crucial role in the folding of proteins. Here, the role of water in the dynamics of proteins has been investigated using a theoretical protein-solvent model and a statistical physics…

软凝聚态物质 · 物理学 2015-05-27 Olivier Collet

A simple model for the formation of the polymer-enzyme conjugates has been proposed and described using corresponding extension of the Wertheim's first-order thermodynamic perturbation theory (TPT1) for the system of associating chain…

软凝聚态物质 · 物理学 2025-03-12 Halyna Butovych , Yurij V. Kalyuzhnyi , Taras Patsahan , Jaroslav Ilnytskyi

A simple theory for the leading-order correction g_1(r) to the structure of a hard-sphere liquid with discrete (e.g. square-well) potential perturbations is proposed. The theory makes use of a general approximation that effectively…

统计力学 · 物理学 2007-12-10 Artur B. Adib

We consider the low-energy effective field theory describing the infrared dynamics of non-dissipative fluids. We extend previous work to accommodate conserved charges, and we clarify the matching between field theory variables and…

高能物理 - 理论 · 物理学 2012-08-23 Sergei Dubovsky , Lam Hui , Alberto Nicolis , Dam Thanh Son
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